首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9562篇
  免费   1187篇
  国内免费   806篇
化学   6516篇
晶体学   158篇
力学   417篇
综合类   44篇
数学   1292篇
物理学   3128篇
  2023年   149篇
  2022年   257篇
  2021年   274篇
  2020年   375篇
  2019年   345篇
  2018年   303篇
  2017年   311篇
  2016年   414篇
  2015年   438篇
  2014年   409篇
  2013年   618篇
  2012年   673篇
  2011年   671篇
  2010年   499篇
  2009年   460篇
  2008年   511篇
  2007年   423篇
  2006年   416篇
  2005年   368篇
  2004年   318篇
  2003年   225篇
  2002年   252篇
  2001年   176篇
  2000年   198篇
  1999年   174篇
  1998年   95篇
  1997年   105篇
  1996年   98篇
  1995年   87篇
  1994年   90篇
  1993年   104篇
  1992年   85篇
  1991年   71篇
  1990年   69篇
  1989年   52篇
  1988年   59篇
  1987年   51篇
  1986年   75篇
  1985年   77篇
  1984年   65篇
  1983年   61篇
  1982年   61篇
  1980年   71篇
  1979年   55篇
  1978年   64篇
  1977年   63篇
  1976年   59篇
  1975年   64篇
  1974年   49篇
  1973年   56篇
排序方式: 共有10000条查询结果,搜索用时 127 毫秒
11.
在实际应用中,常常使用多个重写系统。本文主要讨论重写系统和的合流性,并给出了一个重写系统和具有合流性的充分条件。  相似文献   
12.
We consider front solutions of the Swift–Hohenberg equation ∂ t u= -(1+ ∂ x 2)2 u + ɛ2 u -u 3. These are traveling waves which leave in their wake a periodic pattern in the laboratory frame. Using renormalization techniques and a decomposition into Bloch waves, we show the non-linear stability of these solutions. It turns out that this problem is closely related to the question of stability of the trivial solution for the model problem ∂ t u(x,t) = ∂ x 2 u (x,t)+(1+tanh(x-ct))u(x,t)+u(x,t) p with p>3. In particular, we show that the instability of the perturbation ahead of the front is entirely compensated by a diffusive stabilization which sets in once the perturbation has hit the bulk behind the front. Received: 23 February 2001 / Accepted: 27 August 2001  相似文献   
13.
全光纤反射式马赫曾德尔干涉型多波长滤波器的研究   总被引:2,自引:1,他引:1  
对反射式的马赫-曾德尔干涉型多波长滤波器的性能作了较详细的研究,得出了两个耦合器的分光比和两臂的臂长差对其输出谱线的影响,结论对设计制作不同性能指标的该型多波长滤波器具有重要的参考价值。实验上用光纤熔融拉锥法制作了该种器件,实验结果与理论相符合。  相似文献   
14.
15.
16.
The synthesis and structural characterization of a series of novel, fluorinated poly(phthalazinone ether)s containing perfluorophenylene moieties are described. The monomers, 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a – 2d ), were conveniently and efficiently synthesized from phenols and phthalic anhydride in two steps via 2‐(4′‐hydroxybenzoyl)benzoic acids, which were first obtained by the Friedel–Crafts reaction in good yields and with high stereoselectivity and were then converted into 2a – 2d by fusion with hydrazine. All the polymers were prepared by nucleophilic aromatic substitution (SNAr) polycondensation between the compounds perfluorobiphenyl and 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a ‐ 2d ). The resulting fluorinated polymers were readily soluble in common organic solvents (e.g., CHCl3, tetrahydrofuran, dimethylformamide, dimethyl sulfoxide, N‐methylpyrrolidone, etc.) at room temperature. Their weight‐average molecular weights and the polydispersities ranged from (7.96–18.25) × 103 to 1.31–2.71, respectively. Their glass‐transition temperatures varied from 213 to 263 °C. They were all stable up to 390 °C both in air and in argon. The 5% weight‐loss temperatures of these polymers in air and argon ranged from 393–487 to 437–509 °C, respectively. Wide‐angle X‐ray diffraction studies indicated they were all amorphous and could be attributed to the presence of kink nonplanar moiety, phenyl phthalazinone along the polymer backbone. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 925–932, 2004  相似文献   
17.
溶胶-凝胶法制备小颗粒(Y,Gd)BO_3∶Eu及其表征   总被引:1,自引:0,他引:1  
用溶胶 凝胶方法制备了平均粒径为 1~ 2 μm的小颗粒、高发射效率的 (Y ,Gd)BO3 ∶Eu红色发射荧光体。用XRD、SEM、粒度分析和PL光谱对荧光体作了表征和研究。常规固相反应合成 (Y ,Gd)BO3 ∶Eu需在 1 2 0 0℃以上才能形成均一的固溶体。而溶胶 凝胶法制取稀土正硼酸盐 80 0℃灼烧已可形成均一的单相 (Y ,Gd)BO3 ∶Eu,在 1 1 0 0℃可得到发光亮度最高的荧光体。它的亮度是常规固相反应于 1 2 0 0℃制得的荧光体的 1 2 0 %。采用溶胶 凝胶法制取 (Y ,Gd)BO3 ∶Eu荧光体 ,可在相当宽的实验条件范围内得到小粒径、窄分布和高亮度的荧光体 ,且有良好的颗粒形貌。  相似文献   
18.
A mono-funtionalised tetraphenylporphyrin (TPP) bearing valine moiety at the phenyl ring was synthesized for photocytotoxicity examination in four steps, starting from regiospecific mono-nitration of TPP at the phenyl ring. The in vitro photocytotoxicitic effect against SPC-Al adenocarcinona cell line was tested.  相似文献   
19.
20.
The crystal structures of two ancylite specimens from Khibiny massif (the Kola Peninsula, Russia)—ancylite-(Ce) from alkali hydrothermalites (Sr1.01Ca0.02Ba0.01)Σ1.04(Ce0.52La0.28Nd0.11Pr0.04 Sm0.01)Σ0.96(CO3)2(OH0.83F0.13)Σ0.96 · 0.9H2O and ancylite-(Ce) from carbonatites—have (Sr0.80Ca0.05Ba0.01)Σ0.86(Ce0.62La0.40Nd0.09Pr0.03) Σ1.14(CO3)2(OH0.99F0.15)Σ1.14 · 1.0H2O been refined by the Rietveld method. A focusing STOE-STADIP diffractometer with a bent Ge(111) primary monochromator was used (λ MoK α 1 radiation, 2.16° < 2θ < 54.98°; reflection number 237–437). All the computations for ancylite from alkali hydrothermalites were performed within the sp. gr. Pmc21, a = 5.0634(1) Å, b = 8.5898(1) Å, c = 7.2781(1) Å, V = 316.55(1) Å3, R wp = 1.90; the computations for ancylite from carbonatites were performed within the sp. gr. Pmcn, a = 5.0577(1) Å, b = 8.5665(2) Å, c = 7.3151(2) Å, V = 316.94(1) Å3, R wp = 2.38 in the anisotropic approximation of thermal vibrations of cations and oxygen atoms.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号