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951.
The role of intrachain dipole interactions in the formation of a lamellar morphology is investigated using a number of statistical vinylidene fluoride copolymers with nonpolar components as an example. It is shown that the large and interlamellar spacings regularly increase as the intrachain dipole interaction weakens. 相似文献
952.
The mechanism of X-ray waveguide-resonance propagation or the radiation superstream model, which can become the ground of X-ray nanophotonics, is discussed briefly. Some attention is devoted to features consideration of the simplest devices characterized by the waveguide-resonance transportation of X-ray beams. The experimental data showing the user possibilities of a simplest waveguide-resonators application for diffractometry are presented. We discuss the main reasons to improve the metrological characteristics for total reflection X-ray fluorescence (TXRF) analytical method in case when the target exciting beam is formed by a waveguide-resonator. Some problems appearing during the waveguide-resonator application are formulated. 相似文献
953.
Summary A non-destructive method is described for the determination of major and minor constituents in archeological specimens by energy-dispersive X-ray fluorescence. Homogeneity tests are made by measuring at various sites of the specimen. In the same way, mean values are obtained for inhomogeneous specimen without taking samples. For calibration, powder standards are used. In case of the determination of elements with numbers up to 14 (Si) a vacuum chamber is used and the dimensions of the specimens are limited by the dimensions of that vacuum chamber, whereas for the determination of elements from K up to U specimens of any size, form or weight are suitable.
Zerstörungsfreie Analyse von archäologischen Proben mit Hilfe der Energie-dispersiven Röntgenfluorescenzanalyse
Zusammenfassung Eine zerstörungsfreie Methode für die Bestimmung von Haupt- und Nebenbestandteilen in archäologischen Proben mit Hilfe der Energie-dispersiven Röntgenfluorescenzanalyse wird beschrieben. Für Homogenitätstests wird an mehreren Stellen der Probe gemessen. In der gleichen Weise werden für inhomogene Proben Mittelwerte erhalten ohne Probenahme. Für die Eichung werden Pulverstandards verwendet. Im Falle der Bestimmung von Elementen mit Ordnungszahlen bis 14 (Si) wird eine Vakuumkammer eingesetzt, und die Dimensionen der Proben sind durch die Dimensionen dieser Vakuumkammer begrenzt, während für die Bestimmung der Elemente K bis U Proben jeder Größe, jeder Form oder jeden Gewichts verwendbar sind.相似文献
954.
J. Bartella K. Kastner K. Röll und K. -H. Schuller 《Fresenius' Journal of Analytical Chemistry》1987,329(2-3):289-291
Summary Besides functional behaviour of coatings their resistivity against corroding attack is a crucial criterion for quality. The application of special corroding and abrading tests yields after short times predictions about stability of the product in practical use. A number of tests have been applied to thin magnetic storage media. Besides tests of function and visual observations with light- and scanning electron microscopes, AES- and XPS-investigations were applied to discuss corrosion resistivity. 相似文献
955.
956.
K. Stein und F. Umland 《Fresenius' Journal of Analytical Chemistry》1986,323(2):176-177
Ohne Zusammenfassung
Wir danken dem Fonds der Chemischen Industrie für finanzielle Unterstützung. 相似文献
Trace analysis of lead, cadmium and manganese in honey and sugar
Wir danken dem Fonds der Chemischen Industrie für finanzielle Unterstützung. 相似文献
957.
E. S. Filatov S. V. Sysoev Ludmila N. Zelenina Tamara P. Chusova V. A. Logvinenko P. P. Semyannikov I. K. Igumenov 《Journal of Thermal Analysis and Calorimetry》2006,86(2):537-539
Thermal behaviour
of a series of lithium β-diketonates: Li(dpm) (dpm=dipivaloylmethanate
(2,2,6,6-tetramethylheptane-3,5- dionate)), Li(pta) (pta=pivaloyltrifluoracetonate
(2,2-dimethyl-6,6,6-trifluoro-3,5-hexanedionate)), Li(tfa) (tfa=trifluoracetylacetonate
(1,1,1-trifluoro-2,4-pentandionate)), Li(hfa) (hfa=hexafluoracetylacetonate
(1,1,1,5,5,5-hexafluoro-2,4-pentandionate)) has been investigated. Gas phase
composition of these complexes has been established. Temperature dependences
of vapor pressure of lithium compounds were obtained by static and dynamic
methods, and thermodynamic parameters were calculated. Dependence of compound
volatility on ligand structure is shown. For Li(dpm) detailed investigation
has been done by differential scanning calorimetry (DSC). 相似文献
958.
959.
Praveen K. Tandon Gayatri Sumita Sahgal Manish Srivastava Santosh B. Singh 《应用有机金属化学》2007,21(3):135-138
Catalytic activities of three transition metals, as iridium (III) chloride, rhodium (III) chloride and palladium (II) chloride, were compared in the oxidation of six aromatic aldehydes (benzaldehyde, p‐chloro benzaldehyde, p‐nitro benzaldehyde, m‐nitro benzaldehyde, p‐methoxy benzaldehyde and cinnamaldehyde), two hydrocarbons (viz. (anthracene and phenanthrene)) and one aromatic and one cyclic alcohol (cyclohexanol and benzyl alcohol) by 50% H2O2. The presence of traces (substrate: catalyst ratio equal to 1:62500 to 1:1961) of the chlorides of iridium(III), rhodium(III) and palladium(II) catalyze these oxidations, resulting in good to excellent yields. It was observed that in most of the cases palladium(II) chloride is the most efficient catalyst. Conditions for the highest and most economical yields were obtained. Deviation from the optimum conditions decreases the yields. Oxidation in aromatic aldehydes is selective at the aldehydeic group only and other groups remain unaffected. This new, simple and economical method, which is environmentally safe, also requires less time. Reactive species of catalysts, existing in the reaction mixture are also discussed. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
960.
A. I. Maksimov 《Thermophysics and Aeromechanics》2007,14(4):469-492
The paper briefly describes the life and activities of F.A. Zander and Yu.V. Kondratyuk (A.I. Shargei), pioneers of domestic
rocket engineering who made a significant contribution to the development of cosmonautics and rocket technologies. The main
ideas and proposals of these prominent scientists and inventors in the field of rocket and space engineering, which found
their application in space conquering, are considered.
To the 120th anniversary of F.A. Zander and 110th anniversary of Yu.V. Kondratyuk 相似文献