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排序方式: 共有273条查询结果,搜索用时 250 毫秒
61.
M. Anikina V. Aksinenko E. Dementiev M. Gaździcki N. Glagoleva A. Golokhvastov L. Goncharova A. Grachov K. Iovchev S. Kadykova N. Kaminsky S. Khorozov E. Kuznetsova J. Lukstins A. Matyushin V. Matyushin E. Okonov T. Ostanevich E. Shevchenko S. Sidorin G. Vardenga O. Balea N. Nikorovich T. Ponta L. Chkhaidze T. Dzobava M. Destpotashvili I. Tuliani E. Khusainov N. Nurgozin B. Suleimanov E. Skrzypczak T. Tymieniecka 《Zeitschrift fur Physik C Particles and Fields》1984,25(1):1-11
Data on Λ's andK 0's, produced in central nucleus-nucleus collisions (C?C, C?Ne, O?Ne, C?Cu, C?Zr, C?Pb, O?Pb) at a 4.5 GeV/c momentum per incident nucleon obtained in the streamer chamber spectrometer SKM-200, are presented. Multiplicities, transverse momenta, rapidities and other characteristics are considered and compared with those for inelastic He?Li interactions. The polarization of Λ's was found to be consistent with zero. The upper limit of \(\bar \Lambda /\Lambda \) production ratio was estimated to be ≤10?2 with a 90% confidence level. The results are compared with data of other experiments and some model calculations. 相似文献
62.
63.
Liao Y Eichinger BE Firestone KA Haller M Luo J Kaminsky W Benedict JB Reid PJ Jen AK Dalton LR Robinson BH 《Journal of the American Chemical Society》2005,127(8):2758-2766
A series of novel nonlinear optical (NLO) chromophores 1-4 incorporating the ferrocenyl (Fc) group as an electron donor and 2-dicyanomethylene-3-cyano-4-methyl-2,5-dihydrofuran (TCF) derivatives as electron acceptors are presented. The use of a constant Fc donor and varied acceptors and bridges makes it possible to systematically determine the contribution of the conjugated bridge and the acceptor strength to chromophore nonlinear optical activity. The X-ray crystal structures of all four chromophores allow for the systematic investigation of the structure-property relationship for this class of molecules. For example, the crystal structures reveal that both cyclopentadienyl groups in the ferrocenyl donor contribute to the electron donating ability. The first-order hyperpolarizabilities beta of these chromophores, measured by hyper-Rayleigh scattering (HRS) relative to p-nitroaniline are reported. These beta values are compared to those calculated by density functional theory (DFT). The excellent agreement between the theoretical and experimental beta values demonstrates that a linear relation exists between the hyperpolarizability and the bond length alternation. An electrooptic coefficient, r(33), of approximately 25 pm/V at 1300 nm, for compound 4, incorporated into a polymer matrix, is competitive with organic chromophores. Moreover, this r(33) is more than 30 times larger than the previously reported value for an organometallic chromophore in a poled polymer matrix. This work not only underscores the potential for Fc donor moieties, which have been underutilized, but also demonstrates that experimental characterization and theoretical simulations are now congruent, viable methods for assessing potential performance of NLO materials. 相似文献
64.
Vladimir Kaminsky Michael Buback Mark Egorov 《Macromolecular theory and simulations》2002,11(2):128-135
The effects of non‐ideal initiator decomposition, i.e., decomposition into two primary radicals of different reactivity toward the monomer, and of primary radical termination, on the kinetics of steady‐state free‐radical polymerization are considered. Analytical expressions for the exponent n in the power‐law dependence of polymerization rate on initiation rate are derived for these two situations. Theory predicts that n should be below the classical value of 1/2. In the case of non‐ideal initiator decomposition, n decreases with the size of the dimensionless parameter α ≡ (ktz /kdz) √rinkt, where ktz is the termination rate coefficient for the reaction of a non‐propagating primary radical with a macroradical, kdz is the first‐order decomposition rate coefficient of non‐propagating (passive) radicals, rin is initiation rate, and kt is the termination rate coefficient of two active radicals. In the case of primary radical termination, n decreases with the size of the dimensionless parameter β ≡ kt,s rin1/2/kp,s M rt,l1/2, where kt,s is the termination rate coefficients for the reaction of a primary (“short”) radical with a macroradical, kt,l is the termination rate coefficients of two large radicals, kp,s is the propagation rate coefficient of primary radicals and M is monomer concentration. As kt is deduced from coupled parameters such as kt /kp, the dependence of kp on chain length is also briefly discussed. This dependence is particularly pronounced at small chain lengths. Moreover, effects of chain transfer to monomer on n are discussed. 相似文献
65.
ZrIV and TaV Complexes with Methano‐Bridged Bis(aryloxy) Ligands The bis(aryloxy) ligand precursor compounds bis(2‐trimethylsiloxy‐5‐tbutylphenyl)methane (L–SiMe3) and its bromoderivative (2‐trimethylsiloxy‐3‐bromo‐5‐tbutylphenyl)(2′‐trimethylsiloxy‐5′‐tbutylphenyl)methane (LBr–SiMe3) are prepared in analogy to the corresponding calixarenes in excellent yields. X‐ray structure analysis for LBr–SiMe3: space group P21/c, a = 12.462(7), b = 10.466(6), c = 23.315(14) Å, β = 105.02(4)°, V = 2937(3) Å3, Z = 4. L–SiMe3 and LBr–SiMe3 react with ZrIV and TaV chlorides in very good yields forming di‐ and trinuclear complexes. From the reaction of CpZrCl3 with LBr–SiMe3 in the ratio of 3 : 2 a Zr3 complex ( 7 ) is obtained, with one LBr ligand only, which Zr atoms are bridged by a μ3‐oxygen. The X‐ray structure analysis of 7 (space group R 3, a = 33.23(6), c = 24.47(8) Å, V = 23405(128) Å3, Z = 18) additionally reveals that one phenolato oxygen atom of the LBr ligand is terminally bound to a distorted tetragonal‐pyramidal coordinated Zr atom, while the second phenolato oxygen atom of the LBr ligand forms a bridge to another Zr atom with a distorted octahedral coordination. The third Zr atom is also found in a distorted octahedral coordination mode. The reactions of L–SiMe3 and LBr–SiMe3 with CpTaCl4 and TaCl5 yield dinuclear Ta complexes with a bridging bis(aryloxy) ligand. NMR spectroscopic data point out that the coordination of the bis(aryloxy) ligands in the Ta complexes very much resembles that in the Zr3‐complex with one terminal and one bridging phenolato oxygen atom. The Zr3 and the Ta complexes LBrTa2Cp2Cl6 and LTa2Cl8 were tested with respect to their catalytic properties in olefin polymerisation reactions in the presence of MAO. 相似文献
66.
Walter Kaminsky Christian Strübel Hans Lechert Dieter Genske Seong Ihl Woo 《Macromolecular rapid communications》2000,21(13):909-912
Mesoporous aluminosilicates – type MCM‐41 – were used as carriers for syndiospecific propene polymerisation using [Me2C(Cp)(Flu)]ZrCl2/MAO as catalyst. Alumina‐free mesoporous MCM‐41 reveals a far greater polymerisation activity than the analogous carrier containing alumina. The use of MCM‐41 as carrier material at low propene concentration and high polymerisation temperature produces syndiotactic polypropene (sPP) with higher syndiotacticity and higher melting points than achieved when using a homogenous system or a supported system based on spherical SiO2. 相似文献
67.
68.
Amita Gupta Alexei Yu Ganin Parmanand Sharma Vikrant Agnihotri LM Belova KV Rao Mikhail E Kozlov AA Zakhidov RH Baughman 《Pramana》2002,58(5-6):1051-1059
We present studies of novel nanocomposites of BiNi impregnated into the structure of opals as well as inverse opals. Atomic force microscopy and high resolution elemental analyses show
a highly ordered structure and uniform distribution of the BiNi filler in the matrix. These BiNi-based nanocomposites are
found to exhibit distinct ferromagnetic-like ordering with transition temperature of about 675 K. As far as we know there
exists no report in literature on any BiNi compound which is magnetic. 相似文献
69.
The probability W for the atomic ionization by nuclei as a function of the impact parameter x is expressed through the ionization matrix element Mif. Values of W(x) for K-shell ionization calculated with the first Born Mif are compared with the experimental data and other calculations. 相似文献