全文获取类型
收费全文 | 3333篇 |
免费 | 572篇 |
国内免费 | 367篇 |
专业分类
化学 | 2280篇 |
晶体学 | 42篇 |
力学 | 259篇 |
综合类 | 13篇 |
数学 | 338篇 |
物理学 | 1340篇 |
出版年
2024年 | 19篇 |
2023年 | 98篇 |
2022年 | 163篇 |
2021年 | 152篇 |
2020年 | 166篇 |
2019年 | 155篇 |
2018年 | 132篇 |
2017年 | 115篇 |
2016年 | 192篇 |
2015年 | 173篇 |
2014年 | 186篇 |
2013年 | 235篇 |
2012年 | 343篇 |
2011年 | 351篇 |
2010年 | 220篇 |
2009年 | 179篇 |
2008年 | 175篇 |
2007年 | 170篇 |
2006年 | 162篇 |
2005年 | 125篇 |
2004年 | 94篇 |
2003年 | 88篇 |
2002年 | 52篇 |
2001年 | 45篇 |
2000年 | 47篇 |
1999年 | 50篇 |
1998年 | 44篇 |
1997年 | 48篇 |
1996年 | 38篇 |
1995年 | 30篇 |
1994年 | 31篇 |
1993年 | 37篇 |
1992年 | 30篇 |
1991年 | 28篇 |
1990年 | 22篇 |
1989年 | 16篇 |
1988年 | 12篇 |
1987年 | 6篇 |
1986年 | 16篇 |
1985年 | 5篇 |
1984年 | 3篇 |
1983年 | 6篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1973年 | 1篇 |
1970年 | 2篇 |
1957年 | 2篇 |
排序方式: 共有4272条查询结果,搜索用时 0 毫秒
11.
树脂吸附法处理水杨酸甲酯生产废水的研究 总被引:7,自引:0,他引:7
采用吸附树脂NDA—99处理水杨酸甲酯生产废水,结果表明该树脂时废水中的5磺基水杨酸及水杨酸均具有良好的吸附—脱附性能.废水经预处理和吸附处理后,CODCr由57000-59000mg/L降至6300mg/L左右,去除率接近89%.用IBV8%NaOH 3BVH2O作脱附剂,在温度为60℃、流量为IBV/h的条件下,脱附率接近100%,树脂可重复使用.高浓度脱附液经酸化、浓缩、冷却结晶,可回收5—磺基水杨酸,回收率为95%左右。纯度为78%。 相似文献
12.
~(13)C and ~1H NMR technique was used to study the interaction of Gly-Gly with heavy lanthanide cations Dy~(3+), Ho~(3+), Er~(3+), Tm~(3+) and Yb~(3+) in aqueous solution. The stability constants for the 1:1 and 1:2 complexes of Gly-Gly with Ho~(3+) and Yb~(3+) were determined from the titration curves of chemical shift versus concentration ratio of lanthanide to Gly-Gly. The solution structure of the Ln-Gly-Gly complex was analyzed based upon the ~(13)C and ~1H lanthanide-induced shifts and the results show that in the complex Gly-Gly is coordinated to the lanthanide ion through the carboxyl oxygens with the backbone of the ligand in an extended state. 相似文献
13.
14.
Two molecular imprinting polymer (MIP) monolithic columns with (S)-(-)-1,1'-bi-2-naphthol and (R)-(+)-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2-naphthol as the templating molecules, respectively, have been prepared by in situ polymerization using 4-vinylpyridine and ethylene dimethacrylate as functional monomer and cross-linker, respectively. The columns with good flow-through properties were obtained by changing the molar ratio of the functional monomer and the template molecule. The effects of mobile-phase composition on separation of enantiomers were systematically investigated. The results indicate that hydrophobic interaction in aqueous solution and hydrogen-bonding interaction in ACN between the enantiomers and polymers could play important roles in the retention and resolution. The effects of chromatographic conditions, such as flow rate, column temperature, sample loading, on the enantioseparation were also studied. Further, these two MIP columns show a cross-reactivity. 相似文献
15.
现场表面拉曼光谱研究Fe-Mo合金诱导共沉积 总被引:1,自引:0,他引:1
现场表面拉曼光谱结果显示,在0.2mol·L-1Na2MoO4,pH=4.0的溶液中,电位正于0.5V(vsSCE)时只观察到多钼酸盐的拉曼峰(940、880和450cm-1).负于-0.5V时,出现中心位于730cm-1的宽峰.同时电极表面有蓝色膜生成.表明混合氧化态(MO(Ⅳ),MO(Ⅴ))氧化膜的形成.730cm-1的峰在-1.9V时仍然存在,说明氧化膜没有被进一步还原.在钼酸钠溶液中同时含有0.1mol·L-1FeSO4和0.2mol·L-1柠檬酸时,中间态氧化膜的拉曼峰的中心移到740cm-1.且峰强度随着电位从-1.3V负移到-1.9V而逐渐减弱并最终消失.电极表面沉积层呈银白色,说明由于Fe2 的存在,钼的中间态氧化膜的结构发生了变化,能够被进一步还原形成Fe-Mo合金,表现出诱导共沉积的特征. 相似文献
16.
17.
聚氯乙烯—丁腈橡胶—氯丁橡胶三元共混物的研究 总被引:1,自引:0,他引:1
测定了聚氯乙烯(PVC)-丁脯橡胶(NBR-29)-氯丁橡胶(CR)三元共混物的冲击性能和应力-应变行为,用动态力分析、扫描电和透射电镜研究了共混物的相容性和形态结构。结果表明,NBR-29对PVC,CR有良好的增容作用,三元共混物是部分相容的二相体系,具有良好的抗冲击性能。 相似文献
18.
Cellulose synthesis in maize: isolation and expression analysis of the cellulose synthase (CesA) gene family 总被引:7,自引:0,他引:7
Laura Appenzeller Monika Doblin Roberto Barreiro Haiyin Wang Xiaomu Niu Krishna Kollipara Lori Carrigan Dwight Tomes Mike Chapman Kanwarpal S. Dhugga 《Cellulose (London, England)》2004,11(3-4):287-299
Stalk lodging in maize results in significant yield losses. We have determined that cellulose per unit length of the stalk is the primary determinant of internodal strength. An increase in cellulose concentration in the wall might allow simultaneous improvements in stalk strength and harvest index. Cellulose formation in plants can be perturbed by mutations in the genes involved in cellulose synthesis, post-synthetic cellulose alteration or deposition, N-glycosylation, and some other genes with as yet unknown functions. We have isolated 12 members of the cellulose synthase (CesA) gene family from maize. The genes involved in primary wall formation appear to have duplicated relatively independently in dicots and monocots. The deduced amino acid sequences of three of the maize genes, ZmCesA10–12, cluster with the Arabidopsis CesA sequences that have been shown to be involved in secondary wall formation. Based on their expression patterns across multiple tissues, these three genes appear to be coordinately expressed. The remaining genes show overlapping expression to varying degrees with ZmCesA1, 7, and 8 forming one group, ZmCesA3 and 5 a second group, and ZmCesA2 and 6 exhibiting independent expression of any other gene. This suggests that the varying levels of coexpression may just be incidental except in the case of ZmCesA10–12, which may interact with each other to form a functional enzyme complex. Isolation of the expressed CesA genes from maize and their association with primary or secondary wall formation has made it possible to test their respective roles in cellulose synthesis through mutational genetics or transgenic approaches. This information would be useful in improving stalk strength. 相似文献
19.
微分倒数示波计时电位法的研究—定量测试及滴定分析 总被引:3,自引:0,他引:3
首次利用微分倒数示波图定量测试微量金属离子并滴定分析药物,结果满意。 相似文献
20.
Three novel perylene polyimides (PPIs) containing p‐n diblock units were designed and synthesized for use in dye‐sensitized mesoporous TiO2 solar cells. They all dissolve in m‐cresol and N‐methyl‐2‐pyrrolidone (NMP). Their visible light absorption, electrochemical and photoelectrochemical properties were systematically studied. The polyimides have band gap energies of 2.16, 2.19 and 2.25 eV deduced from ultraviolet–visible absorption spectra, and electron affinity (Ea) and ionization potential (IP) of ?3.93 and 6.10 eV for PPI1, ?3.94 and 6.13 eV for PPI2, ?3.93 and 6.59 eV for PPI3, respectively, deduced from cyclic voltammogram. Experimental data show that introduction of 4,4′‐bisaminetriphenylamine cannot only greatly enhance optic‐electro conversion efficiency, but also enhance the dissolubility which in favorable for making the devices. The relationship of structure and properties of PPI is discussed and the mechanism of photocurrent generation is explained. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献