全文获取类型
收费全文 | 324355篇 |
免费 | 6792篇 |
国内免费 | 3361篇 |
专业分类
化学 | 160323篇 |
晶体学 | 5263篇 |
力学 | 16613篇 |
综合类 | 228篇 |
数学 | 46619篇 |
物理学 | 105462篇 |
出版年
2022年 | 1850篇 |
2021年 | 2400篇 |
2020年 | 2794篇 |
2019年 | 2913篇 |
2018年 | 11729篇 |
2017年 | 12582篇 |
2016年 | 8737篇 |
2015年 | 4248篇 |
2014年 | 5132篇 |
2013年 | 11151篇 |
2012年 | 13100篇 |
2011年 | 22670篇 |
2010年 | 14281篇 |
2009年 | 14322篇 |
2008年 | 19221篇 |
2007年 | 22455篇 |
2006年 | 8226篇 |
2005年 | 13909篇 |
2004年 | 9733篇 |
2003年 | 9104篇 |
2002年 | 6854篇 |
2001年 | 6779篇 |
2000年 | 5425篇 |
1999年 | 4175篇 |
1998年 | 3308篇 |
1997年 | 3240篇 |
1996年 | 3241篇 |
1995年 | 2991篇 |
1994年 | 2797篇 |
1993年 | 2579篇 |
1992年 | 3173篇 |
1991年 | 3038篇 |
1990年 | 2977篇 |
1989年 | 2953篇 |
1988年 | 2940篇 |
1987年 | 2925篇 |
1986年 | 2755篇 |
1985年 | 3477篇 |
1984年 | 3474篇 |
1983年 | 2743篇 |
1982年 | 2843篇 |
1981年 | 2873篇 |
1980年 | 2632篇 |
1979年 | 2978篇 |
1978年 | 2976篇 |
1977年 | 3009篇 |
1976年 | 2879篇 |
1975年 | 2605篇 |
1974年 | 2559篇 |
1973年 | 2552篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
71.
Tuning the Basicity of Cyano‐Containing Ionic Liquids to Improve SO2 Capture through Cyano–Sulfur Interactions
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Guokai Cui Fengtao Zhang Xiuyuan Zhou Prof. Haoran Li Prof. Jianji Wang Prof. Congmin Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(14):5632-5639
A new approach has been developed to improve SO2 sorption by cyano‐containing ionic liquids (ILs) through tuning the basicity of ILs and cyano–sulfur interaction. Several kinds of cyano‐containing ILs with different basicity were designed, prepared, and used for SO2 capture. The interaction between these cyano‐containing ILs and SO2 was investigated by FTIR and NMR methods. Spectroscopic investigations and quantum chemical calculations showed that dramatic effects on SO2 capacity originate from the basicity of the ILs and enhanced cyano–sulfur interaction. Furthermore, the captured SO2 was easy to release by heating or bubbling N2 through the ILs. This efficient and reversible process, achieved by tuning the basicity of ILs, is an excellent alternative to current technologies for SO2 capture. 相似文献
72.
I. F. Golovnev E. I. Golovneva L. A. Merzhievsky V. M. Fomin V. E. Panin 《Physical Mesomechanics》2015,18(3):179-186
Molecular dynamics simulation was performed to study the formation of cluster structure, interfaces, and surfaces with different curvature radii in a perfect nanocrystal passed through by a nonlinear wave. It is shown that this process is a type of nanostructure self-organization in response to an external energy flux with subsequent development of a strong rotational field. 相似文献
73.
74.
75.
Mathematical Notes - 相似文献
76.
The satisfiability (SAT) problem is a core problem in computer science. Existing studies have shown that most industrial SAT instances can be effectively solved by modern SAT solvers while random SAT instances cannot. It is believed that the structural characteristics of different SAT formula classes are the reasons behind this difference. In this paper, we study the structural properties of propositional formulas in conjunctive normal form (CNF) by the principle of structural entropy of formulas. First, we used structural entropy to measure the complex structure of a formula and found that the difficulty solving the formula is related to the structural entropy of the formula. The smaller the compressing information of a formula, the more difficult it is to solve the formula. Secondly, we proposed a -approximation strategy to approximate the structural entropy of large formulas. The experimental results showed that the proposed strategy can effectively approximate the structural entropy of the original formula and that the approximation ratio is more than 92%. Finally, we analyzed the structural properties of a formula in the solution process and found that a local search solver tends to select variables in different communities to perform the next round of searches during a search and that the structural entropy of a variable affects the probability of the variable being flipped. By using these conclusions, we also proposed an initial candidate solution generation strategy for a local search for SAT, and the experimental results showed that this strategy effectively improves the performance of the solvers CCAsat and Sparrow2011 when incorporated into these two solvers. 相似文献
77.
Acta Mathematica Sinica, English Series - We are interested in the existence and asymptotic behavior for the least energy solutions of the following fractional eigenvalue problem $$\left({\rm{P}}... 相似文献
78.
Acoustical Physics - The problem of pulsed excitation of an acoustic waveguide with a constant cross section is considered. Absorption is ignored. As the most general model of such a waveguide,... 相似文献
79.
Mohammad Azam Saud I. Al-Resayes Agata Trzesowska-Kruszynska Rafal Kruszynski S.F. Adil N.K. Lokanath 《Journal of Saudi Chemical Society》2019,23(5):636-641
A new derivative of dioxouranium(VI) salen complex, [UO2(L)(pyridine)], where [L = N,N′-Bis(2-hydroxybenzylidene)-2,2-dimethyl-1,3-propanediamine] is synthesized and characterized by elemental analysis (C, H, N), FT-IR, ESI-MS spectrometry, UV/Vis, fluorescence, 1H and 13C NMR spectroscopy and thermal gravimetric (TG) study. Furthermore, the single crystal X-ray diffraction measurements of the complex were carried out at 100 and 273 K. The crystal structure measurements revealed that the complex has distorted pentagonal bipyramidal geometry with uranium atom located at the centre and bonded to two phenoxy oxygen and two azomethine nitrogen in tetradenate fashion and one nitrogen from pyridine making it seven coordinated. In addition, the photoluminescence property of the complex was also recorded. 相似文献
80.
随着经济的飞速发展,社会对能源的需求日益扩大,对工业废水的无害化处理也提出了更高的要求。光催化燃料电池 (photocatalytic fuel cell, PFC) 在燃料电池中引入半导体光催化材料作为电极,实现了有机污染物高效降解和同步对外产电的双重功能,在废水无害化与资源化利用方面具有潜在的应用价值。半导体光催化电极是PFC系统高效运行的核心组件,增强其可见光响应和光生载流子分离是提高PFC性能的关键策略。反应器结构设计和运行参数优化也有利于改善PFC性能。本文从PFC基本原理和应用入手,综述了PFC在环境污染物资源化处理中的研究进展,并详细阐述了提高PFC的污染控制性能和产电效率的优化手段,为进一步设计高效稳定的PFC系统并实现其在水污染控制和清洁能源生产中的应用提供理论指导。 相似文献