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41.
42.
The reactions of p‐nitrophenyl acetate (PNPA) with a series of monopyridinium oximes, viz. 2‐PAM (2‐hydroxyiminomethyl‐1‐methylpyridinium iodide), 3‐PAM (3‐hydroxyiminomethyl‐1‐methylpyridinium iodide), and 4‐PAM (4‐hydroxyiminomethyl‐1‐methylpyridinium iodide) have been studied in the presence of cationic surfactants of same hydrophobic chain length (C16) within the concentration range of 0.5–6.0 mM at pH 8.0 under the pseudo‐first‐order condition. The observed rate constant (kobs) increases with increasing surfactant concentration culminating into a maximum, and this has been analyzed in detail following the concepts of micellar catalysis. The structure–activity relationship of the investigated oximes has been discussed, and 2‐PAM was found to be the most reactive among all the three investigated oximes for the cleavage of PNPA. Esterolytic decomposition of p‐nitrophenyldiphenyl phosphate with oximate ions (? CH?NO?) was followed in cetyltrimethylammonium bromide micelles at pH 9.0, and 4‐PAM was the most reactive oxime for the micellar hydrolysis of phosphate ester. The apparent acid dissociation constants (pKa) of the investigated oximes have been determined spectrophotometrically. © 2011 Wiley Periodicals, Inc. Int J Chem Kinet 43: 569–578, 2011 相似文献
43.
Krokovny P Abe K Abe K Abe T Adachi I Ahn BS Aihara H Akatsu M Asano Y Aso T Aulchenko V Aushev T Bakich AM Ban Y Banas E Bay A Bedny I Behera PK Bizjak I Bondar A Bozek A Bracko M Brodzicka J Browder TE Casey BC Chang P Chao Y Chen KF Cheon BG Chistov R Choi SK Choi Y Danilov M Dong LY Drutskoy A Eidelman S Eiges V Enari Y Everton CW Fang F Fukunaga C Gabyshev N Garmash A Gershon T Golob B Gordon A Guo R Haba J Hanagaki K Handa F Harada Y Hayashii H Hazumi M Heenan EM Higuchi T Hinz L Hojo T 《Physical review letters》2002,89(23):231804
We report the first observation of a B meson decay that is not accessible by a direct spectator process. The channel B(0)-->D(+)(s)K- is found in a sample of 85 x 10(6) BB; events, collected with the Belle detector at KEKB, with a branching fraction B(B(0)-->D(+)(s)K-)=(4.6(+1.2)(-1.1)+/-1.3) x 10(-5). We also obtain evidence for the B0-->D(+)(s)pi(-) decay with branching fraction B(B0-->D(+)(s)pi(-))=(2.4(+1.0)(-0.8)+/-0.7) x 10(-5). This value may be used to extract a model-dependent value of |V(ub)|. 相似文献
44.
Fang F Hojo T Abe K Abe K Abe T Adachi I Aihara H Akatsu M Asano Y Aso T Aulchenko V Bakich AM Ban Y Banas E Bay A Behera PK Bizjak I Bondar A Bozek A Bracko M Brodzicka J Browder TE Casey BC Chang P Chao Y Chen KF Cheon BG Chistov R Choi SK Choi Y Choi YK Danilov M Drutskoy A Eidelman S Eiges V Enari Y Fukunaga C Gabyshev N Garmash A Gershon T Golob B Hara T Hastings NC Hayashii H Hazumi M Heenan EM Higuchi T Hinz L Hokuue T Hoshi Y Hou WS Huang HC Igaki T Igarashi Y Iijima T Inami K 《Physical review letters》2003,90(7):071801
We report measurements of branching fractions for charged and neutral B-->eta(c)K decays where the eta(c) meson is reconstructed in the K(0)(S)K+/-pi(-/+), K+K-pi(0), K(*0)K-pi(+), and pp; decay channels. The neutral B0 channel is a CP eigenstate and can be used to measure the CP violation parameter sin(2phi(1). We also report the first observation of the B0-->eta(c)K(*0) mode. The results are based on an analysis of 29.1 fb(-1) of data collected by the Belle detector at KEKB. 相似文献
45.
In vivo mapping of functional domains and axonal connectivity in cat visual cortex using magnetic resonance imaging 总被引:5,自引:0,他引:5
Kim DS Kim M Ronen I Formisano E Kim KH Ugurbil K Mori S Goebel R 《Magnetic resonance imaging》2003,21(10):1131-1140
Noninvasive cognitive neuroimaging studies based on functional magnetic resonance imaging (fMRI) are of ever-increasing importance for basic and clinical neurosciences. The explanatory power of fMRI could be greatly expanded, however, if the pattern of the neuronal circuitry underlying functional activation could be made visible in an equally noninvasive manner. In this study, blood oxygenation level-dependent (BOLD)-based fMRI and diffusion tensor imaging (DTI) were performed in the same cat visual cortex, and the foci of fMRI activation utilized as seeding points for 3D DTI fiber reconstruction algorithms, thus providing the map of the axonal circuitry underlying visual information processing. The methods developed in this study will lay the foundation for in vivo neuroanatomy and the ability for noninvasive longitudinal studies of brain development. 相似文献
46.
Abe K Abe K Adachi I Ahn BS Aihara H Akatsu M Alimonti G Aoki K Asai K Asai M Asano Y Aso T Aulchenko V Aushev T Bakich AM Banas E Behari S Behera PK Beiline D Bondar A Bozek A Browder TE Casey BC Chang P Chao Y Cheon BG Choi SK Choi Y Doi Y Dragic J Eidelman S Enari Y Enomoto R Everton CW Fang F Fujii H Fujita Y Fukunaga C Fukushima M Garmash A Gordon A Gotow K Guler H Guo R Haba J Haji T Hamasaki H Hanagaki K Handa F Hara K Hara T Hastings NC Hayashi K Hayashii H Hazumi M Heenan EM Higuchi I 《Physical review letters》2001,86(15):3228-3232
We report a determination of the B(0)(d)-&B_(0)(d) mixing parameter Deltam(d) based on the time evolution of dilepton yields in Upsilon(4S) decays. The measurement is based on a 5.9 fb(-1) data sample collected by the Belle detector at KEKB. The proper-time difference distributions for same-sign and opposite-sign dilepton events are simultaneously fitted to an expression containing Deltam(d) as a free parameter. Using both muons and electrons, we obtain Deltam(d) = 0.463+/-0.008 (stat)+/-0.016 (syst) ps(-1). This is the first determination of Deltam(d) from time evolution measurements at the Upsilon(4S). We also place limits on possible CPT violations. 相似文献
47.
Abe K Abe K Abe R Adachi I Ahn BS Aihara H Akatsu M Alimonti G Asai K Asai M Asano Y Aso T Aulchenko V Aushev T Bakich AM Banas E Behari S Behera PK Beiline D Bondar A Bozek A Browder TE Casey BC Chang P Chao Y Chen KF Cheon BG Chistov R Choi SK Choi Y Dong LY Dragic J Drutskoy A Eidelman S Eiges V Enari Y Enomoto R Everton CW Fang F Fujii H Fukunaga C Fukushima M Gabyshev N Garmash A Gershon TJ Gordon A Gotow K Guler H Guo R Haba J Hamasaki H Hanagaki K Handa F Hara K Hara T Hastings NC 《Physical review letters》2001,87(9):091802
We present a measurement of the standard model CP violation parameter sin2 phi(1) based on a 29.1 fb(-1) data sample collected at the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy e(+)e(-) collider. One neutral B meson is fully reconstructed as a J/psi K(S), psi(2S)K(S), chi(c1)K(S), eta(c)K(S), J/psi K(L), or J/psi K(*0) decay and the flavor of the accompanying B meson is identified from its decay products. From the asymmetry in the distribution of the time intervals between the two B meson decay points, we determine sin2 phi(1) = 0.99+/-0.14(stat)+/-0.06(syst). We conclude that we have observed CP violation in the neutral B meson system. 相似文献
48.
Harsh Kumar Kanchan Bhardwaj Natlia Cruz-Martins Eugenie Nepovimova Patrik Oleksak Daljeet Singh Dhanjal Sonali Bhardwaj Reena Singh Chirag Chopra Rachna Verma Prem Parkash Chauhan Dinesh Kumar Kamil Ku
a 《Molecules (Basel, Switzerland)》2021,26(11)
The ingestion of contaminated water and food is known to cause food illness. Moreover, on assessing the patients suffering from foodborne disease has revealed the role of microbes in such diseases. Concerning which different methods have been developed for protecting food from microbes, the treatment of food with chemicals has been reported to exhibit an unwanted organoleptic effect while also affecting the nutritional value of food. Owing to these challenges, the demand for natural food preservatives has substantially increased. Therefore, the interest of researchers and food industries has shifted towards fruit polyphenols as potent inhibitors of foodborne bacteria. Recently, numerous fruit polyphenols have been acclaimed for their ability to avert toxin production and biofilm formation. Furthermore, various studies have recommended using fruit polyphenols solely or in combination with chemical disinfectants and food preservatives. Currently, different nanoparticles have been synthesized using fruit polyphenols to curb the growth of pathogenic microbes. Hence, this review intends to summarize the current knowledge about fruit polyphenols as antibacterial agents against foodborne pathogens. Additionally, the application of different fruit extracts in synthesizing functionalized nanoparticles has also been discussed. 相似文献
49.
Tijen Tanyalcin Diler Aslan Yusuf Kurtulmus Nalan Gökalp Kamil Kumanlioğlu 《Accreditation and quality assurance》2000,5(9):383-387
In this study the reference intervals for folate and vitamin B12 were estimated according to the National Committee for Clinical Laboratory Standards Approved Guideline C28-A and International
Federation of Clinical Chemistry recommendations. The study included 155 women and 124 men between ages 18–40. The health
status was confirmed by history, physical examination and a questionnaire. The central 95% reference intervals of serum folate
and vitamin B12 for women, determined non-parametrically, were found to be 3.9–18.1 ng/ml and 101–666.7 pg/ml, respectively.
The reference values of serum folate and vitamin B12 for men were also found to be 2,5–17.6 ng/ml and 100–699.57 pg/ml, respectively.
We did not observe subclass differences between females and males.
Received: 15 April 2000 · Accepted: 15 April 2000 相似文献
50.
Kamil Kaminski Marian Paluch R. Wrzalik Jerzy Ziolo Radoslav Bogoslovov C. Michael Roland 《Journal of polymer science. Part A, Polymer chemistry》2008,46(11):3795-3801
The polymerization and crosslinking of tetraethylene glycol dimethacrylate were induced by high pressure. The product was analyzed by both swelling experiments and broadband dielectric spectroscopy to determine the structure, with IR measurements used to follow the extent of reaction and its temperature dependence. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 3795–3801, 2008 相似文献