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101.
Janak KE Tanski JM Churchill DG Parkin G 《Journal of the American Chemical Society》2002,124(16):4182-4183
Mo(PMe3)6 reacts with thiophene to give the eta5-thiophene complex (eta5-C4H4S)Mo(PMe3)3 and the eta5-butadiene-thiolate complex (eta5-C4H5S)Mo(PMe3)2(eta2-CH2PMe2), which are the first examples of (i) eta5-thiophene coordination and (ii) C-S cleavage and hydrogenation by a molybdenum compound. Deuterium labeling studies suggest that the hydrogenation of thiophene may involve an alkylidene intermediate, an observation that has ramifications for the mechanisms of hydrodesulfurization. 相似文献
102.
Heats of adsorption and heats of interaction for natural gas odorants on clay and organo-clay, respectively, were determined by means of wall-coated open-tubular (WCOT) column gas chromatography. The odorants studied are organic thiol and sulfide compounds. Clay stationary phases were created from the synthetic clay Laponite-RD. Subsequent coatings with octadecane created an organo-clay stationary phase. Experimental results show that, as a class, sulfide odorants have larger enthalpies on clay and organo-clay surfaces than thiol odorants. Therefore, we conclude that thiols are less likely to be sequestered on soil surfaces. The effect of hydrated clay surfaces on odorant enthalpies is also presented. Further, we demonstrate that Lewis acid-base chemistry on clay surfaces explains the significant difference in enthalpy magnitudes between the sulfide and thiol classes. 相似文献
103.
We variationally determine the dynamics of bright soliton trains composed of harmonically trapped Bose-Einstein condensates with attractive interatomic interactions. In particular, we obtain the interaction potential between two solitons. We also discuss the formation of soliton trains due to the quantum mechanical phase fluctuations of a one-dimensional condensate. 相似文献
104.
Raman scattering studies of the high-pressure stability of pentaerythritol tetranitrate, C(CH2ONO2)4
Lipinska-Kalita KE Pravica MG Nicol M 《The journal of physical chemistry. B》2005,109(41):19223-19227
High-pressure Raman scattering studies have been performed on a crystalline energetic material, pentaerythritol tetranitrate C(CH2ONO2)4 (PETN), an important secondary explosive. In situ, ambient-temperature investigations employed diamond anvil cell techniques and nitrogen as a quasi-hydrostatic-pressure-transmitting medium. The pressure-induced alterations in the profiles of the Raman lines, including positions, bandwidths, and intensities, were studied in a compression sequence up to about 31.3 GPa and in a subsequent decompression to ambient conditions. The observed changes of the Raman spectra implied that PETN gradually densified and compressed smoothly up to the highest investigated pressures. Compression below 12 GPa gradually shifted all Raman peaks to higher frequencies without significantly changing their relative intensities or bandwidths. At higher pressures, the peak intensities of the Raman spectra decreased considerably and the bands broadened significantly. The Raman spectrum of the material quenched from 31.3 GPa to ambient conditions indicated that no pressure-driven permanent reconstructive modification or decomposition of the PETN structure occurred. That is, the spectral changes were completely reversible upon compression and subsequent decompression to ambient conditions. 相似文献
105.
Aubert B Barate R Boutigny D Couderc F Karyotakis Y Lees JP Poireau V Tisserand V Zghiche A Grauges E Palano A Pappagallo M Pompili A Chen JC Qi ND Rong G Wang P Zhu YS Eigen G Ofte I Stugu B Abrams GS Borgland AW Breon AB Brown DN Button-Shafer J Cahn RN Charles E Day CT Gill MS Gritsan AV Groysman Y Jacobsen RG Kadel RW Kadyk J Kerth LT Kolomensky YG Kukartsev G Lynch G Mir LM Oddone PJ Orimoto TJ Pripstein M Roe NA Ronan MT Wenzel WA Barrett M Ford KE Harrison TJ Hart AJ Hawkes CM Morgan SE 《Physical review letters》2005,95(4):041805
We present results from an analysis of B(0)B(0)--> rho(+)rho(-) using 232 x 10(6) Gamma (4S) --> BB decays collected with the BABAR detector at the PEP-II asymmetric-energy B factory at SLAC. We measure the longitudinal polarization fraction f(L) = 0.978 +/- 0.014(stat) + 0.021 / -0.029(syst) and the CP-violating parameters S(L)= -0.33 +/- 0.24(stat) + 0.08 / -0.14(syst) and C(L)= -0.03 +/- 0.18(stat) +/- 0.09(syst). Using an isospin analysis of B --> rhorho decays, we determine the unitarity triangle parameter alpha. The solution compatible with the standard model is alpha = (100 +/- 13) degrees. 相似文献
106.
Aubert B Barate R Boutigny D Couderc F Gaillard JM Hicheur A Karyotakis Y Lees JP Tisserand V Zghiche A Palano A Pompili A Chen JC Qi ND Rong G Wang P Zhu YS Eigen G Ofte I Stugu B Abrams GS Borgland AW Breon AB Brown DN Button-Shafer J Cahn RN Charles E Day CT Gill MS Gritsan AV Groysman Y Jacobsen RG Kadel RW Kadyk J Kerth LT Kolomensky YG Kukartsev G Lynch G Mir LM Oddone PJ Orimoto TJ Pripstein M Roe NA Ronan MT Shelkov VG Wenzel WA Barrett M Ford KE Harrison TJ Hart AJ Hawkes CM Morgan SE 《Physical review letters》2005,95(4):041804
We present a search for the decay B(-)--> tau(-)nu(tau) in a sample of 88.9 x 10(6) BB pairs recorded with the BABAR detector at the Stanford Linear Accelerator Center B factory. One of the two B mesons from the Gamma(4S) is reconstructed in a hadronic or a semileptonic final state, and the decay products of the other B in the event are analyzed for consistency with a B(-) --> tau(-)nu(tau) decay. We find no evidence of a signal and set an upper limit on the branching fraction of B(B(-) --> tau(-) nu(tau)) < 4.2 x 10(-4) at the 90% confidence level. 相似文献
107.
Aubert B Barate R Boutigny D Couderc F Karyotakis Y Lees JP Poireau V Tisserand V Zghiche A Grauges-Pous E Palano A Pompili A Chen JC Qi ND Rong G Wang P Zhu YS Eigen G Ofte I Stugu B Abrams GS Borgland AW Breon AB Brown DN Button-Shafer J Cahn RN Charles E Day CT Gill MS Gritsan AV Groysman Y Jacobsen RG Kadel RW Kadyk J Kerth LT Kolomensky YG Kukartsev G Lynch G Mir LM Oddone PJ Orimoto TJ Pripstein M Roe NA Ronan MT Wenzel WA Barrett M Ford KE Harrison TJ Hart AJ Hawkes CM Morgan SE 《Physical review letters》2005,94(13):131801
We search for the decay B0-->rho(0)rho(0) in a data sample of about 227x10(6) Upsilon(4S)-->BB decays collected with the BABAR detector at the PEP-II asymmetric-energy e(+)e(-) collider at SLAC. We find no significant signal and set an upper limit of 1.1x10(-6) at 90% C.L. on the branching fraction. As a result, the uncertainty due to penguin contributions on the Cabibbo-Kobayashi-Maskawa unitarity angle alpha measured in B-->rhorho decays is decreased to 11 degrees at 68% C.L. 相似文献
108.
Aubert B Barate R Boutigny D Couderc F Gaillard JM Hicheur A Karyotakis Y Lees JP Tisserand V Zghiche A Palano A Pompili A Chen JC Qi ND Rong G Wang P Zhu YS Eigen G Ofte I Stugu B Abrams GS Borgland AW Breon AB Brown DN Button-Shafer J Cahn RN Charles E Day CT Gill MS Gritsan AV Groysman Y Jacobsen RG Kadel RW Kadyk J Kerth LT Kolomensky YG Kukartsev G Lynch G Mir LM Oddone PJ Orimoto TJ Pripstein M Roe NA Ronan MT Shelkov VG Wenzel WA Barrett M Ford KE Harrison TJ Hart AJ Hawkes CM Morgan SE 《Physical review letters》2005,94(4):041802
We present measurements of the branching fraction and CP-violating asymmetries in the decay B0-->f0(980)K0S. The results are obtained from a data sample of 123 x 10(6) Upsilon(4S)-->BB decays. From a time-dependent maximum likelihood fit, we measure the branching fraction B(B0-->f0(980)(-->pi+pi-)K0)=(6.0+/-0.9+/-0.6+/-1.2)x10(-6), the mixing-induced CP violation parameter S=-1.62(+0.56)(-0.51)+/-0.09+/-0.04, and the direct CP violation parameter C=0.27+/-0.36+/-0.10+/-0.07, where the first errors are statistical, the second systematic, and the third due to model uncertainties. We measure the f0(980) mass and width to be mf0(980)=(980.6+/-4.1+/-0.5+/-4.0) MeV/c2 and Gammaf0(980)=(43(+12)(-9)+/-3+/-9) MeV/c2, respectively. 相似文献
109.
Reaction of a solution of CuSO(4) and S,S'-diphenylsulfimide, Ph(2)SNH 1, with sodium salts of trimesic acid (H(3)tma) in MeOH gives the 2-D coordination network [Cu(3)(Ph(2)SNH)(6)(tma)(2)] in which each trimesate is bound to three copper centres. Addition of other solvents to the reaction mixture causes a change in the shape of the network. By this route, three forms have been prepared and characterised by X-ray crystallography. These include the known honeycomb, 2, and brick-wall, 3, motifs and a herringbone, 4, arrangement which is novel for transition metal-containing trimesate complexes. Key to the supramolecular isomerism observed is the ability of 1 to facilitate structural isomerism at copper(II) centres. In contrast to 2 in which the copper centres are square planar, 4 is analogous to an inter-allogon, with both planar and tetrahedral copper centres. Also prepared is a related complex which is composed of discrete units of three copper centres. These are further linked into a 2-D network by hydrogen bonds. 相似文献
110.
Aubert B Barate R Boutigny D Couderc F Gaillard JM Hicheur A Karyotakis Y Lees JP Tisserand V Zghiche A Palano A Pompili A Chen JC Qi ND Rong G Wang P Zhu YS Eigen G Ofte I Stugu B Abrams GS Borgland AW Breon AB Brown DN Button-Shafer J Cahn RN Charles E Day CT Gill MS Gritsan AV Groysman Y Jacobsen RG Kadel RW Kadyk J Kerth LT Kolomensky YG Kukartsev G Lynch G Mir LM Oddone PJ Orimoto TJ Pripstein M Roe NA Ronan MT Shelkov VG Wenzel WA Ford KE Harrison TJ Hawkes CM Morgan SE Watson AT 《Physical review letters》2004,93(18):181806
We search for B meson decays into two-body combinations of eta, eta', omega, and phi mesons from 89 x 10(6) BB pairs collected with the BABAR detector at the PEP-II asymmetric-energy e+e- collider at SLAC. We find the branching fraction B(B0-->etaomega)=(4.0(+1.3)(-1.2)+/-0.4)x10(-6) with a significance of 4.3 sigma. For the other decay modes we set the following 90% confidence level upper limits on the branching fractions, in units of 10(-6): B(B0-->etaeta)<2.8, B(B0-->etaeta')<4.6, B(B0-->eta'eta')<10, B(B0-->eta'omega)<2.8, B(B0-->etaphi)<1.0, B(B0-->eta'phi)<4.5, and B(B0-->phiphi)<1.5. 相似文献