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51.
Proteins with molecular mass (M(r)) <20 kDa are often poorly separated in 2-D sodium dodecyl sulfate polyacrylamide gel electrophoresis. In addition, low-M(r) proteins may not be readily identified using peptide mass fingerprinting (PMF) owing to the small number of peptides generated in tryptic digestion. In this work, we used a 2-D liquid separation method based on chromatofocusing and non-porous silica reversed-phase high-performance liquid chromatography to purify proteins for matrix-assisted laser desorption/ionization time-of-flight mass spectrometric (MALDI-TOFMS) analysis and protein identification. Several proteins were identified using the PMF method where the result was supported using an accurate M(r) value obtained from electrospray ionization TOFMS. However, many proteins were not identified owing to an insufficient number of peptides observed in the MALDI-TOF experiments. The small number of peptides detected in MALDI-TOFMS can result from internal fragmentation, the few arginines in its sequence and incomplete tryptic digestion. MALDI-QTOFMS/MS can be used to identify many of these proteins. The accurate experimental M(r) and pI confirm identification and aid in identifying post-translational modifications such as truncations and acetylations. In some cases, high-quality MS/MS data obtained from the MALDI-QTOF spectrometer overcome preferential cleavages and result in protein identification. 相似文献
52.
Zhao J Zhang Y Kan Y Zhu L 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2004,60(3):679-688
The vibrational spectra of Group IIB elements halides MX2 and their dimers M2X4 (M=Zn(II), Cd(II) and Hg(II); X=F, Cl, Br and I) have been systematically investigated by ab initio RHF and B3LYP methods with LanL2MB, LanL2DZ and SDD basis sets. The optimized geometries, calculated vibrational frequencies are evaluated via comparison with the experimental data. The vibrational frequencies, calculated by these methods with different basis sets, are compared to each other too. The best results can be obtained by RHF/SDD method, with this method, the deviations for MX2 and Hg2X4 are <7%. Some vibrational frequencies of M2X4 that have not been experimentally reported are also predicted. 相似文献
53.
Hong‐Ze Gao Zhong‐Min Su Chun‐Sheng Qin Ri‐Gen Mo Yu‐He Kan 《International journal of quantum chemistry》2004,97(6):992-1001
Bis(2‐methyl‐8‐quinolinolato)aluminum(III) hydroxide complex (AlMq2OH) is used in organic light‐emitting diodes (OLEDs) as an electron transport material and emitting layer. By means of ab initio Hartree–Fock (HF) and density functional theory (DFT) B3LYP methods, the structure of AlMq2OH was optimized. The frontier molecular orbital characteristics and energy levels of AlMq2OH have been analyzed systematically to study the electronic transition mechanism in AlMq2OH. For comparison and calibration, bis(8‐quinolinolato)aluminum(III) hydroxide complex (Alq2OH) has also been examined with these methods using the same basis sets. The lowest singlet excited state (S1) of AlMq2OH has been studied by the singles configuration interaction (CIS) method and time‐dependent DFT (TD‐DFT) using a hybrid functional, B3‐LYP, and the 6‐31G* basis set. The lowest singlet electronic transition (S0 → S1) of AlMq2OH is π → π* electronic transitions and primarily localized on the different quinolate ligands. The emission of AlMq2OH is due to the electron transitions from a phenoxide donor to a pyridyl acceptor from another quinolate ligand including C → C and O → N transference. Two possible electron transfer pathways are presented, one by carbon, oxygen, and nitrogen atoms and the other via metal cation Al3+. The comparison between the CIS‐optimized excited‐state structure with the HF ground‐state structure indicates that the geometric shift is mainly confined to the one quinolate and these changes can be easily understood in terms of the nodal patterns of the highest occupied and lowest unoccupied molecular orbitals. On the basis of the CIS‐optimized structure of the excited state, TD‐B3‐LYP calculations predict an emission wavelength of 499.78 nm. An absorption wavelength at 380.79 nm on the optimized structure of B3LYP/6‐31G* was predicted. They are comparable to AlMq2OH 485 and 390 nm observed experimentally for photoluminescence and UV‐vis absorption spectra of AlMq2OH solid thin film on quartz, respectively. Lending theoretical corroboration to recent experimental observations and supposition, the reasons for the blue‐shift of AlMq2OH were revealed. © 2003 Wiley Periodicals, Inc. Int J Quantum Chem, 2004 相似文献
54.
A series of 4‐[2‐(alicyclic‐[1,2,4]oxadiazol‐3‐yl)phenoxy]‐butyric acids were synthesized from N‐hydroxy‐2‐isopropoxy benzamidine in 4 steps with good yields. These [1,2,4]oxadiazoles are novel platelet aggregation inhibitors preventing human platelet aggregation induced by thromboxane derivative U44,619 and adenosine diphosphate. A structure‐activity‐relationship study revealed that the potency for these 5‐oxadiazoles increases with the increase in the ring size of the alicylic rings. Derivative 8f may be useful as a template for the design of more potent anti‐platelet agents. 相似文献
55.
随着杂原子分子筛研究领域的开拓与发展,近年来,对钛硅沸石的研究逐渐增多.Ti-ZSM-11(TS-2)型分子筛是由Reddy,Ratanasarny等[1]首先合成的.钛硅沸石的表征与其它杂原子分子筛相比较为复杂,对杂原子Ti是否进入了骨架还没有一个直接的证据,且争议较多.在红外光谱的研究中,对960cm-1-980cm-1区间的特征吸收的归属也存在着很大的分歧[2-4].钛硅沸石在H2O2对有机化合物的选择氧化领域有极其优良的催化性能[1],因此,对它的开发有广泛的应用前景.本文以动态和静态相结合的水热晶化法合成了Ti-ZSM-11型分子筛.IR光… 相似文献
56.
Kangli Min Fengzhen Huang Xiaomei Lu Yi Kan Junting Zhang Song Peng Yaoyang Liu Jie Su Chao Zhang Zijian Liu Jinsong Zhu 《Solid State Communications》2012,152(4):304-306
KNb0.95Co0.05O3 (KN–Co) ceramic was prepared via a solid-state reaction method, and the effect of cobalt dopant on the structural, electric, and magnetic properties was studied. The KN–Co ceramic with polycrystalline perovskite structure exhibited ferromagnetic and ferroelectric properties simultaneously at room temperature, and the coupling of them was confirmed by a large magnetocapacitance effect (about 13%) near the Curie temperature. The possible causes for the magnetism and magnetoelectric properties are discussed. 相似文献
57.
A series of 4-[(4-n-polyfluoroalkoxy-2,3,5,6-tetrafluorophenyl)ethynyl]phenyl fluoro-substituted benzoate liquid crystals have been synthesized. Their phase transition temperatures have been measured by optical polarizing microscopy and confirmed by DSC. The results show that a highly fluorinated terminal chain impairs mesomorphic properties. 相似文献
58.
A series of 4-(4-n-heptoxy-2,3-difluorophenylethynyl)phenyl 3-nitro-4-polyfluoroalkoxybenzoate liquid crystals was synthesized and their phase transition behaviours were studied by optical polarizing microscopy and DSC. The results show that the mesogens containing long polyfluoroalkoxy chain tend to exhibit the smectic A phase. 相似文献
59.
Kei Fujise Dr. Eiji Tsurumaki Prof. Dr. Kan Wakamatsu Prof. Dr. Shinji Toyota 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(14):4548-4552
Polycyclic aromatic compounds consisting of four or five fused anthracene units were synthesized by PtCl2-catalyzed cycloisomerization as novel long expanded helicenes. These compounds have helical structures with significant stacking of the terminal anthracene moieties at 0.33 nm interlayer distance. In the UV-vis and fluorescence spectra, the absorption and emission bands were red-shifted as the number of fused anthracene units was increased. The characteristic broad and long-lived emission bands of the long analogues are explained by the excimer-like stabilization of the excited state. These photophysical data as well as their cyclic voltammetric data are discussed on the basis of the π-conjugation and interlayer π⋅⋅⋅π interactions in the molecular structures and the molecular orbitals. The barrier and mechanism of helical inversion are also reported. 相似文献
60.
Two resorcyl di[4-(4-alkoxy-2,3-difluorophenyl)ethynyl]benzoate liquid crystals were prepared and their mesomorphic properties observed and measured. Achiral antiferroelectric phases were seen with increasing length of the hydrocarbon terminal chains. 相似文献