Absorption spectroscopy using a coherent transition radiation millimeter wave light source

The characteristics and applicability of the absorption spectroscopy system using the coherent transition radiation light source have been investigated. The configurations of the system are relatively simple. The operational conditions of an electron linear accelerator have been evaluated. The stability of the light intensity has been within ±2–3% in a wavenumber range of 4–13 cm⁻¹. The light intensity has been found to be more than six orders of magnitude higher than that for the lowest limit for detection.     

A Spinorization of a Constrained Vector System and a Spinor Reconstruction Theorem

An elementary method of conctructing a spinor from vectors satisfying constraint conditions is proposed. We consider orthonormal triad and tetrad as an orientable physical object and introduce parameter representations of them, in terms of the Euler angles and the pseudo-Euler angles. Having determined the transformation property of the parameters, we set up the spinor determining equation. This equation is solved. The solution (spinor) contains four arbitrary complex constants, in 3 + 1 dimensional space. Using the proposed method, we prove the spinor reconstruction theorem, i.e. the original Dirac spinor can be reconstructed from seven of the sixteen hermitian bilinear forms, except the overall phase factor (the gauge freedom of the 1st kind). The energy density of the spinor field is written in terms of currents and their space derivatives.     

A Hexagonal Planar Metal Complex

A six‐coordinate [ML₃Z₃]‐type transition‐metal complex with a hexagonal planar geometry has been isolated and characterized, extending the scope of six‐coordinate metal coordination compounds to those with a geometry beyond octahedral and trigonal prismatic.     

Layer-by-layer assembly of partially sulfonated isotactic polystyrene with poly(vinylamine)

The stereoregular synthetic polymer isotactic polystyrene bearing partially sulfonated groups (SiPS) was used as a layer-by-layer assembled thin film for the first time. When a low molecular weight compound was employed as the pair for the alternative layer-by-layer (LbL) assembly, the frequency shift was very small using quartz crystal microbalance (QCM) analysis, whereas poly(vinylamine) (PVAm) formed an effective pair for the construction of LbL films with SiPS. When it was neutralized, SiPS was not assembled, probably due to the loss of effective polymer-polymer interactions. The ionic strength conditions revealed a slight difference of the assembly behavior on the isotactic polymer as compared to the atactic one. The assembled LbL film showed the same peaks over the range from 1141 to 1227 cm(-1) and 700 cm(-1) in the FT-IR/ATR spectra as the bulk complex of SiPS/PVAm, and the thickness on one side was calculated at 76 nm by QCM analysis. The surface roughness of the film was also observed by AFM.     

Molecular weight between entanglements for linear d-glucans

Dynamic viscoelasticity measurements were carried out for concentrated solutions of linear d-glucans in BmimCl to examine the effect of the linkage between repeating units of glucose on the rheological properties. The values of molecular weight between entanglements (M _e) were determined for four d-glucans: curdlan, pullulan, cellulose, and amylose. From the concentration dependence of M _e, the value of M _e in the molten state (M _e,melt) for each d-glucan was estimated as a material constant. The order of M _e,melt became cellulose?<?pullulan?<?curdlan?<?amylose, indicating that the linkage is actually influential in M _e,melt for the linear d-glucans. The relationship between M _e,melt and the molecular structure of the d-glucans were discussed assuming that the values of M _e,melt for the d-glucans primarily reflect the chain stiffness such as the characteristic ratio C _∞ on the analogy of synthetic polymers. Although the trend was not so clear, it was shown that N _unit is a decreasing function of C _∞ .