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891.
We report X-ray absorption near edge structures (XANES) study of CeAl2 thin films of various thicknesses, 40-120 nm, at Al K- and Ce L3-edges. The threshold of the absorption features at the Al K-edge shifts to the higher photon energy side as film thickness decreases, implying a decreased in Al p-orbital charges. On the other hand, from Ce L3-edge spectra, we observed a decrease in the 5d4f occupancy as the surface-to-bulk ratio increases. The valence of Ce in these thin films, as revealed by the Ce L3-edge spectral results, is mainly trivalent. From a more detailed analysis we found a small amount of Ce4+ contribution, which increases with decreasing film thickness. Our results indicate that the surface-to-bulk ratio is the key factor which affects the electronic structure of CeAl2 thin films. The above observations also suggest that charge transfer from Al to Ce is associated with the decrease of the film thickness. 相似文献
892.
O. Životský K. Postava L. Kraus M. Foldyna J. Pištora 《Journal of magnetism and magnetic materials》2006
In this paper we investigate the surface magnetic properties of as-quenched (AQ) CoFeCrBSi ribbons prepared by planar flow casting method with using magneto-optic Kerr effect (MOKE). Measured hysteresis loops in longitudinal and transversal configurations enable us to obtain the information of ribbons surface magnetic properties. Moreover, we suggest new magneto-optic method, which is based on measurements of magneto-optical effects depending on DC current flowing through the ribbon. Experimental data of AQ ribbons are then compared with the model, which describes the influence of incidence angle on magneto-optical angles. 相似文献
893.
Nanosize aluminum substituted nickel zinc ferrites were prepared through aerosol route and characterized using TEM, XRD, magnetic measurements and Mössbauer spectroscopy. The particle size of as obtained samples was found to be ∼10 nm which increases up to ∼85 nm upon annealing at 1200 °C. The unit cell parameter ‘a’ decreases linearly with concentration of aluminum due to the small ionic radius of aluminum. The saturation magnetization for all the samples after annealing at 1200 °C lies in the range 12.9–72.6 emu/g and decreases linearly with concentration of aluminum. Room temperature Mössbauer spectra of all as obtained samples of ferrite compositions exhibited a broad doublet suggesting super paramagnetic nature. This doublet is further resolved into two doublets and assigned to the surface region and internal region atoms of the particles. The samples annealed at 1200 °C show broad sextets, which were fitted with five sextets, indicating different local environment of both tetrahedrally and octahedrally coordinated Fe cation. 相似文献
894.
The hydrothermal synthesis and magnetic entropy change for the perovskite manganite La0.5Ca0.3Sr0.2MnO3 have been studied. The La0.5Ca0.3Sr0.2MnO3 can be produced as phase-pure, crystalline powders in one step from solutions of metal salts in aqueous potassium hydroxide solution at a temperature of 513 K in 72 h. Scanning electron microscopy shows that the materials are made up of cuboid-shaped particles in typical dimension of 4.0×2.5×1.6 μm. Heat treatment can improve the magnetocaloric effect for the hydrothermal sample. The maximum magnetic entropy change ΔSM for the as-prepared sample is 0.88 J kg−1 K−1 at 315 K for a magnetic field change of 2.0 T. It increases to 1.52 J kg−1 K−1, near its Curie temperature (317 K) by annealing the sample at 1473 K for 6 h. The hydrothermal synthesis method is a feasible route to prepare high-quality perovskite material for magnetic refrigeration application. 相似文献
895.
The use of phase-Doppler anemometry (PDA) to characterize the detail in-flight plasma sprayed particle behavior has been demonstrated
previously [Ma et al. Plasma Chem Plasma Process 24(1):85; 25(1):56] The present articles shows further that a direct relationship
may exist between the PDA measured particle volume flux and the coating microstructure and deposition efficiency (DE). In
the situation when the precise particle temperature information is not available, the PDA measured particle volume flux may
provide an alternative to predict quantitatively the variation of the coating microstructure and the DE. By monitoring the
in-flight particle volume flux variations, instead of the particle velocity, size and temperature individually and simultaneously,
the optimal settings of the plasma spraying parameters may also be determined conveniently. However, it is noted that the
effective applications of such approach depend largely on the particle surface morphology and the pre-determination of the
particle size range. 相似文献
896.
A generalized linear differential equation in a Banach space is studied. The construction of a phase space and solutions with the help of the spectral theory of linear operators, ergodic theorems, and degenerate semigroups of linear operators is carried out. 相似文献
897.
S. E. Bogushevich V. N. Makatun A. K. Potapovich I. I. Ugolev 《Journal of Applied Spectroscopy》1991,55(4):1016-1020
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 55, No. 4, pp. 613–618, October, 1991. 相似文献
898.
The present paper is aimed to display the performance of the Fourier-Galerkin technique developed earlier by the authors for numerical treatment of localized solutions in
2(-∞, ∞) for higher-order equations. The solitary-wave solution of the Kortweg-de Vries fifth order equation is obtained numerically and compared with approximate results of other authors. 相似文献
899.
K. -H. Ulbrich 《manuscripta mathematica》1987,59(4):391-397
Let A be a finite Hopf algebra over a commutative ring k. We show a one-to-one correspondence between the A-Galois extensions of k and certain functors from the category of A-comodules to the category of k-modules. 相似文献
900.