全文获取类型
收费全文 | 997篇 |
免费 | 15篇 |
国内免费 | 5篇 |
专业分类
化学 | 699篇 |
晶体学 | 14篇 |
力学 | 10篇 |
数学 | 74篇 |
物理学 | 220篇 |
出版年
2023年 | 6篇 |
2021年 | 7篇 |
2020年 | 6篇 |
2019年 | 11篇 |
2018年 | 6篇 |
2016年 | 14篇 |
2015年 | 9篇 |
2014年 | 14篇 |
2013年 | 43篇 |
2012年 | 29篇 |
2011年 | 46篇 |
2010年 | 22篇 |
2009年 | 32篇 |
2008年 | 41篇 |
2007年 | 57篇 |
2006年 | 75篇 |
2005年 | 67篇 |
2004年 | 35篇 |
2003年 | 43篇 |
2002年 | 37篇 |
2001年 | 25篇 |
2000年 | 24篇 |
1999年 | 19篇 |
1998年 | 11篇 |
1997年 | 11篇 |
1996年 | 16篇 |
1995年 | 20篇 |
1994年 | 11篇 |
1993年 | 9篇 |
1992年 | 24篇 |
1991年 | 9篇 |
1990年 | 19篇 |
1989年 | 13篇 |
1988年 | 17篇 |
1987年 | 15篇 |
1986年 | 11篇 |
1985年 | 10篇 |
1984年 | 16篇 |
1982年 | 14篇 |
1981年 | 6篇 |
1979年 | 15篇 |
1978年 | 19篇 |
1977年 | 18篇 |
1976年 | 6篇 |
1975年 | 5篇 |
1974年 | 8篇 |
1973年 | 5篇 |
1970年 | 5篇 |
1968年 | 4篇 |
1967年 | 5篇 |
排序方式: 共有1017条查询结果,搜索用时 46 毫秒
61.
Risa Fukuzumi Dr. Satoshi Kaneko Shintaro Fujii Prof. Tomoaki Nishino Dr. Manabu Kiguchi 《Chemphyschem》2020,21(4):274-274
The front cover artwork was provided by the group of Prof. Nishino, Tokyo Institute of Technology. The image depicts the investigation of the structure and electron transport of the Au, Ag, Cu, Ni, Fe, and Pd atomic junctions doped with dichloroethylene. Read the full text of the Article at 10.1002/cphc.201900988 . 相似文献
62.
An ITO electrode was coated by a Nafion film incorporating Ru(bpy)32+ complex as redox centers either by mixture casting method, adsorption method, or swelling method and the electrochemical reactivity of the modified electrode was determined by the in-situ spectrocyclic voltammogram (SCV) in a sodium perchlorate aqueous solution at pH 1.2. A modified Poisson statistics equation was used to estimate the charge transfer distance (Ro) between the Ru(bpy)32+ complexes. The estimated charge transfer distances for the electrodes prepared by swelling method (Ro = 1.63 nm for the electrode modified in M/W 1:10, and 1.69 nm in M/W 1:2) and adsorption method (Ro = 1.61 nm) were longer than that for mixture casting method (Ro = 1.5 nm). Based on the different procedure of Ru(bpy)32+ complex incorporation in the Nafion film, the reasons that affect the apparent charge transfer distance were discussed. 相似文献
63.
64.
Junko Fukutomi Yuko Adachi Akari Kaneko Atsuomi Kimura Hideaki Fujiwara 《Journal of inclusion phenomena and macrocyclic chemistry》2007,58(1-2):115-122
The inclusion complex formation of 4-sulfothiacalix[4]arene sodium salt (STCAS) and Xe has been investigated by using hyperpolarized
129Xe NMR spectroscopy. Our new continuous-flow type hyperpolarizing system has advantageous capabilities that can supply hyperpolarized
gases continuously and directly to a sample solution in a NMR tube. Consequently saturated Xe concentration in the aqueous
solution of STCAS is maintained during the NMR experiment, and 129Xe NMR spectra can be obtained in remarkably short time. STCAS concentration dependence of 129Xe chemical shift has been analyzed in an elaborated way by a computer method as well as a simple graphic method that we have
proposed. The association constant K:13.6±0.8 M−1 at 25 °C was obtained, and further analysis of the temperature dependence has successfully given thermodynamic parameters
of enthalpy (ΔH) and entropy (ΔS) for the inclusion complex formation: ΔH = −11.9±1.9 kJ mol−1 and ΔS = −17.4±5.8 JK−1 mol−1. The energetic aspects of complex formation are discussed from the size effect and from the molecular theory of standard
entropy, and a release of definite number of water molecules from STCAS cavity is suggested in the inclusion complex formation
with Xe. 相似文献
65.
Tozuka Z Kaneko H Shiraga T Mitani Y Beppu M Terashita S Kawamura A Kagayama A 《Journal of mass spectrometry : JMS》2003,38(8):793-808
Triple-stage quadrupole (TSQ) electrospray ionization (ESI) tandem mass spectrometry (MS/MS) and ion trap ESI-MS/MS can be used to cleave protonated molecules to produce carbocations and neutral molecules in the positive ion mode. Dissociation products which correspond to protonated forms of neutral fragment molecules can also be trapped and detected. These protonated molecules in turn can cleave via carbocation cleavage, ipso cleavage, onium cleavage or McLafferty or related rearrangements. One can elucidate the structures of metabolites from the differences in m/z ratios of the fragments arising from the original drug compound and its metabolite. This strategy for structural elucidation is further facilitated by estimates of the reactivity of drugs with oxygen diradicals involved in cytochrome P-450 cycles. 相似文献
66.
67.
68.
The pH dependencies of electrochemomechanical deformation (ECMD) including the cyclic voltammetry and the expansion ratio in conducting polymers, polyaniline (PANI), and poly(o-methoxyaniline) film were studied to elucidate the mechanisms. It was found that the ECMD is governed by the conformational change of polymer structure as well as the insertion of bulky ions in the manner of comparable magnitude. Expansion ratios >20% in the ECMD were demonstrated for the thickness direction of PANI film. The results suggest that the magnitude of ECMD can be improved by choosing the preparation method of films. 相似文献
69.
We study the correlation between CP violation in neutrino oscillations and leptogenesis in the framework with two heavy Majorana neutrinos and three light neutrinos. Among three unremovable CP phases, a heavy Majorana phase contributes to leptogenesis. We show how the heavy Majorana phase contributes to Jarlskog determinant J as well as neutrinoless double beta decay by identifying a low energy CP-violating phase which signals the CP-violating phase for leptogenesis. For some specific cases of the Dirac mass term of neutrinos, a direct relation between lepton number asymmetry and J is obtained. We also study the effect coming from the phases which are not related to leptogenesis. 相似文献
70.
Feng DL Damascelli A Shen KM Motoyama N Lu DH Eisaki H Shimizu K Shimoyama Ji JI Kishio K Kaneko N Greven M Gu GD Zhou XJ Kim C Ronning F Armitage NP Shen ZX 《Physical review letters》2002,88(10):107001
The low-energy electronic structure of the nearly optimally doped trilayer cuprate superconductor Bi(2)Sr(2)Ca(2)Cu(3)O(10+delta) is investigated by angle-resolved photoemission spectroscopy. The normal state quasiparticle dispersion and Fermi surface and the superconducting d-wave gap and coherence peak are observed and compared with those of single- and bilayer systems. We find that both the superconducting gap magnitude and the relative coherence-peak intensity scale linearly with T(c) for various optimally doped materials. 相似文献