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11.
Direct and selective catalytic arylation of alpha-C-H bond in pyridine with iodobenzene was achieved in up to 70% yield. Phosphido-bridged bisruthenium complexes 6a and 6b arising from Ru3(CO)12 and PPh3 were identified as active catalysts. The formation of complexes 6a and 6b was investigated, a sequence of C-H and C-P bond cleavage, cluster fragmentation, and disproportionation was established, and the intermediate ruthenium complexes lying on this pathway were isolated and fully characterized. 相似文献
12.
Air/polymer distribution coefficients for polycyclic aromatic hydrocarbons by solid-phase microextraction sampling 总被引:2,自引:0,他引:2
Two methods to estimate distribution coefficients (K) between air and poly(dimethylsiloxane) (PDMS) coating of solid-phase microextraction (SPME) fibers for eight low molecular polycyclic aromatic hydrocarbons (PAHs) there are presented. The PDMS phases were used for determination of the coefficients according to equilibrium theory with help of a developed static calibration system (SCS). Another way to estimate the coefficients is based on the use of a linear relationship between the logarithm of the coefficients (log K) and linear temperature-programmed retention indexes (LTPRI) of the compounds without necessity to calibrate. The log K values for both of methods ranged from 5.2 (naphthalene) to 8.9 (pyrene) at 22 degrees C. Relative standard deviation (R.S.D.) of log K for each compound determined by static calibration was no more than 5.3%. R.S.D. of retention times for LTPRI indices did not exceed 0.28% for repeated injection. All experiments were implemented on a GC-MS system. 相似文献
13.
Herein, we report the first use of chiral alkaloid brucine to synthesize novel porphyrin-brucine conjugate capable of acting as a gelator of methanol and acetonitrile at extremely low level of concentration. The synthesis, characterization and spectral properties of gelator based on a novel structural motif, quaternized alkaloid conjugates, are described. Different spectroscopic methods (1H NMR spectroscopy, Raman and infrared spectroscopy, and spectroscopy of electronic and vibrational circular dichroism) were used for characterization of the prepared organogel. The aggregation of the gelator studied by UV-vis spectroscopy and electronic circular dichroism showed the formation of chiral J-aggregates in water and water-methanol (1:1) mixture. A new methodology for the determination of functional groups involved in gel formation based on vibrational circular dichroism is presented. 相似文献
14.
A new method is proposed for the synthesis of pitch-based carbons with bimodal distribution of uniform mesopores formed by co-imprinting of spherical silica colloids and hexagonally ordered mesoporous particles of SBA-15 into mesophase pitch particles and subsequent silica dissolution. 相似文献
15.
Continuous chemiluminescence determination of formaldehyde in air based on Trautz-Schorigin reaction 总被引:1,自引:0,他引:1
A new continuous method for the determination of formaldehyde in air is described. A cylindrical wet effluent diffusion denuder is used for the collection of formaldehyde from air into a thin film of absorption liquid (distilled-deionized water). Formaldehyde in the denuder concentrate is on-line detected employing a chemiluminescence flow method based on a reaction of formaldehyde and gallic acid with hydrogen peroxide in an alkaline solution. The collection efficiency of formaldehyde is quantitative at the air flow rate of 0.5 L min−1 (absorption liquid flow rate of 336 μL min−1). The limit of detection (S/N = 3) is 0.60 μg m−3 HCHO (0.49 ppb). The calibration graph is linear up to 300 μg m−3 HCHO (244 ppb). The relative standard deviations of chemiluminescence method for 1 × 10−6 and 5 × 10−6 M HCHO are 2.87% and 1.49%, respectively. Acetaldehyde interferes negligible, other compounds do not interfere. The method was employed for formaldehyde measurement in ambient air. The comparison measurement illustrates the good agreement of results obtained by proposed method with those obtained by reference fluorimetric method. 相似文献
16.
A new approach is developed for estimating the limit of detection in second-order bilinear calibration with the generalized rank annihilation method (GRAM). The proposed estimator is based on recently derived expressions for prediction variance and bias. It follows the latest IUPAC recommendations in the sense that it concisely accounts for the probabilities of committing both types I and II errors, i.e. false positive and false negative declarations, respectively. The estimator has been extensively validated with simulated data, yielding promising results. 相似文献
17.
Kubát P Lang K Janda P Anzenbacher P 《Langmuir : the ACS journal of surfaces and colloids》2005,21(21):9714-9720
The interaction between self-aggregated porphyrins such as 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS) and 5,10,15,20-tetrakis(4-phosphonatophenyl)porphyrin (TPPP), and a generation 5 (G5) PAMAM dendrimer template is governed by minute differences of porphyrin acido-basic properties. While at neutral pH both monomeric TPPS and TPPP form complexes with G5, decreasing pH did not lead to porphyrin ring protonation (pK(a) approximately 5) but rather to the preferential formation of H-aggregates (probably H-dimers), most likely due to protonation of the G5. Upon further acidification of the solution, this face-to-face orientation of the porphyrin units is being converted to edge-to-edge aligned J-aggregates with a tightly defined structure. This process starts by protonation of the porphyrin ring at pH below 2.3 and 2.8 for TPPS and TPPP, respectively. The AFM imaging of porphyrin/G5 nanostructures obtained at pH 0.7 shows the formation of long nanorods of TPPS with partially aggregated G5 and small aggregates of TPPP connected to individual G5 molecules. 相似文献
18.
Kamil Walczak 《Central European Journal of Chemistry》2004,2(3):524-533
An analytical approach to the electron transport phenomena in molecular devices is presented. The analyzed devices are composed
of various molecular bridges attached to two semi-infinite electrodes. Molecular system is described within the tight-binding
model, while the coupling to the electrodes is analyzed through the use of Newns-Anderson chemisorption theory. The current-voltage
(I-V) characteristics are calculated through the integration of transmission function in the standard Landauer formulation.
The essential question of quantum interference effect of electron waves is diseussed in three aspects: (i) the geometry of
a molecular bridge, (ii) the presence of an external magnetic field and (iii) the location of chemical substituent. 相似文献
19.
A theoretical analysis of inelastic electron tunneling spectroscopy (IETS) experiments conducted on molecular junctions is presented, where the second derivative of the current with respect to voltage is usually plotted as a function of applied bias. Within the nonperturbative computational scheme, adequate for arbitrary parameters of the model, we consider the virtual conduction process in the off-resonance region. Here we study the influence of few crucial factors on the IETS spectra: the strength of the vibronic coupling, the phonon energy, and the device working temperature. It was also shown that weak asymmetry in the IETS signal with respect to bias polarity is obtained as a result of strongly asymmetric connection with the electrodes. 相似文献
20.
Stefan Mommer Kamil Sokoowski Magdalena Olesiska Zehuan Huang Oren A. Scherman 《Chemical science》2022,13(30):8791
Extended polymeric structures based on redox-active species are of great interest in emerging technologies related to energy conversion and storage. However, redox-active monomers tend to inhibit radical polymerisation processes and hence, increase polydispersity and reduce the average molecular weight of the resultant polymers. Here, we demonstrate that styrenic viologens, which do not undergo radical polymerisation effectively on their own, can be readily copolymerised in the presence of cucurbit[n]uril (CB[n]) macrocycles. The presented strategy relies on pre-encapsulation of the viologen monomers within the molecular cavities of the CB[n] macrocycle. Upon polymerisation, the molecular weight of the resultant polymer was found to be an order of magnitude higher and the polydispersity reduced 5-fold. The mechanism responsible for this enhancement was unveiled through comprehensive spectroscopic and electrochemical studies. A combination of solubilisation/stabilisation of reduced viologen species as well as protection of the parent viologens against reduction gives rise to the higher molar masses and reduced polydispersities. The presented study highlights the potential of CB[n]-based host–guest chemistry to control both the redox behavior of monomers as well as the kinetics of their radical polymerisation, which will open up new opportunities across myriad fields.Extended polymeric structures based on redox-active species are of great interest in emerging technologies related to energy conversion and storage.Polyviologens are redox-active polymers based on N-substituted bipyridinium derivatives which have emerged as promising materials for energy conversion and storage.1–5 Their physicochemical properties can be adjusted through copolymerisation of the redox-active viologen monomers.6–8 The resultant materials are stable, water soluble and exhibit fast electron transfer kinetics. Polyviologens have been commonly fabricated through step-growth polymerisation in linear and dendritic architectures,9–13 as supramolecular polymers,14–16 networks,6,17,18 and covalent organic frameworks.19,20 Alternatively, anionic/cationic or metathesis-based polymerisations are used to avoid interference of radical-stabilising monomers with the radical initiators, however, these techniques are highly water- and/or oxygen-sensitive.21,22 When free-radical polymerisation (FRP) is conducted in the presence of viologen species, its reduction can cause a depletion of active radicals and thus disruption of the polymerisation process. Despite varying solvents, comonomers and initiator loadings, the direct FRP of viologen-containing monomers remains therefore limited to molar masses of 30 kDa.23–25 Accessing higher molar masses has been possible via post-polymerisation modification,26–28 which has impacted the electrochemical properties of the resultant materials.29,30 Alternative strategies to access higher molar masses of redox-active polymers and control their polymerisation are highly desirable.Incorporation of cucurbit[n]uril (CB[n]) macrocycles have lead to a variety of functional materials through host–guest chemistry.31–34 Moreover, the redox chemistry of viologens can be modulated through complexation with CB[n].35–38 Specifically, CB[n] (n = 7, 8) can tune the redox potential of pristine viologens and efficiently sequester monoreduced viologen radical cations, avoiding precipitation in aqueous environments. Further to this, we recently demonstrated that the viologen radical cation is stabilised by −20 kcal mol−1 when encapsulated in CB[7].39Consequently, we envisioned that incorporating CB[n]s as additives prior to polymerisation could (i) overcome current limits in accessible molar masses, (ii) increase control over FRP of viologen-based monomers through encapsulation and (iii) enable separation of radical species avoiding aggregation.Here, we demonstrate a new approach to control FRP of redox-active monomers leading to high molar masses and decreased dispersity of the resultant polymers. In absence of CB[n], co-polymerisation of the N-styryl-N′-phenyl viologen monomer 12+ and N,N-dimethylacrylamide (DMAAm) only occurs at high initiator loadings (>0.5 mol%, Fig. 1a), leading to low molecular weights and high polydispersity. Using our synthetic approach, 12+ is efficiently copolymerised with DMAAm in the presence of CB[n] (n = 7, 8) macrocycles resulting in control of the polymer molar mass across a broad range, 4–500 kDa (Fig. 1b). Finally, CB[n] are successfully removed from the polymer via competitive host–guest binding and dialysis. Spectroscopic and electrochemical studies revealed that solubilisation/stabilisation of the reduced species and/or shielding of the redox-active monomers from electron transfer processes was responsible for this enhancement.Open in a separate windowFig. 1Schematic representation of the investigated polymerisation. (a) Conventional free radical polymerisation either completely fails to copolymerise redox-active monomers (low initiator loading) or delivers copolymers with limited molar masses and high dispersities (high initiator loading). (b) CB[n]-mediated protection suppresses interference of viologen monomers with radicals formed through the initiation process facilitating copolymerisation. The molar mass of the resulting copolymers is readily tunable via the amount of present CB[n] macrocycles and the CB[n] is post-synthetically removed via competitive binding to yield the final copolymer with desired molar mass. Cl− counter-ions are omitted for clarity.Recent studies on symmetric aryl viologens demonstrated 2 : 2 binding modes with CB[8] and high binding constants (up to Ka ∼ 1011 M−2).40,41 Incorporation of polymerisable vinyl moieties, in combination with the relatively static structure of their CB[n] host–guest complexes, was postulated to allow polymerisation without unfavorable side reactions. The asymmetric N-styryl-N′-phenyl viologen monomer 12+ prepared for this study (Fig. S1a and S2–S13†) displays a linear geometry and was predicted to bind CB[n] (n = 7, 8) in a 2 : 1 and 2 : 2 binding fashion (Fig. S1b†).40,42 Binding modes between CB[n] (n = 7, 8) and 12+ were investigated through titration experiments (1H NMR and ITC) which confirmed the formation of 1·(CB[7])2 and (1)2·(CB[8])2 (see Fig. S25 and S26†). 1H NMR titration of CB[7] with 12+ demonstrates encapsulation of both aryl moieties (including the vinyl group) through upfield chemical shifts of the respective signals (Fig. 2a). Similar upfield shifts were observed for CB[8] (Fig. 2c). Different para-aryl substituents (vinyl vs. hydrogen) resulted in either head-to-tail or head-to-head (1)2·(CB[8])2 dimers (Fig. S1b and S26†), a previously reported phenomenon.43 Nonetheless, the reversible nature of the complex renders the vinyl group temporarily available for copolymerisation. In the presence of CB[8], 12+ yields polymer molar masses of up to 500 kDa as its complexation is more robust. ITC data confirmed binding stoichiometry, with binding constants of Ka = 2.64 × 106 M−1 for 1·(CB[7])2 and Ka = 9.02 × 1010 M−2 for (1)2·(CB[8])2 (Table S2, Fig. S29a and b†).Open in a separate windowFig. 2Supramolecular complexation of 12+ and CB[n]. 1H NMR spectra of 12+ at (a) χCB[7] = 2, (b) χCB[n] = 0 and (c) χCB[8] = 1 in D2O. Cl− counter-ions are omitted for clarity.The free radical copolymerisation of 12+ and DMAAm ([M] = 2 M), in the absence of CB[n], was based on optimised DMAAm homopolymerisations (Fig. S14 and S15†) and full conversion was confirmed by 1H NMR spectroscopy (Table S1 and Fig. S16†). 12+ was maintained at 1 mol% relative to DMAAm and by varying the radical initiator concentration molar masses of up to 30 kDa with broad dispersities (Đ = 11.4) were obtained (Fig. S17†). Lower initiator concentrations (<0.25 mol%) limited polymerisation (Mn = 3.7 kDa) and size exclusion chromatography elution peaks exhibited extensive tailing, suggesting that 12+ engages in radical transfer processes.To verify our hypothesis that CB[n] macrocycles can modulate the redox behavior of 12+, FRP of 12+ and DMAAm was conducted with varying amounts of CB[n] (n = 7, 8) (Fig. 3, S18 and S20†). Full conversion of all monomers including their successful incorporation into the polymer was verified via1H NMR spectroscopy and SEC (Fig. S18 and S21–S23†). Using CB[7], the molar mass of the copolymers was tunable between Mn = 3.7–160 kDa (Fig. 3b and S21a†). Importantly, in the presence of CB[8], a broad range of molar masses Mn = 3.7–500 kDa were accessible for 0 < χCB[8] < 1.2 (Fig. S20 and S21b†). Increasing the CB[n] (n = 7, 8) concentration caused dispersity values to converge to Đ = 2.2 (χCB[8] = 1.2, χ is the ratio of CB[n] to the redox-active monomer, Fig. S20†). The copolymers were purified by addition of adamantylamine (competitive binder) prior to dialysis to deliver CB[n]-free redox-active copolymers (Fig. S23†).Open in a separate windowFig. 3(a) In situ copolymerisation of DMAAm with 12+ and CB[7]. (b) Molar mass and dispersity vs. amount of CB[7] in the system. Fitted curve is drawn to guide the eye. Cl− counter-ions are omitted for clarity.The range of molar masses obtainable through addition of CB[n] (n = 7, 8) correlated with the measured Ka (Fig. 3b and S20†). Binding of 12+ to CB[8] was stronger and therefore lower concentrations of CB[8] were required to shift the binding equilibrium and mitigate disruption of the polymerisation. Dispersity values reached a maximum at χCB[7] = 0.6 or χCB[8] = 0.3, suggesting 1+˙ is only partially encapsulated. Consequently, higher CB[n] concentrations can enable FRP with lower initiator concentrations (0.10 mol%, Fig. S19†), which demonstrates the major role of complexation to modulate electron accepting properties of 12+.The redox-active monomer 12+ can engage with propagating primary radicals (Pm˙) to either be incorporated into the growing polymer chain (Pm–12+˙) or to abstract an electron deactivating it (Pm). This deactivation likely occurs through oxidative termination producing 1+˙ (energetic sink), inactive oligo- and/or polymer chains (Pm) and a proton H+, causing retardation of the overall polymerisation. Oxidative terminations have been previously observed in aqueous polymerisations of methyl methacrylate, styrenes and acrylonitriles that make use of redox initiator systems.44–47 Another example by Das et al. investigated the use of methylene blue as a retarder, with the primary radical being transferred to a methylene blue electron acceptor via oxidative termination, altogether supporting the outlined mechanism of our system (extended discussion see ESI, Section 1.4†).48The process of retardation can, however, be successfully suppressed, when monomer 12+ is encapsulated within CB[n] macrocycles. Herein the formation of 1·(CB[7])2 or (1)2·(CB[8])2 results in shielding of the redox-active component of 12+ from other radicals within the system, hampering other electron transfer reactions. This inhibits termination and results in extended polymerisation processes leading to higher molar mass polymers through mitigation of radical transfer reactions. Moreover, suppressing the formation of 1+˙ through supramolecular encapsulation minimises both π and σ dimerisation of the emerging viologen radical species,39 preventing any further reactions that could impact the molar mass or polydispersity of the resulting polymers.Cyclic voltammetry (CV) and UV-Vis titration experiments were conducted to provide insight into the impact of CB[n] on the redox behavior and control over FRP of 12+. Excess of CB[n] (n = 7, 8) towards 12+ resulted in a complete suppression of electron transfer processes (Fig. S31 and S32†). Initially, 12+ shows a quasi-reversible reduction wave at −0.44 V forming 1+˙ (Fig. 4a). Increasing χCB[7], this reduction peak decreases and shifts towards more negative potentials (−0.51 V, χCB[7] = 1) accompanied by the formation of 12+·(CB[7])1. A second cathodic peak emerges at −0.75 V due to the increased formation of 12+·(CB[7])2. At χCB[7] = 2, this peak shifts to −0.80 V, where it reaches maximum intensity, once 12+·(CB[7])2 is the dominating species in solution. When 2 < χCB[7] < 4, the intensity of the reduction peak decreases and the complexation equilibrium is shifted towards the bound state, complete suppression of the reduction peak occurs at χCB[7] = 4. Similarly, the oxidation wave intensity is reduced by 95% at χCB[7] = 4 causing suppression of potential oxidative radical transfer processes (Fig. 4c).Open in a separate windowFig. 4Mechanism of the CB[n]-mediated (n = 7, 8) strategy for the controlled copolymerisation of redox-active monomer 12+. (a) Cyclic voltammogram with varying amounts of CB[7]. (b) UV-Vis titration of 12+ with varying amounts of CB[7]. (c) Intensity decay of the oxidation peak at −0.27 V and change in absorption maximum of 1+˙ at 590 nm vs. χCB[7]. (d) Electron transfer processes of 12+ to generate 1+˙ and 10. (e) Reduction of 12+ resulting in precipitation of 10. (f) Stabilisation of 1+˙ through encapsulation with CB[7]. (g) Protection of 12+ from redox processes through CB[7]-mediated encapsulation.The concentration of 1+˙ can be monitored using UV-Vis (Fig. 4b and S34†).49 Absorbance at 590 nm (λmax) vs. χCB[7] was plotted and the concentration of 1+˙ increases, reaching a maximum at χCB[7] = 4 (Fig. 4c). When χCB[7] > 4, a decrease in concentration of 1+˙ was observed. We postulate the following mechanism: at χCB[7] = 0, 12+ is reduced to produce high concentrations of 1+˙ that partially disproportionates to form 10, which precipitates (Fig. 4e and S34†). When 0 < χCB[7] < 4, increasing amounts of green 1+˙ are stabilised through encapsulation within CB[7] suppressing disproportionation (Fig. 4c (cuvette pictures), Fig. 4f). For χCB[7] > 4, 12+ is protected from reduction through encapsulation (Fig. 4g).To further demonstrate applicability of this strategy, we chose another viologen-based monomer 22+ for copolymerisation (Fig. 5a). As opposed to 12+, CB binds predominantly to the styryl moiety of 22+ (Fig. S27 and S28†).50 ITC data showed that 22+ binds CB[7] in a 1 : 1 fashion with a binding affinity of Ka = 2.32 × 106 M−1 (Fig. S30 and Table S2†). Monomer 22+ was also analysed via CV and showed three reversible reduction waves at −0.91 V, −0.61 V (viologen) and 0.40 V (styrene). Similar to 12+, excess CB[7] selectively protects the molecule from redox processes, while the vinyl moiety remains accessible (Fig. 5a, S33c and d†). For CB[8], only partial suppression of electron transfer processes was observed (Fig. S33e and f†). We therefore chose CB[7] as an additive to increase control over FRP of 22+ (Fig. 5b). Copolymerisation of 22+ (1 mol%) and DMAAm ([M] = 2 M) at χCB[7] = 0 resulted in Mn = 28 kDa. When χCB[7] = 0.1, 0.2 or 0.3, Mn increased gradually from 124 to 230 and 313 kDa, respectively, demonstrating the potential of this strategy for FRP of redox-active monomers. Higher percentages of CB[7] led to copolymers with presumably higher molar masses causing a drastic decrease in solubility that prevented further analysis. Investigations on a broader spectrum of such copolymers, including those with higher contents of 22+ are currently ongoing.Open in a separate windowFig. 5(a) Cyclic voltammogram of viologen-containing monomer 22+ and its complexation with CB[n] (n = 7, 8) at a concentration of 1 mM using a scan rate of 10 mV s−1 in 0.1 mM NaCl solution. (b) Molar mass and dispersity of 22+-containing copolymers vs. equivalents of CB[7]. Cl− counter-ions are omitted for clarity.In conclusion, we report a supramolecular strategy to induce control over the free radical polymerisation of redox-active building blocks, unlocking high molar masses and reducing polydispersity of the resulting polymers. Through the use of CB[n] macrocycles (n = 7, 8) for the copolymerisation of styrenic viologen 12+, a broad range of molar masses between 3.7–500 kDa becomes accessible. Our mechanistic investigations elucidated that the redox behavior of monomer 12+ is dominated by either CB[n]-mediated stabilisation of monoradical cationic species or protection of the encapsulated pyridinium species from reduction. In the stabilisation regime (χCB[7] < 4), 12+ is reduced to form the radical cation 1+˙, which is subsequently stabilised through CB[7] encapsulation. Upon reaching a critical concentration of CB[7] (χCB[7] > 4), the system enters a protection-dominated regime, where reduction of 12+ is suppressed and the concentration of 1+˙ diminishes. The resulting copolymers can be purified by use of a competitive binder to remove CB[n] macrocycles from the product. This strategy was successfully translated to a structurally different redox-active monomer that suffered similar limitations. We believe that the reported strategy of copolymerisation of redox-active monomers will open new avenues in the synthesis of functional materials for energy conversion and storage as well as for applications in electrochromic devices and (nano)electronics. 相似文献