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111.
Novel 2,3-dihydro-4-pyridinones were synthesized via the reaction of curcumin and primary amines or amine acetates under microwave irradiation. Montmorillonite K-10 was used as a catalyst. Reaction times did not exceed 120 s. The structures of the compounds were established by elemental analysis and from their mass, 1H- and 13C-NMR spectra. 相似文献
112.
Ali Reza Fakhari Saeed Nojavan Samad Nejad Ebrahimi Christopher John Evenhuis 《Journal of separation science》2010,33(14):2153-2159
This study investigated the use of ultrasound‐assisted extraction to improve the extraction efficiency of morphine, codeine and thebaine from the papaver plants. Extraction conditions such as type of solvent, temperature, duration, frequency and power level of ultrasonic were optimized and the influences of different parameters on resolution of alkaloids in CE were studied. The optimized condition for CE separation includes a sodium phosphate buffer (100 mM, pH 3.0) containing 5 mM α‐CD. The optimized extraction conditions for ultrasound‐assisted extraction was an extraction time of 1 h, an ultrasonic frequency of 60 kHz with water–methanol (80:20) at 40°C as the extraction solvent. The LOD for alkaloids was found to be 0.1 μg/mL at a signal‐to‐noise ratio of 3:1. The RSDs for peak areas were in the range of 1.4–4.4%. The amounts of opium alkaloids (mg/100 g dried sample) in four Iranian papaver plants were found to be in the range of 7.8–8.7 (morphine), 5.5–9.5 (codeine) and 1.4–10.4 (thebaine). It should be emphasized that no cleanup of the filtered extract was required; hence, direct determination after extraction drastically simplifies the analytical process. 相似文献
113.
Synthesis and antimicrobial activity of some novel 2-(substituted fluorobenzoylimino)-3-(substituted fluorophenyl)-4-methyl-1,3-thiazolines 总被引:1,自引:0,他引:1
The synthesis of several 2-(substituted fluorobenzoylimino)-3-(substituted fluorophenyl)-4-methyl-1,3-thiazolines (2a-t) was carried out by base-catalyzed cyclization of corresponding 1-(fluorobenzoyl)-3-(fluorophenyl)thioureas (1a-t) with 2-bromoacetone in aqueous medium. The structures of the synthesized compounds were confirmed by spectral and elemental analysis. All synthesized compounds were evaluated for in vitro antibacterial activity using Gram-positive bacteria (Staphylococcus aureus, Bacillus subtilis) and Gram-negative bacteria (Escherichia coli, Pseudomonas aeruginosa). The minimum inhibitory concentration (MIC) was determined for the most active compounds. In vitro antifungal activity was also determined against the five fungal species (Rhizopus oryzae, Fusarium oxysporum, Aspergillus terreus, A. niger and A. fumigatus). 相似文献
114.
Mohammed Taghi Zafarani-Moattar Saeed Nasiri 《The Journal of chemical thermodynamics》2010,42(9):1071-1078
(Liquid + liquid) equilibrium (LLE) for the {poly ethylene glycol di-methyl ether 2000 (PEGDME2000) + Na2HPO4 + H2O} system have been determined experimentally at T = (298.15, 308.15, 313.15, and 318.15) K. The effects of temperature on the binodals and tie-lines for the investigated aqueous two-phase system (ATPS) have been studied. An empirical non-linear expression developed by Merchuk was used for reproducing the experimental binodal data. In this work, the three fitting parameters of the Merchuk equation were obtained with the temperature dependence expressed in the linear form with (T ? T0) K as a variable. Furthermore, the modified local composition segment-based NRTL and Wilson models and also osmotic virial equation were used to describe the LLE data of the studied system. Also, the effects of the type of salt on LLE are discussed. In addition, the effects of end groups of the polymers PEGDME2000 and poly ethylene glycol 2000 on phase forming ability were studied. The complete phase diagram for the poly ethylene {glycol di-methyl ether 2000 (PEGDME2000) + Na2HPO4 + H2O} system has also been determined at T = 298.15 K. 相似文献
115.
The synchronization problem for a general class of uncertain chaotic systems is addressed. The underlying systems may be perturbed by unknown time-varying parameters, unstructured uncertainties, and external disturbances. Meanwhile, the time-varying parameters and disturbances are neither required to be periodic nor to have known bounds. Assuming the disturbances are L(2) signals, an adaptive control incorporated with H(∞) control technique is employed to construct a robust adaptive synchronization algorithm. Then, removing such assumption, a novel adaptive-based method is developed to achieve the goal of synchronization. In order to demonstrate the effectiveness of the proposed algorithms, such methods are applied to solve the synchronization problem of uncertain chaotic Chua's circuits. 相似文献
116.
Rodolfo Gambini Jorge Pullin Saeed Rastgoo 《General Relativity and Gravitation》2011,43(12):3569-3592
We recently studied gravity coupled to a scalar field in spherical symmetry using loop quantum gravity techniques. Since there
are local degrees of freedom one faces the “problem of dynamics”. We attack it using the “uniform discretization technique”.
We find the quantum state that minimizes the value of the master constraint for the case of weak fields and curvatures. The
state has the form of a direct product of Gaussians for the gravitational variables times a modified Fock state for the scalar
field. In this paper we do three things. First, we verify that the previous state also yields a small value of the master
constraint when one polymerizes the scalar field in addition to the gravitational variables. We then study the propagators
for the polymerized scalar field in flat space-time using the previously considered ground state in the low energy limit.
We discuss the issue of the Lorentz invariance of the whole approach. We note that if one uses real clocks to describe the
system, Lorentz invariance violations are small. We discuss the implications of these results in the light of Hořava’s Gravity at the Lifshitz point and of the argument about potential large Lorentz violations in interacting field theories of Collins et al. 相似文献
117.
Alireza Khorsandi Saeed Ghavami Sabouri Somaieh Fathi Marzieh Asadnia-Jahromi 《Optics & Laser Technology》2011,43(5):956-959
We have reported a modified V-shaped external cavity, which is constructed around a commercial diode laser operating at a center wavelength of λ=785 nm by adding a new coated glass plate with about 50% reflectivity to the cavity. This allows simultaneous dual-wavelengths operation in the vicinity of Δνmin=0.18 THz to Δνmax=0.22 THz, which can be used as laser source for terahertz generation either for semiconductor devices or nonlinear schemes. 相似文献
118.
Mansoor FarbodMorteza Zargar Shoushtari Saeed Parhoodeh 《Physica B: Condensed Matter》2011,406(2):205-210
In this paper we have introduced a simple method for the fabrication of aluminum doped zinc oxide (AZO) nanoparticles. The Zn1−xAlxO nanoparticles with different concentrations of Al (x=0.01, 0.03, 0.06, 0.09, 0.12) were fabricated successfully by this method. The samples were analyzed by the use of several techniques such as SEM, EDX, XRD, PL and UV-vis spectroscopy. The SEM images showed that the fabricated nanoparticles had spherical shapes. The XRD patterns of the samples indicated that the Al atoms substituted in the Zn positions in the crystal lattice of ZnO and there were some changes in the lattice parameters. A blue shift in the λmax of the absorption and a red shift in the λmax of the emission were observed. The results also indicated that the amount of shifts had a direct relationship with the changes in the lattice parameters. 相似文献
119.
Khazaei M Liang Y Bahramy MS Pichierri F Esfarjani K Kawazoe Y 《J Phys Condens Matter》2011,23(40):405403
We have performed a set of first-principles simulations to consider the possible phase transitions in molecular crystals of HCN under high pressure. Our calculations reveal several transition paths from the orthorhombic phase to tetragonal and then to triclinic phases. The transitions from the orthorhombic to the tetragonal phases are of the second order, whereas those from the tetragonal to the triclinic phases turn out to be of the first-order type and characterized by an abrupt decrease in volume. Our calculations show that, by adjustment of the temperature and pressure of the HCN molecular crystal, novel layered and polymeric crystals with insulating, semiconducting or metallic properties can be found. Based on our simulation results, two different crystal formation mechanisms are deduced. The stabilities of the predicted structures at ambient pressure are further assessed by performing phonon or MD simulations. In addition, the electron transport properties of the predicted polymers are obtained using the non-equilibrium Green's function technique combined with density functional theory. The results show that the polymers have metallic-like I-V characteristics. 相似文献
120.
Yaghoub Haghighatnia Saeed Balalaie Hamid Reza Bijanzadeh 《Helvetica chimica acta》2012,95(5):818-824
Some new amidated fentanyl (=N‐[1‐(2‐phenylethyl)piperidin‐4‐yl]‐N‐phenylpropanamide) analogs with a 4‐(N‐phenylamido)piperidine scaffold and additional amide bonds have been designed and synthesized through Ugi four‐component reaction (Ugi‐4CR). Good‐to‐high yields, diversity‐oriented synthesis, and possible applications in drug discovery are advantages of this approach. 相似文献