全文获取类型
收费全文 | 10635篇 |
免费 | 883篇 |
国内免费 | 548篇 |
专业分类
化学 | 7300篇 |
晶体学 | 145篇 |
力学 | 468篇 |
综合类 | 46篇 |
数学 | 967篇 |
物理学 | 3140篇 |
出版年
2024年 | 18篇 |
2023年 | 136篇 |
2022年 | 258篇 |
2021年 | 350篇 |
2020年 | 314篇 |
2019年 | 311篇 |
2018年 | 262篇 |
2017年 | 255篇 |
2016年 | 408篇 |
2015年 | 357篇 |
2014年 | 444篇 |
2013年 | 731篇 |
2012年 | 878篇 |
2011年 | 913篇 |
2010年 | 599篇 |
2009年 | 549篇 |
2008年 | 689篇 |
2007年 | 615篇 |
2006年 | 573篇 |
2005年 | 476篇 |
2004年 | 418篇 |
2003年 | 347篇 |
2002年 | 343篇 |
2001年 | 217篇 |
2000年 | 173篇 |
1999年 | 152篇 |
1998年 | 121篇 |
1997年 | 105篇 |
1996年 | 106篇 |
1995年 | 96篇 |
1994年 | 70篇 |
1993年 | 75篇 |
1992年 | 68篇 |
1991年 | 67篇 |
1990年 | 52篇 |
1989年 | 54篇 |
1988年 | 40篇 |
1987年 | 33篇 |
1986年 | 33篇 |
1985年 | 33篇 |
1984年 | 36篇 |
1983年 | 28篇 |
1982年 | 26篇 |
1981年 | 32篇 |
1980年 | 22篇 |
1979年 | 20篇 |
1978年 | 25篇 |
1977年 | 21篇 |
1976年 | 21篇 |
1975年 | 21篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
11.
Young-Bae Seu Taeg-Kyeong Lim Chang-Jin Kim Sun-Chul Kang 《Tetrahedron: Asymmetry》1995,6(12):3009-3014
Optically active epoxy alcohol, (R)-2-butyryloxymethylglycidol3 which is the precursor of a tert-alcohol chiral building block was obtained in high enantiomeric purity, 98.7% e.e., by lipase-catalyzed asymmetric hydrolysis using a phosphate buffer and organic co-solvent system in 95% of chemical yield. 相似文献
12.
Kyung Hwa Hong Jong Lyoul Park In Hwan Sul Ji Ho Youk Tae Jin Kang 《Journal of Polymer Science.Polymer Physics》2006,44(17):2468-2474
Polyvinyl alcohol (PVA) nanofibers containing Ag nanoparticles were prepared by electrospinning PVA/silver nitrate (AgNO3) aqueous solutions, followed by short heat treatment, and their antimicrobial activity was investigated for wound dressing applications. Since PVA is a water soluble and biocompatible polymer, it is one of the best materials for the preparation of wound dressing nanofibers. After heat treatment at 155 °C for 3 min, the PVA/AgNO3 nanofibers became insoluble, while the Ag+ ions therein were reduced so as to produce a large number of Ag nanoparticles situated preferentially on their surface. The residual Ag+ ions were reduced by subsequent UV irradiation for 3 h. The average diameter of the Ag nanoparticles after the heat treatment was 5.9 nm and this value increased slightly to 6.3 nm after UV irradiation. It was found that most of the Ag+ ions were reduced by the simple heat treatment. The PVA nanofibers containing Ag nanoparticles showed very strong antimicrobial activity. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2468–2474, 2006 相似文献
13.
For the methylsilsesquioxane film whose optical birefringence is almost zero, it was recently reported that its vertical thermal expansion coefficient (CTE) was approximately one order of magnitude larger than the lateral CTE. Though the birefringence is not an absolute predictor of anisotropic behavior, the discrepancy in both the CTEs was so remarkable that it was essential to investigate whether the anisotropy was intrinsic property or not. If the effect of Poisson's ratio is considered in the calculation of the vertical CTE and when elastic modulus measured by surface acoustic wave spectroscopy is used in the assessment of the lateral CTE, both the CTEs are coincident with each other. Therefore, it can be concluded that the discrepancy in the CTEs can be attributed to a higher in‐plane polymer chain orientation but it can also arise from the misleadingly assumed modulus and Poisson's ratio. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3109–3120, 2006 相似文献
14.
In this paper, we give a recursive construction from an LTTS(v + 2) to an LTTS(16v + 2) for v 3. Furthermore, the existence of LTTS(2n + 2) is proved. Thereby, we completely solve the existence problem of LTTS)(v) (large set of pairwise disjoint transitive triple systems of order v). 相似文献
15.
16.
Suoyuan Lian Lei Gao Zhenhui Kang Di Wu Yang Lan Lin Xu 《Solid State Communications》2004,132(6):375-378
Single-crystal magnetite nanowires with average diameter of ca. 20 nm and length of up to several micrometers were prepared by a simple alkaline surfactant-free hydrothermal process. The crystallinity, purity, morphology, and structural features of the as-prepared magnetite nanowires were investigated by powder X-ray diffraction, transmission electron microscopy (TEM) and selected area electron diffraction. The composition and length of nanowires depends on the pH, with higher pH favoring longer nanowires composed entirely of Fe3O4. A mechanism for nanowire growth is proposed. 相似文献
17.
对一类遗传程序设计问题,提出了简单等长的分布式染色体,取代复杂变长的树结构染色体,使演化算子操作更方便,个体复杂度得到有效控制.用该染色体形式解决割草问题,分析了分布式染色体带来的一些性质,并给出了很好的计算结果. 相似文献
18.
Georgia Benkart Seok-Jin Kang Duncan Melville 《Transactions of the American Mathematical Society》1998,350(8):3297-3319
We construct quantum deformations of enveloping algebras of Borcherds superalgebras, their Verma modules, and their irreducible highest weight modules.
19.
E.Y. Kang Yoon B. Kim K.Y. Kim Y.H. Chung H.K. Baik 《Journal of magnetism and magnetic materials》2006
FeSiBNb amorphous powder cores were prepared with the amorphous powder by gas atomization and subsequent hot pressing of resulting powder after creating oxide layers on the amorphous powder. Fully amorphous FeSiBNb powders with good soft magnetic properties were successfully obtained in the particle size range below 100 μm. FeSiBNb amorphous powder cores exhibit stable permeability up to 10 MHz, showing excellent high-frequency characteristics. 相似文献
20.
Jin Kyu Park Dong Hun Lee Bok Ju Song Jae Buem Oh Hwan Kyu Kim 《Journal of polymer science. Part A, Polymer chemistry》2006,44(3):1326-1342
We have designed and synthesized novel perfluorinated polyimides with 3D controlled structure. At first, we successfully developed the new synthetic routes to diamines with pendant bulky perfluorinated aromatic units in a multi‐step synthetic procedure. Novel perfluorinated polyimides were prepared in a two‐step reaction in N‐methyl‐2‐pyrrolidinone (NMP) solution: The first step was for the synthesis of polyamic acids (PAAs) and the second reaction was for the imidization of PAA. The polymer yield was over 89% and the inherent viscosity of PAAs was in the range of 0.24–0.36 dL/g. The thin films were prepared by spin‐coating the PAA solution in NMP onto various substrates such as a Si wafer or a KBr pellet, dried at 80 °C and further cured at 230 °C. The resultant polyimides are thermally stable over 400 °C. The refractive index and birefringence of the resultant polyimides are 1.5858–1.6452 and 0.01–0.005, respectively. The refractive index of polyimide decreases with increasing the fluorine content. The copolymerization and the ether linkages into the backbone reduce the birefringence of polyimides. Surprisingly, the pendant ether linkage is not a crucial factor in reducing the polyimide birefringence. Their birefringence is comparatively very low, compared with that of previous polyimides. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1326–1342, 2006 相似文献