排序方式: 共有32条查询结果,搜索用时 0 毫秒
11.
LUDVÍK BENEŠ KLÁRA MELÁNOVÁ JAN SVOBODA VÍTĚZSLAV ZIMA 《Journal of inclusion phenomena and macrocyclic chemistry》2006,55(3-4):289-293
Intercalates of o-, m-, and p-toluidine into α-Zr(HPO4)2 · H2O were prepared and characterized by powder X-ray diffraction, thermogravimetric analysis and infrared spectroscopy. As follows from IR, toludine molecules are protonated in the interlayer space. Toluidine molecules are arranged in a bimolecular way in the intercalates containing more than 1.5 toluidine molecules per Zr atom. On the other hand, a monolayer of the toluidine molecules is supposed in the intercalates with less than one toluidine molecule per Zr atom. 相似文献
12.
13.
Biomolecular homochirality, the origin of which is still a puzzle, has challenged scientists to design chemical systems that provide chiral molecules through absolute asymmetric synthesis and to amplify a small stereochemical bias in such systems. The photoresolution of the enantiomers of helical-shaped, sterically overcrowded alkene 1 with circularly polarized light and the transduction of the stereochemical information by triggering the helical arrangement of a large collection of achiral molecules in a twisted nematic liquid crystalline phase (2) are examples of control and amplification of chirality. 相似文献
14.
Numerous organic and inorganic laboratory standards were gathered from nine European and North American laboratories and were analyzed for their delta(18)O values with a new on-line high temperature pyrolysis system that was calibrated using Vienna standard mean ocean water (VSMOW) and standard light Antartic precipitation (SLAP) internationally distributed reference water samples. Especially for organic materials, discrepancies between reported and measured values were high, ranging up to 2 per thousand. The reasons for these discrepancies are discussed and the need for an exact and reliable calibration of existing reference materials, as well as for the establishment of additional organic and inorganic reference materials is stressed. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
15.
We study the connection between the number of ascending and descending cuts of a linear order, its classical size, and its
effective complexity (how much [how little] information can be encoded into it). 相似文献
16.
A review is presented of the calculation of photoionization spectra, particularly in the spectral range where electron autoionization of diatomic molecules takes place. In addition to some interesting results obtained over years that compare favourably with experiment, the emphasis here is put on the relation between the methods developed for the calculation of observables associated with the continuum energy spectrum of the electrons and the Alchemy system of programs. This system of programs serves as a basis for initial and intermediate calculations. The examples presented show that diatomic molecules not only in gas phase but also oriented in space or physisorbed at surfaces may be studied readily. 相似文献
17.
K H?kansson RA Zubarev RV Coorey VL Talrose P H?kansson 《Rapid communications in mass spectrometry : RCM》1999,13(12):1169-1174
An HMX/insulin two-layer system was chosen as a model for further investigation of the matrix properties of explosive materials for protein analytes in plasma desorption mass spectrometry. The dependencies of the molecular ion yield and average charge state as a function of the analyte thickness were studied. An increase in the charge state of multiply protonated molecular species was confirmed as the major matrix effect, with the average charge state z at the smallest thickness studied being higher than in matrix-assisted laser desorption/ionization and closer to the value obtained in electrospray ionization under standard acidic conditions. Observed charge state distributions are significantly narrower than the corresponding Poisson distributions, which suggests that the protonation of insulin is limited in plasma desorption by the number of basic sites in the molecule, similar to electrospray ionization. Both the curve displaying total molecular ion yield and the one showing the total charge (proton) yield as a function of the insulin thickness have maxima at a thickness different from an insulin monolayer. These observations diminish the significance of a matrix/analyte interface mechanism for the explosive matrix assistance. Instead, a mechanism related to the chemical energy release during conversion of the explosive after the ion impact is proposed. As additional mechanisms, enhanced protonation of the analyte through collisions with products of the explosive decay is considered, as well as electron scavenging by other products, which leads to a higher survival probability of positively charged protein molecular ions. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
18.
Acoustic performance characteristics of catalysts in the exhaust system are important in the development of predictive tools for the breathing system of internal combustion engines. To understand the wave attenuation behavior of these elements with firing engines, dynamometer experiments are conducted on a 3.0L V-6 engine with two different exhaust systems: one with the catalysts on the cross-over pipe, and the other that replaces the catalysts with equal length straight pipes. The instantaneous crank-angle resolved pressure data are acquired at wide open throttle and 500 rpm intervals over the operating range of the engine (from 1000 to 5000 rpm) at various locations in both exhaust systems. The effect of the catalyst is then isolated and discussed in terms of insertion loss at critical locations in the exhaust system. The analysis is presented both in terms of time-domain and order-domain. The predictive capability of a finite-difference based time-domain nonlinear approach is also demonstrated as applied to large amplitude waves in the exhaust system of firing engines. 相似文献
19.
Marat Faizrahmanov Asher Kach Iskander Kalimullin Antonio Montalbn Vadim Puzarenko 《Mathematical Logic Quarterly》2019,65(1):37-45
It is proved that for every countable structure and a computable successor ordinal α there is a countable structure which is ‐least among all countable structures such that is Σ‐definable in the αth jump . We also show that this result does not hold for the limit ordinal . Moreover, we prove that there is no countable structure with the degree spectrum for . 相似文献
20.
Asher M. Kach 《Archive for Mathematical Logic》2008,47(3):211-219
The main result is that for sets , the following are equivalent:
Other results discuss the relationship between these sets and the sets.
The author’s research was partially supported by a VIGRE grant fellowship. The author thanks Denis Hirschfeldt and Steffen
Lempp for an insightful conversation about LIMINF sets; Christopher Alfeld and Robert Owen for numerous comments and suggestions; and his thesis advisor Steffen Lempp for
his guidance. 相似文献
(1) | The shuffle sum σ(S) is computable. |
(2) | The set S is a limit infimum set, i.e., there is a total computable function g(x, t) such that enumerates S. |
(3) | The set S is a limitwise monotonic set relative to 0′, i.e., there is a total 0′-computable function satisfying such that enumerates S. |