Spin-parity combinations in 16N from the 18O(d,α)16N reaction

The reaction ¹⁸O(d, α)¹⁶N has been studied using a tensor-polarized deuteron beam at incident energies of 8.50, 9.25, 10.00, 10.30, 10.75 and 11.30 MeV. From measurement of the tensor analysing power of the reaction when the α-particles are emitted near 0°, spin-parity combinations have been deduced for thirteen levels in ¹⁶N up to 6.2 MeV excitation. These results, together with previous work, lead to new and unambiguous spin and parity assignments for four of these levels.     

Tunneling motions of methyl groups in manganese acetate tetrahydrate

The temperature dependence of the tunneling motions of the methyl groups in Manganese Acetate Tetrahydrate has been studied by high resolution inelastic neutron scattering in a range between 0.06 K and 40 K. The results are in qualitative agreement with models based on rotor-phonon and rotor-rotor coupling valid for temperature regions above and below 5 K respectively. The finite line width of one of the tunneling lines which persists at very low temperatures and the anomalous positive shift of the same line at higher temperatures is not understood.     

Dilaton as the Higgs boson

We propose a model where the role of the electroweak Higgs field is played by the dilaton. The model contains terms which explicitly violate gauge invariance; however, it is shown that this violation is fictitious, so that the model is a consistent low-energy effective theory. In the simplest version of the idea the resulting low-energy effective theory is the same as the top mode standard model.     

Stability of self-similar plane shocks with Hertzian nonlinearity

The nonlinear progressive wave equation [McDonald and Kuperman, J. Acoust. Soc. Am. 81, 1406-1417 (1987)] is expressed in a form to accommodate Hertzian nonlinearity of order n=3/2 typical of granular media. Stability of self-similar plane weak shocks against perturbations in three dimensions is demonstrated for arbitrary order nonlinearity with 1 相似文献   

Proton sponge phosphines: electrospray-active ligands

Attachment of a proton sponge to a phosphine ligand renders neutral complexes of the ligand highly amenable to analysis by electrospray ionisation mass spectrometry (ESI-MS). The ligand 1,8-bis(dimethylamino)naphthyldiphenylphosphine (3) is extremely efficient and highly selective in forming exclusively [M + H]+ ions, which may be detected at very low concentration. Ionisation efficiency of 3 in the presence of H+ approached 100%. The bis-substituted ligand bis{1,8-bis(dimethylamino)naphthyl}phenylphosphine (4) was also prepared and characterised, as were Fe(CO)4- (5c), Mn(eta5-C5H4Me)(CO)2- (6) and W(CO)5- (7) complexes of 3. Compounds 3, 3.HBr.EtOH, 4 and 5c were all structurally characterised.     

Enhanced Fermi-surface nesting in superconducting BaFe2(As(1-x)P(x))2 revealed by the de Haas-van Alphen effect

The three-dimensional Fermi-surface morphology of superconducting BaFe2(As0.37P0.63)2 with T(c)=9 K is determined using the de Haas-van Alphen effect. The inner electron pocket has a similar area and k(z) interplane warping to the observed hole pocket, revealing that the Fermi surfaces are geometrically well nested in the (π,π) direction. These results are in stark contrast to the fermiology of the nonsuperconducting phosphides (x=1), and therefore suggest an important role for nesting in pnictide superconductivity.     

Diastereoselective [4 + 4]-photocycloaddition reactions of pyran-2-ones: rapid access to functionalized 5-8-5 skeletons

Fused bicyclic pyran-2-ones with pendant furan side chains and an oxygenated stereogenic center adjacent to the pyranone ring oxygen were prepared via FeCl(3)-catalyzed Michael addition. Irradiation furnished the corresponding lactone-bridged tricyclic [4 + 4]-cycloadducts with good facial selectivity. Surprisingly, the major isomer resulted from approach of the furan from the same face as the protected alcohol. [reaction: see text]