Layered Double Hydroxide as Cordycepin Delivery Nanocarrier

Layered double hydroxides (LDHs), also called “anionic clays”, have received considerable attention due to their technological importance in catalysis, adsorption, optics, nanocomposite engineering materials and medical science1-5. LDHs are layered mate…     

CVD Reactions of TiCl4 with Ammonia： a Quantum Chemical Study

Based on density functional calculations, the mechanism and the energetic course of the chemical vapor deposition （CVD） reaction of TiCl4 with NH3 were studied at the level of B3LYP with 6-311g（d） basis set. Furthermore, the polymerization processes of dimerization, trimerization and tetramerization were investigated. The calculation results indicate that the formation of polymers is favored at the elimination reaction. On the basis of the calculated energetics, a possible mechanism of the reduction reaction has been proposed.     

免疫亲和柱净化/柱前衍生化-高效液相色谱荧光检测法测定粮谷中的T-2毒素

建立了免疫亲和柱净化/柱前衍生化-高效液相色谱荧光检测器测定粮谷中T-2毒素含量的方法。样品经甲醇-水(体积比为80∶20)混合溶剂提取,通过免疫亲和柱(IAC)净化,以氰酸蒽(1-AN)为衍生化试剂、4-二甲基氨基吡啶(DMAP)为催化剂进行衍生,以ZORBAX Eclipse XDB-C18 柱为分离柱,乙腈-水(体积比为80∶20)为流动相进行高效液相色谱分离及荧光检测，荧光检测的激发波长为381 nm，发射波长为470 nm。T-2毒素的质量浓度为0.01~1.5 mg/L时与峰高呈良好的线性,相关系数为0.9985。在0.01~1.5 μg/g添加水平下，回收率为79.7%~94.5%,相对标准偏差小于7%；检出限（S/N＝3）为0.01 μg/g。该方法净化效果好,灵敏度高,操作简便快速。     

边孔弧形闸门水流脉动压力特性研究

弧形泄水闸是水利枢纽工程中常见的挡水、泄水建筑物,其在关闭或开启过程中或者局部开启运行时,在水流脉动压力作用下会产生振动,容易引起闸门结构破坏。本文针对边孔闸门与中孔闸门不同的水流边界条件特点,制作了带导流墙与无导流墙两个弧形闸门模型。在实验室内开展了不同库水位、不同闸门开度下的物理模型试验,并对两个模型上大量测点的水流脉动压力数据进行比较分析。试验表明,导流墙的存在对脉动压力主频的影响较小,但对脉动压力均方根值影响较大;在较高库水位下相对开度位于0.2至0.3区间内时,导流墙的存在不但不会改善闸门的受力状况,反而还会导致受力增强。     

人造金刚石的微观结构模型

将静态超高压高温合成的人造金刚石晶粒利用RTO包埋法制备成适合TEM观察的样品,发现这些金刚石晶粒是由多根细长的纳米多晶棒沿一定取向规则地以捆束状堆叠、聚集而成,而这些纳米多晶棒之间填充了无定型碳。也就是说,人造金刚石晶粒是由结晶碳素和无定型碳组成的。由此,提出并绘制了人造金刚石晶粒的微观结构模型示意图,可用于解释人造金刚石的各向异性及其他宏观性能特征。在以上结论的基础上,笔者认为业界经常提及的"单晶"金刚石称谓可能并不严谨,可能并不是纯粹由结晶金刚石材料组成。     

Controlled kinetics of non-enzymatic chemiluminescence reactions for simple imaging of DNA and protein

A robust and sensitive non-enzymatic chemiluminescence (CL) imaging method is presented. In the method a fast-emitting CL reaction is tuned to furnish a slower-emitting reaction suitable for simple CL imaging. Typically, non-enzymatic CL reactions between luminol or fluorescein and oxygen species generated by KCN as catalyst, were rather fast and unsuitable for CL imaging; the speed of the reactions could, however, be reduced substantially by changing KCN for CH(3)CN or benzonitrile. Light emission from the tuned CL reaction was intense and long-lived, and even with a simple arrangement high sensitivity could be achieved. The maximum CL peak was reached after approximately 1.5 min in the presence of 25% acetonitrile, and as little as 16 fmol commercial isoluminol-labeled streptavidin was detected and visualized on either microplate or membrane. The approach was further illustrated by imaging of DNA on a membrane and of antibody on a microplate by use of biotin-streptavidin chemistry. Overall, this simple, economical, and sensitive CL imaging system is expected to be very useful in biochemical analysis, and greatly complements currently used enzyme-based CL imaging methods, especially in routine applications.     

4,4′‐Thio­dipyridinium tetra­chloro­copper(II)

The title compound, (C₁₀H₁₀N₂S)[CuCl₄], was obtained by the reaction of cupric chloride with pyridine‐4‐thiol in a mixture of aceto­nitrile and tetra­hydro­furan, suggesting that the desulfurization and coupling reactions of pyridine‐4‐thiol occurred in the presence of the Cu²⁺ ion. X‐ray diffraction analysis reveals the presence of one 4,4′‐thio­dipyridinium cation, H₂bps²⁺, and one [CuCl₄]²⁻ anion. The cations interact with the anions via N—H⋯Cl hydrogen‐bonding interactions to form a closed `chair' conformation.     

非紧L-凸度量空间中的一个新的不动点定理及其对极大极小不等式和鞍点的应用

In this paper,a new fixed point theorem is established in noncompact complete Lconvex metric spaces.As applications,a maximal element theorem,a minimax inequality and a saddle point theorem are obtained.     

稀土Ce掺杂对ZnO结构和光催化性能的影响

采用共沉淀-焙烧法合成了一系列不同含量的稀土Ce掺杂的ZnO光催化剂. 利用傅里叶变换红外(FT-IR)光谱、粉末X射线衍射(XRD)、扫描电镜(SEM)、紫外-可见(UV-Vis)光谱、光致发光(PL)谱等技术对所制备的光催化剂进行了系列表征. 以酸性橙II脱色降解为模型反应, 考察了掺杂不同含量的铈及不同焙烧温度对ZnO的物理结构和光催化脱色性能的影响. 结果表明: 掺入质量分数(w)为2%的铈可以明显改善氧化锌表面状态, 有利于产生更多的表面羟基; 同时可以抑制光生电子与光生空穴(e^-/h⁺)的复合, 显著提高光催化脱色活性和光催化稳定性; 焙烧温度对光催化剂的晶体结构、表面性能和光催化活性产生较大影响, 500 °C的焙烧处理使样品的结晶度较高, 同时催化剂颗粒粒径较细, 表面具有丰富的羟基. 但过高的焙烧温度(600-800 °C)将导致催化剂的物理结构发生恶化, 降低光催化性能.     

北京谱仪桶部簇射计数器能量响应特性研究

在北京正负电子对撞机的J/ψ和Ds能区,选择了辐射巴巴事例,并以此来研究北京谱仪的桶部簇射计数器能量响应特性.在消除了由于电子和辐射光子在桶部簇射计数器中沉积能量区域重叠的影响后,正确地得到了桶部簇射计数器在电子和光子动量小于2GeV以下的能量响应,表明在所研究能区,桶部簇射计数器的能量响应线性很好.对桶部簇射计数器微小的非线性进行修正后,重建的π0不变质量谱得到改善.