养殖鱼邻苯二甲酸酯的含量分析

目的：为了解宁波地区淡水养殖鱼PAEs污染情况。方法采用液液超声萃取-气质联用法对宁波6个不同养殖点5种淡水养殖鱼体内8种邻苯二甲酸酯含量进行分析。结果宁波地区养殖鱼主要受 DMP、 DEP、 DBP、 DEHP 和 DOP 污染，质量分数最高可达134.1、258.9、249.2、830.8和5029μg/kg；草鱼、鳊鱼、鳙鱼、鲫鱼和乌鳢邻苯二甲酸污染指数PPI分别为9.999、9.735、13.97、8.945和5.809μg/kg。结论宁波地区淡水养殖鱼鱼体邻苯二甲酸酯含量与养殖环境有关，与鱼种无关。     

ON THE WILLMORE’S THEOREM FOR CONVEX HYPERSURFACES

Let M be a compact convex hypersurface of class C2, which is assumed to bound a nonempty convex body K in the Euclidean space Rn and H be the mean curvature of M. We obtain a lower bound of the total square of mean curvature M H2dA. The bound is the Minkowski quermassintegral of the convex body K. The total square of mean curvature attains the lower bound when M is an (n-1)-sphere.     

Efficient adsorption and photocatalytic degradation of Congo red onto hydrothermally synthesized NiS nanoparticles

The influence of the length of the cation alkyl chain on the dispersibility by ultrasonic treatment of TiO₂ nanopowders in hydrophilic imidazolium-based room temperature ionic liquids was studied for the first time by dynamic light scattering and advanced rheology. TiO₂ nanopowders had been synthesized by chemical vapor synthesis (CVS) under varied conditions leading to two different materials. A commercial nanopowder had been used for comparison. Characterizations had been done using transmission electron microscopy, X-ray diffraction, nitrogen adsorption with BET analysis, and FT-IR spectroscopy. Primary particle sizes were about 6 and 8 nm for the CVS-based and 26 nm for the commercial materials. The particle size distribution in the dispersion was strongly influenced by the length of the cation alkyl chain for all the investigated powders with different structural characteristics and concentrations in the dispersion. It was found that an increase of the alkyl chain length was beneficial, leading to a narrowing of the particle size distribution and a decrease of the agglomerate size in dispersion. The smallest average nanoparticle sizes in dispersion were around 30 nm. Additionally, the surface functionality of the nanoparticles, the concentration of the solid material in the liquid, and the period of ultrasonic treatment control the dispersion quality, especially in the case of the ionic liquids with the shorter alkyl chain. The influence of the nanopowders characteristics on their dispersibility decreases considerably with increasing cation alkyl chain length. The results indicate that ionic liquids with adapted structure are candidates as absorber media for nanoparticles synthesized in gas phase processes to obtain liquid dispersions directly without redispergation.     

Ionic conductivity and interfacial stability of Li6PS5Cl–Li6.5La3Zr1.5Ta0.5O12 composite electrolyte

Solid electrolytes which possess excellent lithium-ion conductivity and chemical compatibility with electrode materials are necessary for the commercialization of all-solid-state lithium batteries. However, a single solid electrolyte meeting above requirements is difficult. Consequently, the composite electrolytes have attracted more attention. In this paper, Li₆PS₅Cl–xLi_6.5La₃Zr_1.5Ta_0.5O₁₂ (LLZTO) (x = 0, 2.5 wt%, 5 wt%, 10 wt%) composite electrolytes are prepared by a simple planetary grinding process. It has been found that adding an appropriate amount of LLZTO can increase the lithium-ion conductivity. At 30 °C, the lithium-ion conductivity increases from 2.6 × 10⁻⁴ S/cm (Li₆PS₅Cl) to 5.4 × 10⁻⁴ S/cm (Li₆PS₅Cl-5 wt% LLZTO). Besides, the addition of LLZTO to the Li₆PS₅Cl can influence the growth rate of the SEI. It has been shown that the SEI growth rate obeys a parabolic rate law, and the growth rates of Li₆PS₅Cl, Li₆PS₅Cl-2.5 wt% LLZTO, Li₆PS₅Cl-5 wt% LLZTO, and Li₆PS₅Cl-10 wt% LLZTO are 8.62, 3.53, 3.33, and 3.38 Ω/h^1/2 at 60 °C, respectively. In lithium plating and stripping experiment, the voltage of symmetrical Li/Li₆PS₅Cl/Li cell suddenly drops to 0 V after cycling 39 h at 0.103 mA/cm² (0.097 mAh/cm²). On the contrary, the Li/Li₆PS₅Cl–xLLZTO (x = 2.5 wt%, 5 wt%, 10 wt%)/Li symmetrical cell exhibits a stable voltage profile over 100 h at the same test conditions. The corresponding interfacial impedance of Li/Li₆PS₅Cl–xLLZTO (x = 2.5 wt%, 5 wt%, 10 wt%) remains stable after 10, 30, and 50 charge/discharge cycles.

     

Performance analysis of a discrete-time Geo/G/1 queue with randomized vacations and at most J vacations

This paper presents the analysis of a discrete-time Geo/G/1$\mathit{Geo}/G/1$ queue with randomized vacations. Using the probability decomposition theory and renewal process, two variants on this model, namely the late arrival system with delayed access (LAS-DA) and early arrival system (EAS), have been examined. For both the cases, recursive solution for queue length distributions at arbitrary, just before a potential arrival, pre-arrival, immediately after potential departure, and outside observer’s observation epochs are obtained. Further, various performance measures such as potential blocking probability, turned-on period, turned-off period, vacation period, expected length of the turned-on circle period, average queue length and sojourn time, etc. have been presented. It is hoped that the results obtained in this paper may provide useful information to designers of telecommunication systems, practitioners, and others.     

ON A MOVING MESH METHOD FOR SOLVING PARTIAL INTEGRO-DIFFERENTIAL EQUATIONS

This paper develops and analyzes a moving mesh finite difference method for solving partial integro-differential equations. First, the time-dependent mapping of the coordinate transformation is approximated by a a piecewise linear function in time. Then, piecewise quadratic polynomial in space and an efficient method to discretize the memory term of the equation is designed using the moving mesh approach. In each time slice, a simple piecewise constant approximation of the integrand is used, and thus a quadrature is constructed for the memory term. The central finite difference scheme for space and the backward Euler scheme for time are used. The paper proves that the accumulation of the quadrature error is uniformly bounded and that the convergence of the method is second order in space and first order in time. Numerical experiments are carried out to confirm the theoretical predictions.     

Numerical simulation of blowup in nonlocal reaction–diffusion equations using a moving mesh method

In this paper we implement the moving mesh PDE method for simulating the blowup in reaction–diffusion equations with temporal and spacial nonlinear nonlocal terms. By a time-dependent transformation, the physical equation is written into a Lagrangian form with respect to the computational variables. The time-dependent transformation function satisfies a parabolic partial differential equation — usually called moving mesh PDE (MMPDE). The transformed physical equation and MMPDE are solved alternately by central finite difference method combined with a backward time-stepping scheme. The integration time steps are chosen to be adaptive to the blowup solution by employing a simple and efficient approach. The monitor function in MMPDEs plays a key role in the performance of the moving mesh PDE method. The dominance of equidistribution is utilized to select the monitor functions and a formal analysis is performed to check the principle. A variety of numerical examples show that the blowup profiles can be expressed correctly in the computational coordinates and the blowup rates are determined by the tests.     

Preparation of Macroporous Sol-Gel Bioglass Using PVA Particles as Pore Former

Bioactive glasses are well known for their bone regeneration ability. Sol-gel bioglasses have many advantages comparing to melt derived bioglasses. 3-D scaffold prepared by sol-gel method is a promising substrate material for bone tissue engineering and large scale bone repair. But it is very difficult to produce macroporous sol-gel bioglasses with pores larger than 100 m. In this work, a series sol-gel bioglasses with macropores larger than 100 m are produced by adding PVA particles into the sol as pore former. The texture feature of this material is obtained by nitrogen adsorption/desorption analysis. Pore size distribution is collected by intrusion mercury porosimetry. SEM (Scanning Electron Microscope) was used to observe the pore structure of these samples. In these bioglasses, the diameter of the pore created by pore former vary from 100 to 300 m. In vitro tests were used to evaluate the bioactivity of these sol-gel bioglasses. The samples prepared in this work show satisfactory handle resistance and good bioactivity.     

Esterase‐Sensitive Prodrugs with Tunable Release Rates and Direct Generation of Hydrogen Sulfide

Prodrugs that release hydrogen sulfide upon esterase‐mediated cleavage of an ester group followed by lactonization are described herein. By modifying the ester group and thus its susceptibility to esterase, and structural features critical to the lactonization rate, H₂S release rates can be tuned. Such prodrugs directly release hydrogen sulfide without the involvement of perthiol species, which are commonly encountered with existing H₂S donors. Additionally, such prodrugs can easily be conjugated to another non‐steroidal anti‐inflammatory agent, leading to easy synthesis of hybrid prodrugs. As a biological validation of the H₂S prodrugs, the anti‐inflammatory effects of one such prodrug were examined by studying its ability to inhibit LPS‐induced TNF‐α production in RAW 264.7 cells. This type of H₂S prodrugs shows great potential as both research tools and therapeutic agents.     

关于求解y″=f（x,y）的高阶p—稳定嵌套的多步方法

0　引　　言最近二十年,关于数值求解二阶周期性常微分方程初值问题y"=f(x,y),y(x0)=y0,y′(x0)=y′0(1)引起了许多研究者的极大兴趣[3,4,10,13].这类方程经常出现在天体力学,波动方程理论等领域.直接数值求解这类问题的经典方法是Stormer-Cowell公式,但是正如文献Lam-bert[7]和Stiefel[11]所指出的,高于两步的Stormer-Cowell公式是数值不稳定的.方程y"=f(x,y)的解具有周期性,因而希望数值解应与解析解有相似的周期性.Lambert和Watson[7]为此引入了P-稳定概念,但随后一些研究者发现,具有P-稳定性质的线性多步法的最大阶是2.为了克服…