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371.
K. Stein und F. Umland 《Fresenius' Journal of Analytical Chemistry》1986,323(2):176-177
Ohne Zusammenfassung
Wir danken dem Fonds der Chemischen Industrie für finanzielle Unterstützung. 相似文献
Trace analysis of lead, cadmium and manganese in honey and sugar
Wir danken dem Fonds der Chemischen Industrie für finanzielle Unterstützung. 相似文献
372.
373.
Praveen K. Tandon Gayatri Sumita Sahgal Manish Srivastava Santosh B. Singh 《应用有机金属化学》2007,21(3):135-138
Catalytic activities of three transition metals, as iridium (III) chloride, rhodium (III) chloride and palladium (II) chloride, were compared in the oxidation of six aromatic aldehydes (benzaldehyde, p‐chloro benzaldehyde, p‐nitro benzaldehyde, m‐nitro benzaldehyde, p‐methoxy benzaldehyde and cinnamaldehyde), two hydrocarbons (viz. (anthracene and phenanthrene)) and one aromatic and one cyclic alcohol (cyclohexanol and benzyl alcohol) by 50% H2O2. The presence of traces (substrate: catalyst ratio equal to 1:62500 to 1:1961) of the chlorides of iridium(III), rhodium(III) and palladium(II) catalyze these oxidations, resulting in good to excellent yields. It was observed that in most of the cases palladium(II) chloride is the most efficient catalyst. Conditions for the highest and most economical yields were obtained. Deviation from the optimum conditions decreases the yields. Oxidation in aromatic aldehydes is selective at the aldehydeic group only and other groups remain unaffected. This new, simple and economical method, which is environmentally safe, also requires less time. Reactive species of catalysts, existing in the reaction mixture are also discussed. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
374.
A. D. English 《Journal of Polymer Science.Polymer Physics》1986,24(4):805-815
NMR spectroscopy has been used to characterize poly(p-phenylene terephthalamide) in the solid state and in solution in sulfuric acid. Solid-state 13C NMR spectra illustrate that the chain structure is highly ordered in the solid state and is of lower symmetry than in solution. Solid-state 13C and 1H NMR results show that only very limited motion takes place over the temperature range of ?170 to +200°C. High-resolution NMR spectra can be observed only in very dilute isotropic solutions because it is the overall rotational motion of the polymer, not segmental motion, that averages the nuclear spin interactions to their isotropic values. These results demonstrate that previous solution NMR studies that were interpreted as reflecting the presence of isotropic and anisotropic high-molecular-weight polymer phases over a wide range of concentrations actually are representative of polymer degradation. 相似文献
375.
376.
K.T.A.L. Burm 《等离子体物理论文集》2007,47(6):458-464
The discharge behaviour of an atmospheric dielectric barrier parallel plate discharge, used for surface treatment, is studied. Since an uniform plasma is preferable for surface treatment, filaments must be avoided in the discharge. The occurrence of filaments can be detected by measuring the current flowing through the discharge. Current and voltage measurements give an indication of the power consumption by the plasma. The power consumption of the plasma as function of the applied frequency is examined. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
377.
This paper provides exact and rigorous upper and lower bounds to the ground state energy of the Single Impurity Anderson Model in the limit of infiniteU. The upper bound approximates the ground state energy very well and the corresponding state may be used as a starting point for further investigations. The energy spectrum of the Single Impurity Anderson Model is calculated exactly for a special non-trivial model density of states describing the bare band electrons. All approaches introduced here are compared to this exact result and to other ground state energy calculations. 相似文献
378.
Kryazhimskiy A. V. Maksimov V. I. 《Proceedings of the Steklov Institute of Mathematics》2006,253(1):S168-S184
A problem of guaranteeing control for a system of parabolic equations is considered. A solving algorithm based on the combination of real time reconstruction processes and feedback control is designed. 相似文献
379.
N. A. Lockerbie 《General Relativity and Gravitation》2006,38(3):533-536
This paper is in answer to the comment on the GRG paper: Lockerbie N.A. Gen. Rel. Grav. 36, 593 (2004), made by A.V. Sanders, G.T. Gillies (ibid.).
N. A. Lockerbie is a member of the STEP (Satellite Test of the Equivalence Principle) Science Study Team, and an Associate
of the Institute for Gravitational Research at the University of Glasgow, Scotland, UK. 相似文献
380.