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151.
In the present study, a reverse-phase high performance liquid chromatography method was developed, validated and applied for the simultaneous determination of gliquidone, pioglitazone hydrochloride and verapamil in tablets and human serum. Chromatographic separation was achieved on a C18 column (5 μm, 25 × 0.46 cm) with a mobile phase consisting of methanol-water-acetonitrile (80:10:10 v/v/v) with a flow rate of 0.7 mL/min and pH adjusted to 3.50 with phosphoric acid at 230 nm. Glibenclamide was used as internal standard. The experimentally derived limit of detection and limit of quantitation were determined to be 0.24, 0.93, 0.40, and 0.80, 3.11, 1.36 μg/mL for gliquidone, pioglitazone, and verapamil, respectively. There were no interfering peaks due to the excipients present in the pharmaceutical tablets. Thus, the proposed method is simple and suitable for the simultaneous analysis of active ingredients in dosage forms and human serum. 相似文献
152.
Copper(II) complex of a Schiff base ligand derived from pyrrolcarbaldehyde and o‐phenylenediamine (H2L) has been synthesized and encapsulated in Y‐zeolite matrix. The hybrid material has been characterized by elemental analysis, IR and UV‐Vis spectroscopic studies as well as X‐ray diffraction (XRD) pattern. The encapsulated copper(II) catalyst is an active catalyst for the oxidation of cyclooctene and cyclohexene using H2O2 as oxidant. Under the optimized reaction conditions 81% conversion of cyclohexene with 65% selectivity for 2‐cyclohexenone formation and 87% conversion of cyclooctene with 46% selectivity for epoxide formation were obtained. 相似文献
153.
Humayun Ajaz Sajjad Hussain Muhammad Altaf Helen Stoeckli‐Evans Anvarhusein A. Isab Rashid Mahmood Shahnila Altaf Saeed Ahmad 《中国化学》2011,29(2):254-258
Antimony(III) complexes of thioamides [thioamides=thiourea (Tu), N,N′‐dimethylthiourea (Dmtu), tetramethylthiourea (Tmtu), imidazolidine‐2‐thione (Imt) and diazinane‐2‐thione (Diaz)] with the general formulae, Sb(thione)nCl3 (n=1, 2, 2.5, 3) were prepared and characterized by elemental analysis, IR and NMR (1H, 13C) spectroscopic methods. The spectral data of the complexes are consistent with the coordination of the thiones to antimony(III). The crystal structure of one of them, {[Sb(Imt)2Cl2]2(μ2‐Imt)}Cl2 ( 1 ), was determined by X‐ray crystallography, which shows that the complex is dinuclear consisting of two [Sb(Imt)2Cl2] units bridged by an Imt molecule. In 1 , the antimony atom is bonded to two chlorine atoms, two sulfur atoms of coordinated Imt molecules and one sulfur atom of a bridging Imt molecule. The antimony environment can be considered to be distorted octahedral with one Cl? ion weakly bound to antimony. 相似文献
154.
A method is described for the simultaneous determination of paracetamol, tizanidine, and diclofenac in mixtures. The method was based on HPLC separation of the three drugs followed by UV detection at 254 nm. The separation was carried out on a Hypersil ODS, C18 (250 x 4.6 mm id, 10 microm particle size) column using the mobile phase aqueous 0.2% ammonium carbonate-methanol (60 + 40, v/v) at a flow rate of 1 mL/min. The linear regression analysis data were used for the regression curve in the range of 170-10 000 ng/mL for paracetamol, 120-10 000 ng/mL for tizanidine, and 20-10 000 ng/mL for diclofenac. No chromatographic interference from tablet excipients was found. In order to check the selectivity of the proposed method, degradation studies were carried out using hydrolysis (acid, basic, and neutral), thermolysis, and oxidation. The developed method, after being validated in terms of precision, robustness, recovery, LOD, and LOQ, was successively applied to the analysis of pharmaceutical formulations and human serum. 相似文献
155.
Mahmoud Reza Sohrabi Azam Marjani Sadegh Moradi Mehran Davallo Saeed Shirazian 《Applied Mathematical Modelling》2011
Chemical absorption of carbon dioxide was studied theoretically using hollow-fiber membrane contactors in this work. A 2D mathematical model was developed to study CO2 transport through hollow-fiber membrane contactors. The model considers axial and radial diffusion in the membrane contactor. It also considers convection in the tube and shell side with chemical reaction. The finite element method (FEM) was used to solve the model equations. Modeling predictions were validated with the experimental data obtained from literature for CO2 absorption in amine aqueous solutions as solvent. The modeling predictions were in good agreement with the experimental data for different values of gas and liquid velocities. The liquid solvents considered for this study include aqueous solutions of monoethanolamine (MEA), diethanolamine (DEA), N-methyldiethanolamine (MDEA), 2-amino-2-methyl-1-propanol (AMP) and potassium carbonate (K2CO3). The simulation results indicated that amine aqueous solutions were better than K2CO3 aqueous solution for CO2 absorption. Also simulation results revealed that the removal of CO2 with aqueous solution of MEA was the highest among the amines solvents. The hollow-fiber membrane contactors showed a great potential in the area of CO2 absorption. 相似文献
156.
Saeed YaghoubiSiamak Noori Amir Azaron Reza Tavakkoli-Moghaddam 《European Journal of Operational Research》2011,215(3):670-678
This article models the resource allocation problem in dynamic PERT networks with finite capacity of concurrent projects (COnstant Number of Projects In Process (CONPIP)), where activity durations are independent random variables with exponential distributions, and the new projects are generated according to a Poisson process. The system is represented as a queuing network with finite concurrent projects, where each activity of a project is performed at a devoted service station with one server located in a node of the network. For modeling dynamic PERT networks with CONPIP, we first convert the network of queues into a stochastic network. Then, by constructing a proper finite-state continuous-time Markov model, a system of differential equations is created to solve and find the completion time distribution for any particular project. Finally, we propose a multi-objective model with three conflict objectives to optimally control the resources allocated to the servers, and apply the goal attainment method to solve a discrete-time approximation of the original multi-objective problem. 相似文献
157.
Halim M Kennedy RD Suzuki M Khan SI Diaconescu PL Rubin Y 《Journal of the American Chemical Society》2011,133(17):6841-6851
Gold(I), silver(I), and copper(I) phosphine complexes of 6,9,12,15,18-pentaaryl[60]fullerides 1a and 1b, namely, [(4-MeC(6)H(4))(5)C(60)]Au(PPh(3)) (2a), [(4-t-BuC(6)H(4))(5)C(60)]Au(PPh(3)) (2b), [(4-MeC(6)H(4))(5)C(60)]Ag(PCy(3)) (3a), [(4-t-BuC(6)H(4))(5)C(60)]Ag(PPh(3)) (3b), [(4-t-BuC(6)H(4))(5)C(60)]Ag(PCy(3)) (3c), [(4-MeC(6)H(4))(5)C(60)]Cu(PPh(3)) (4a), and [(4-t-BuC(6)H(4))(5)C(60)]Cu(PPh(3)) (4b), have been synthesized and characterized spectroscopically. All complexes except for 3c were also characterized by single-crystal X-ray diffraction. Several coordination modes between the cyclopentadienyl ring embedded in the fullerene and the metal centers are observed, ranging from η(1) with a slight distortion toward η(3) in the case of gold(I), to η(2)/η(3) for silver(I), and η(5) for copper(I). Silver complexes 3a and 3b are rare examples of crystallographically characterized Ag(I) cyclopentadienyls whose preparation was possible thanks to the steric shielding provided by fullerides 1a and 1b, which stabilizes these complexes. Silver complexes 3a and 3b both display unexpected coordination of the cyclopentadienyl portion of the fulleride anion with Ag(I). DFT calculations on the model systems (H(5)C(60))M(PH(3)) and CpMPH(3) (M = Au, Ag, or Cu) were carried out to probe the geometries and electronic structures of these metal complexes. 相似文献
158.
Monreal MJ Khan SI Kiplinger JL Diaconescu PL 《Chemical communications (Cambridge, England)》2011,47(32):9119-9121
A new inverted sandwich of a μ-η(6),η(6)-toluene diuranium complex reacted with quinoxaline to form a tetranuclear macrocycle with ferrocene diamide uranium(IV) vertices and reduced quinoxaline edges. 相似文献
159.
Mohammad Reza Yaftian Saeed Rayati Daryoush Emadi Dominique Matt 《Analytical sciences》2006,22(8):1075-1078
The preparation of a lead-selective electrode based on 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis-(diphenylphosphinoylmethoxy)calix[4]arene (1) as an ionophore is reported. The plasticized PVC membrane containing 30% PVC, 57% ortho-nitrophenyloctylether (NPOE), 4% sodium tetraphenylborate (NaTPB) and 9% ionophore 1 was directly coated on a graphite electrode. It exhibits a nearly Nernstian slope of 28.0 +/- 0.2 mV decade(-1) over a concentration range of 1 x 10(-5) - 1 x 10(-2) mol dm(-3) with a detection limit of 1.4 x 10(-6) mol dm(-3). The response time of the electrode was found to be ca. 17 s. The potential of the sensor was independent of the pH variation in the range 3.5 - 5.0. The selectivity of the electrode performance towards lead ions over Th4+, La3+, Sm3+, Dy3+, Y3+, Ca2+, Sr2+, Cd2+, Mn2+, Zn2+, Ni2+, Co2+, NH4+ Ag+, Li+, Na+ and K+ ions was investigated. The prepared electrode was used successfully as an indicator electrode for a potentiometric titration of a lead solution using a standard solution of EDTA. The applicability of the sensor for Pb2+ measurements in various synthetic water samples spiked with lead nitrate was also checked. 相似文献
160.
Zahra Talebpour Saeed Maesum Mehdi Jalali-Heravi Mojtaba Shamsipur 《Analytical sciences》2003,19(7):1079-1082
A 1H-NMR procedure based on an analysis of its data by a multivariate calibration method was conducted for the simultaneous determination of theophylline and caffeine in synthetic and real samples. Partial least squares regression (PLS) was chosen as the calibration method. The methyl signals of theophilline at 3.36 and 3.54 ppm that overlapped with those of caffeine were significant characteristics which were employed in this study for their analyses. The proposed method was successfully applied to recovery studies of theophylline and caffeine from real tablet samples. 相似文献