Atomic Diffusion in Cu/Si （111） and Cu/SiO2/Si （111） Systems by Neutral Cluster Beam Deposition

The Cu films are deposited on two kinds of p-type Si （111） substrates by ionized duster beam （ICB） technique. The interface reaction and atomic diffusion of Cu/Si （111） and Cu/SiO2/Si （111） systems are studied at different annealing temperatures by x-ray diffraction （XRD） and Rutherford backscattering spectrometry （RBS）. Some significant results are obtained： For the Cu/Si （111） samples prepared by neutral dusters, the interdiffusion of Cu and Si atoms occurs when annealed at 230℃. The diffusion coefficients of the samples annealed at 230℃ and 500℃ are 8.5 ×10^-15 cm^2.s^-1 and 3.0 ×10^-14 cm^2.s^-1, respectively. The formation of the copper-silicide phase is observed by XRD, and its intensity becomes stronger with the increase of annealing temperature. For the Cu/SiO2//Si （111） samples prepared by neutral dusters, the interdiffusion of Cu and Si atoms occurs and copper silicides are formed when annealed at 450℃. The diffusion coefficients of Cu in Si are calculated to be 6.0 ×10^-16 cm^2.s^-1 at 450℃, due to the fact that the existence of the SiO2 layer suppresses the interdiffusion of Cu and Si.     

STUDY OF THE IMPINGEMENT OF IMPULSE WAVE UPON A FLAT PLATE

The impulse wave is made by the weak normal shock discharge from an open end of a shock tube. In order to understand the dynamic characteristics of the impulse wave impinging upon a flat plate, experiments are performed over the shock Mach number range from 1·01 to 1·20. A flat plate is placed downstream, normal to the axis of the shock tube, to simulate the impulse wave impingement on an object. The distance between the exit of the shock tube and flat plate is changed. The baffle plate is installed at the exit of the shock tube. The sizes of the baffle plate and impinging flat plate are varied to investigate the magnitude of the impulse wave impinging upon the flat plate. Computational analysis is applied to model the flow field subject to unsteady, axisymmetric, inviscid, compressible, equations. Computational results well predict the experimented dynamic behavior of the impinging impulse wave. The impulse wave impinging upon the flat plate has a sharp peak of very short rising time and its magnitude decreases with distance from the center of the flat plate. The magnitude of the impulse wave impinging upon the flat plate can be predicted by the empirical equations that are developed in the present study.     

DESIGN SENSITIVITY ANALYSIS AND OPTIMIZATION OF AN ENGINE MOUNT SYSTEM USING AN FRF-BASED SUBSTRUCTURING METHOD

The FRF-based substructuring method is one of the most powerful methods in analyzing the responses of complex built-up structures with high modal density. In this paper, a general procedure for the design sensitivity analysis of a vibro-acoustic system has been presented using the FRF-based substructuring formulation. For an acoustic response function, the proposed method gives a parametric design sensitivity expression in terms of the partial derivatives of the connection element properties and the transfer functions of the substructures. The derived noise sensitivity formula is combined with a non-linear programming module to obtain the optimal design for the engine mount system of a passenger car. The objective function is defined as the area of the interior noise graph integrated over a concerned r.p.m. range. The interior noise variations with respect to the dynamic characteristics of the engine mounts and bushings have been calculated using the proposed sensitivity formulation and transferred to a non-linear optimization software. To obtain the FRFs, a finite element analysis was used for the engine mount structures and experimental techniques were used for the trimmed body including the cabin cavity. The optimization based on the sensitivity analysis gives the ideal stiffness of the engine mount and bushings. The resultant interior noise in the passenger car shows that the proposed method is efficient and accurate.     

浦项中子装置上209Bi中子全截面测量(英文)

在浦项中子装置(PNF) 的100 MeV电子直线加速器上利用透射法和飞行时间法测量了209Bi 的0.1~100 eV的中子全截面。文中对于实验装置特点、用吸收片法拟合本底、拟合中子飞行距离和时间零点的处理过程做了较为详细的描述。测量结果与以前发表的实验数据以及评价数据ENDF/B-VII.1 做了比较,比较结果符合得较好。     

Analytical expressions for the correlation function of a hard sphere dimer fluid

A closed form expression is given for the correlation function of a hard sphere dimer fluid. A set of integral equations is obtained from Wertheim's multidensity Ornstein-Zernike integral equation theory with Percus-Yevick approximation. Applying the Laplace transformation method to the integral equations and then solving the resulting equations algebraically, the Laplace transforms of the individual correlation functions are obtained. By the inverse Laplace transformation, the radial distribution function (RDF) is obtained in closed form out to 3D (D is the segment diameter). The analytical expression for the RDF of the hard dimer should be useful in developing the perturbation theory of dimer fluids.     

表面含磺酸基的介孔分子筛催化剂SBA-15-SO3H的制备及其催化性能

采用直接和后合成两种方法制备出含磺酸基的介孔分子筛SBA-15-SO₃H,用XRD和红外光谱分析制备过程中催化剂结构和组成的变化.结果表明,两种方法制备出的含磺酸基的催化剂都保持了SBA-15分子筛的完整晶体结构,并含有质子酸中心-SO₃H;固体核磁共振表征结果证明,两种方法都使MPTMS存在于分子筛的表面;用N₂吸附-脱附测定了它们的比表面积、孔径和孔容;TGA分析认为,MPTMS在分子筛表面的热稳定性大于300℃,酸碱滴定结果说明,直接法获得的催化剂的酸中心多于后合成法.酯化反应结果表明,直接法合成的催化剂比后合成法具有更高的稳定性,且简便、快捷、高效.     

Purification and Characterization of Cyclic AMP-Binding Protein from Ganoderma lucidum

Cyclic AMP-binding protein was purified 30 fold from the mycelia of Ganoderma lucidum by the methods of ammonium sulfate precipitation, DEAE-cellulose, phospho-cellulose ion exchange chromatography and Sephacryl S-100 gel filtration. The molecular mass of the purified protein is 34.5 kDa and 17 kDa by Sephacryl S-100 gel filtration and SDS-ployacrylamide gel electrophoresis, respectively. From these results it is suggested that the protein has a homometric dimmer structure. The pI of the purified protein is pH 8.2 by native isoelectric focusing gel. The half-life of the protein activity in 10% glycerol at 4 ℃ is 7 d in crude extract, but its half-life is only 3 d under purifying conditions. The optimal conditions of the protein activity are at 1 ℃ and pH 7.5. Its activity is increased 6 times by 1 mmol/L Zn^2 and is slightly inhibited by cGMP,Cu^2 and Mn^2 .     

Perturbation theory for the square-well dimer fluid

An analytical equation of state is presented for the square-well dimer fluid of variable well width (1 ≤ λ ≥ 2) based on Barker-Henderson perturbation theory using the recently developed analytical expression for radial distribution function of hard dimers. The integral in the first- and the second-order perturbation terms utilizes the Tang, Y and Lu, B. C.-Y., 1994, J. chem. Phys., 100, 6665 formula for the Hilbert transform. To test the equation of state, NVT and Gibbs ensemble Monte Carlo simulations for square-well dimer fluids are performed for three different well widths (λ = 1.3, 1.5 and 1.8). The prediction of the perturbation theory is also compared with that of thermodynamic perturbation theory in which the equation of state for the square-well dimer is written in terms of that of square-well monomers and the contact value of the radial distribution function.     

ANALYTICAL AND NUMERICAL STUDY ON SPATIAL FREE VIBRATION OF NON-SYMMETRIC THIN-WALLED CURVED BEAMS

For spatial free vibration of non-symmetric thin-walled circular curved beams, an accurate displacement field is introduced by defining all displacement parameters at the centroidal axis and three total potential energy functionals are consistently derived by degenerating the potential energy for the elastic continuum to that for thin-walled curved beams. The closed-form solutions are newly obtained for in-plane and out-of-plane free vibration analysis of monosymmetric curved beams respectively. Also, two thin-walled curved beam elements are developed using the third and fifth order Hermitian polynomials. In order to illustrate the accuracy and the practical usefulness of the present method, analytical and numerical solutions by this study are presented and compared with previously published results or solutions by ABAQUS' the shell element. Particularly, effects of the thickness curvature as well as the inextensional condition are investigated on free vibration of curved beams with monosymmetric and non-symmetric cross-sections.     

Synthesis of 3-Benzyloxy-6-methyl-7-methoxyphenanthrene-9-carboxaldehyde with Utilize Intramolecular Heck Reaction as the Key Step

The substituted phenanthrene-9-carboxyaldehydes are very important intermediates for the syntheses of phenanthroindolizidine and phenanthroquinolizidine alkaloids. The novel title compound was prepared from the reaction of 5 steps starting from the condensation of 3-methoxyl-4-methyl-phenylacetic acid and 4-（benzyloxy）-2-iodobenzaldehyde, followed by esterification, cyclization, reduction, and oxidation. A new method for the preparation of phenanthrene ring via palladium-catalyzed intramolecular Heck reaction was described. The title compound was characterized by IR, ^1H NMR, ^13C NMR, elemental analysis, and MS.