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951.
通过溶胶-凝胶法制备出不同Tb3+掺杂浓度和不同二次煅烧温度下的ZnAl2O4:Tb3+荧光粉, 并利用X射线衍射(XRD)和荧光光谱等对样品进行了表征。由XRD结果可知,当Tb3+掺杂的摩尔分数不大于9%,二次煅烧温度在600℃以上时,所得粉体为结晶性良好的尖晶石相。在紫外光激发下,ZnAl2O4:Tb3+荧光粉的发射光谱由位于488 nm(5D4→7F6)、542 nm(5D4→7F5)、587 nm(5D4→7F4 )和621.5 nm(5D4→7F3)的4个发射峰组成。研究发现,Tb3+的掺杂浓度和二次煅烧温度对样品发光强度有着重要影响,当Tb3+的摩尔分数为5%,二次煅烧温度为900℃时,ZnAl2O4:Tb3+荧光粉的发光最强,继续增加Tb3+掺杂浓度或提高煅烧温度,分别会出现浓度猝灭和温度猝灭现象。 相似文献
952.
双平行圆柱形MDM纳米棒等离子体波导的传输特性分析 总被引:1,自引:0,他引:1
设计了一种由双平行圆柱形纳米棒构成的金属-介质-金属(MDM)型等离子体波导,采用时域有限差分方法(FDTD)分析了波导结构的传输特性。当光波垂直主轴入射时,电磁场被很好地局限在两纳米棒所形成的中间区域以及介质层中,从而在该波导中能够有效地耦合电磁场能量。在工作波长为1 550 nm的情况下,随着内层金属芯半径的增大,有效折射率减小,传播距离增大;而中间介质层厚度增大时,有效折射率增大,传播距离减小。当外层金属壳厚为20 nm时,电场可以很好地被限制在纳米棒的介质层内。上述结果表明:通过调整波导结构的几何参数可以显著提高金属纳米棒的场限制,降低波导本身的损耗, 使波导的有效折射率和传播长度达到最优化。这种等离子体波导能够实现亚波长的光限制,可以应用于光子器件集成和传感器领域。 相似文献
953.
954.
955.
基于电化学-热耦合模型研究聚合物锂离子动力电池放电过程热行为, 分析了放电倍率、冷却条件对电池放电过程的温度变化及分布的影响规律. 结果表明: 3C放电时, 模型计算结果与实测结果的平均偏差为0.57 K, 方差为0.15, 说明模型准确度较高. 电芯的平均生热率在整个放电过程中呈现出增加的趋势, 初期和末期增长较快. 大倍率放电时, 与电流密度的平方呈正比的不可逆热所占的比重较大, 小倍率放电时, 电化学反应可逆热占主导. 改善冷却条件能降低电池放电过程的平均温度, 对流传热过程的表面传热系数为5 W/(m2·K), 1 C, 3 C, 5 C放电结束时, 电芯的平均温升为分别为6.46 K, 17.67 K, 27.53 K, 当对流传热过程的表面传热系数增加至25 W/(m2·K)时, 温升比自然对流条件下相同倍率放电时的温度分别降低了2.91 K, 4.68 K, 5.62 K, 但电芯温度分布的不一致性也会加剧.
关键词:
电化学
耦合
锂离子动力电池
温度分布 相似文献
956.
The addition of nematic compounds with high clearing points (Nh) to multiplexable nematic liquid crystals decreases the temperature dependence of the threshold voltage of twisted nematic displays. This effect depends on the dielectric anisotropy of the nematic liquid crystals containing Nh, as well as on the increase in T c. In the case of 4-n-butylphenyl 4'-(4”-butyibenzoyloxy) benzoate, the low threshold voltage was exceptionally compatible with a small temperature dependence of threshold voltage, and this result was attributed to the large temperature dependence of the dielectric anisotropy in comparison with that of nematic liquid crystals containing other Nh's. 相似文献
957.
In the presence of a pinning potential both the nature of the Peierls transition and the dynamics of the Charge Density Wave are affected. We argue that the periodic potential stabilizes phase solitons, while amplitude solitons can be polarons or bipolarons. For these excitations we give both the extension along the chain as well as the energies of formation. We only discuss the case of a periodic pinning potential as arising from a counterion lattice; neglecting randomness from impurities. 相似文献
958.
Zuming Jiang Zhiqing Su Li Li Kai Zhang Yong Zhu Jiangbo Li 《Journal of Macromolecular Science: Physics》2013,52(7):1030-1040
Using artificial cores, six different partially crosslinked polyacrylamide (PCPAM) suspensions were used for sandpacked core flow experiments; the results indicated that the migration of the PCPAM particles through porous media was a process of plugging and flooding at the same time. A theoretical model was proposed and the sensitive parameter, G′, was determined by rheological oscillation measurements with a 200 μm plate gap. In addition, the validity of the proposed theoretical model was verified by the results of the core flow experiments and a fitting equation of ΔP 1 with G′ was obtained which can be used for quantifying the steady-state pressure of PCPAM suspensions flowing through porous media in the core flow experiments. 相似文献
959.
High-density polyethylene (HDPE) nanocomposites reinforced with hydroxyapatite nanorods (nHA) were fabricated by means of extrusion and injection molding. The thermal, mechanical, and dry sliding wear properties of HDPE-based nanocomposites filled with nHA loadings up to 20 wt% were investigated. The results of mechanical property characterization showed that nHA additions improved the hardness, elastic modulus, and yield strength of HDPE at the expense of its tensile ductility and impact strength. Thermogravimetric analysis and heat deflection temperature measurements revealed that nHA fillers are very effective to enhance the thermal stability of HDPE. The wear behavior of HDPE/nHA nanocomposites was studied using a pin-on-disk tribometer. nHA fillers of a large aspect ratio improved the wear resistance of HDPE substantially because of their load-bearing effect and the formation of a continuous transfer film on the steel counterface. 相似文献
960.
Kai Xiong Lianshi Wang Anqiang Zhang 《Journal of Macromolecular Science: Physics》2013,52(7):1350-1363
POE-graft-methyl methacrylate and acrylonitrile (POE-g-MAN) was prepared by graft copolymerization of methyl methacrylate (MMA) and acrylonitrile (AN) onto polyethylene-octene copolymers (POE) with suspension polymerization. POE-g-MAN/SAN resin blends (AOMS) were prepared by blending POE-g-MAN with styrene-acrylonitrile copolymer (SAN resin). The mechanical properties, compatibility, and thermal stabilities of AOMS were studied. The notched impact strength of the blends reached 54.0 kJ/m2 when the AN/(MMA + AN) ratio (fAN) of POE-g-MAN, benzoyl peroxide dosage, and POE content in AOMS were 15 wt%, 1.0 wt%, and 25 wt%, respectively. Transmission electron microscopy analysis showed that the highest toughness occurred when the size of POE-g-MAN particles and the surface-to-surface inter-particle distance were proper. Scanning electron microscopy analysis indicated that the AOMS fracture surface had plastic flow visible, which looked like a fibril morphology when the AN/(MMA + AN) ratio (fAN) of POE-g-MAN was 15 wt%. The toughening mechanism of AOMS was shear yielding of the matrix, which endowed AOMS with remarkable toughness. Dynamic mechanical thermal analysis showed that the compatibility of the POE phase and SAN phase improved after graft copolymerization of MMA and AN onto POE. When the grafting chain polarity was appropriate, the miscibility between POE-g-MAN and SAN resin was the best. Thermogravimetry analysis showed that thermal stability of AOMS increased with increasing AN units in POE-g-MAN. 相似文献