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91.
Akhilesh K. Arora R. Kesavamoorthy A.K. Sood G. Venkatraraman R. Krishnaswamy Debendranath Sahoo 《Journal of Physics and Chemistry of Solids》1984,45(1):69-77
The formation and dissolution behaviour of precipitates in NaCl : Pb2+ single crystals is studied by light scattering and ultramicroscopy. Measurements of Rayleigh ratio together with ultramicroscopic observations during isochronal annealing indicate the presence of two types of precipitates in as-grown crystals. Isochronal annealing after suitable thermal and thermomechanical treatments shows that precipitates of first type (I) which form and dissolve at lower temperatures, are due to homogeneous nucleation. Precipitates of the second category (II) which form and dissolve at higher temperatures are aligned along crystallographic directions and have their origin in stress-assisted processes. Isothermal annealing has been used to study the dissolution kinetics of the precipitated fraction, and it is found that the kinetics is of first order. The enthalpy of solution is determined from a study of the temperature dependence of the kinetic rate constant, in conjunction with available information on the migration energy of Pb2+ in NaCl. The enthalpy so deduced is in good agreement with the value as usually obtained from the concentration dependence of the dissolution temperature. 相似文献
92.
A direct method of solution is presented for singular integral equations of the first kind, involving the combination of a logarithmic and a Cauchy type singularity. Two typical cases are considered, in one of which the range of integration is a single finite interval and, in the other, the range of integration is a union of disjoint finite intervals. More such general equations associated with a finite number (greater than two) of finite, disjoint, intervals can also be handled by the technique employed here. 相似文献
93.
Simple modification of a protein database for mass spectral identification of N-linked glycopeptides
Atwood JA Sahoo SS Alvarez-Manilla G Weatherly DB Kolli K Orlando R York WS 《Rapid communications in mass spectrometry : RCM》2005,19(21):3002-3006
We describe an algorithm which modifies a protein database such that during a database search deamidation is limited to asparagines strictly contained within the N-glycosylation consensus sequence. The modified database was evaluated using a dataset created from the shotgun proteomic analysis of N-linked glycopeptides from human blood serum. We demonstrate that the application of the modified database eliminates incorrect glycopeptide assignments, reduces the peptide false-discovery rate, and eliminates the need for manual validation of glycopeptide identifications. 相似文献
94.
Bikash Sahoo 《Central European Journal of Physics》2010,8(3):498-508
The entrained flow of an electrically conducting non-Newtonian, viscoelastic second grade fluid due to an axisymmetric stretching
surface with partial slip is considered. The partial slip is controlled by a dimensionless slip factor, which varies between
zero (total adhesion) and infinity (full slip). Suitable similarity transformations are used to reduce the resulting highly
nonlinear partial differential equation into an ordinary differential equation. The issue of paucity of boundary conditions
is addressed, and an effective numerical scheme has been adopted to solve the obtained differential equation even without
augmenting the boundary conditions. The important findings in this communication are the combined effects of the partial slip,
magnetic interaction parameter and the second grade fluid parameter on the velocity and skin friction coefficient. It is observed
that in presence of slip, the velocity decreases with an increase in the magnetic parameter. That is, the Lorentz force which
opposes the flow leads to enhanced deceleration of the flow. Moreover, it is interesting to find that as slip increases in
magnitude, permitting more fluid to slip past the sheet, the skin friction coefficient decreases in magnitude and approaches
zero for higher values of the slip parameter, i.e., the fluid behaves as though it were inviscid. 相似文献
95.
96.
Satyabrata Sahoo Y.K. Ho 《Journal of Quantitative Spectroscopy & Radiative Transfer》2010,111(1):52-62
We present theoretical photoionization cross sections for He 1s2s 1S and He 1s2p 1P states in a Debye plasma environment by the complex coordinate rotation method, using a finite L2 basis set constructed from one electron Laguerre orbitals. The plasma environment is found to appreciably influence the photoionization cross sections near the ionization threshold. In this regard, the photoionization cross sections of isolated He are compared with other theoretical and experimental results. Our results are in good agreement with the previous results. A new minimum appears in the photoionization cross section curve for the metastable 1s2s 1S state. Results are given for the S- and D-wave partial photoionization for the excited 1s2p 1P state. 相似文献
97.
98.
Stability of the generalized quadratic and quartic type functional equation in non-Archimedean fuzzy normed spaces
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In this paper, we prove some stability results concerning the generalized quadratic and quartic type functional equation in the context of non-Archimedean fuzzy normed spaces in the spirit of Hyers-Ulam-Rassias. As applications, we establish some results of approximately generalized quadratic and quartic type mapping in non-Archimedean normed spaces. Also, we show that the assumption of the non-Archimedean absolute value of $2$ is less than $1$ cannot be omitted in our corollaries. The results improve and extend some recent results. 相似文献
99.
Sahoo AK Nakamura Y Aratani N Kim KS Noh SB Shinokubo H Kim D Osuka A 《Organic letters》2006,8(18):4141-4144
Highly efficient synthesis of meso,meso-dibromo doubly and triply fused diporphyrins has been achieved through a powerful oxidative coupling mediated by AuCl3-AgOTf combination. In addition, palladium-catalyzed debromination of meso-bromoporphyrins has been developed. This debromination protocol enables employment of bromine as a protecting group for the reactive meso-position of porphyrins. 相似文献
100.
The electric quadrupole moment for the 4d(2)D(5/2) state of (88)Sr(+); one of the most important candidates for an optical clock, has been calculated using the relativistic coupled-cluster theory. This is the first application of this theory to determine atomic electric quadrupole moments. The result of the calculation is presented and the important many-body contributions are highlighted. The calculated electric quadrupole moment is (2.94 +/- 0.07)ea(2)(0), where a(o) is the Bohr radius and the electronic charge while the measured value is (2.6 +/- 0.3) ea(2)(0). This is so far the most accurate determination of the electric quadrupole moment for the above mentioned state. We have also calculated the electric quadrupole moments for the metastable 4d(2)D(3/2) state of 88(Sr(+) and for the 3d(2)D(3/2.5/2) and 5d(2)D(3/2.5/2) states of (43)Ca(+) and (138)Ba(+), respectively. 相似文献