受激布里渊散射相位共轭现象的二维数值模拟

 使用P.H.Hu等人[3，4]提出的计算途径，数值解了A.Flusberg等人[2]提出的零级方程。计算了布里渊池内随位置而变化的斯托克斯光强度、泵浦光强度和保真度，得到了布里渊池内几个位置上的斯托克斯光相位和强度的横向分布，并计算了泵浦光入口处的反射率和保真度。     

气密性碳涂覆光纤筛选强度与电阻关系研究

通过实验分析确立了把光纤电阻作为衡量气密性碳涂覆光纤通过２％应变筛选的过渡标准。要拉制２％应变筛选的碳涂覆光纤，其电阻值应小于３０ｋΩ／ｃｍ。     

Bombieri's theorem in short intervals

The well-known Bombieri-A. I. Vinogradov theorem states that (1) $$\sum\limits_{q \leqslant x^{\tfrac{1}{2}} (\log x)^{ - s} } {\mathop {\max }\limits_{(a,q) = 1} \mathop {\max }\limits_{y \leqslant x} } \left| {\psi (y,q;a) - \frac{y}{{\varphi (q)}}} \right| \ll \frac{x}{{(\log x)^A }},$$ whereA is an arbitrary positive constant,B=B(A)>0, and as usual, $$\psi (x,q;a) = \sum\limits_{\mathop {n \leqslant x}\limits_{n = a(q)} } {\Lambda (n),}$$ Λ being the Von Mangoldt's function. The problem of finding a result analogous to (1) for short intervals was investigated by many authors. Using Heath-Brown's identity and the approximate functional equation for DirichletL-functions, A. Perelli, J. Pintz and S. Salerno in 1985 established the following extension of Bombieri's theorem: Theorem 1. (2) $$\sum\limits_{q \leqslant Q} {\mathop {\max }\limits_{(a,q) = 1} \mathop {\max }\limits_{h \leqslant y} \mathop {\max }\limits_{\frac{x}{2}< \approx \leqslant x} } \left| {\psi (z + h,q;a) - \psi (z,q;a) - \frac{h}{{\varphi (q)}}} \right| \ll \frac{y}{{(\log x)^A }}$$ where A>0 is an arbitrary constant,y=x ^θ $$\frac{7}{{12}}< \theta \leqslant 1, Q = x^{\frac{1}{{40}}} .$$ ,Q=x ^1/40. By improving the basic lemma which A. Perelli, J. Pintz and S. Salerno used as the main tool to prove Theorem 1, we obtain Theorem 2.Under the same condition as in Theorem 1,for Q=x ^1/38.5, (2)still holds.     

烷基季铵盐插层剂的合成及应用

Three novel intercalation agents were synthesized for the first time, which arose from oleic acid diethylenetriamine or triethylenetetramine 3 - chloro - 2 - hydroxypropy trimethylammonium choride (CHPTA) and chloroethanol. Organophilic vermicullites were synthesized from sodium type vermiculite by cation exchange with new intercalation agents. The results of X - ray diffraction study showed that the gallery distance of the organophilic vermiculite was enlarged from 1 nm to 5 nm or more. A new idea of making design for intercalation agent was provided.     

Solvatochromic studies of interactions between surfactants and poly(N-substituted acrylamide)s

Interactions between poly(N-substituted acrylamide)s and surfactants, such as sodium dodecyl sulfate (SDoS) and sodium decyl sulfate (SDeS), in aqueous solutions were investigated using a solvatochromic probe. The polymers used were poly(N,N-dimethylacrylamide) (PDMA), poly(N-isopropylacrylamide) (PIPA), poly(N-acryloylpyrrolidine) (PAPR), and poly(vinylpyrrolidone) (PVPy) for comparison. They were labeled with pyridinium dicyanomethylide chromophore as a solvatochromic probe, and the changes in the microenvironment polarity of the polymer upon association with surfactant micelles were investigated by monitoring the λ_max in the absorption spectra of the probe molecule. It was found that the Gibbs free energy of micelle stabilization by polymer complexation for SDoS is 7.6, 4.1, and 2.2 kJ mol⁻¹, and for SDeS 5.1, 2.9, and 0.8 kJ mol⁻¹ with PIPA, PAPR, and PDMA, respectively. These results indicate that the complexation between polymer and surfactant is influenced not only by the alkyl-chain length of the surfactant, but also by the polymer side groups.     

从α－蒎烯直接催化酯化高选择性地合成乙酸正龙脑酯的研究－催化剂与反应机理初探

本文提出了新的硼酸类催化剂体系ＨＢ，用该体系对α－蒎烯与无水乙酸相互作用直接合成乙酸正龙脑酯作了较系统的研究。反应得到两种系列产物－酯化产物和异构化产物，酯化产物主要是乙酸正龙脑酯，葑醇酯和松油酯，异构化产物主要是莰烯、烯和松油烯等，总酯化产率为５０％以上，其中乙酸正龙脑酯为２０％以上，是至今从α－蒎烯直接合成乙酸正龙脑酯的最好结果。通过对产物的￣１ＨＮＭＫ图谱分析及动力学考察，确证反应主产物是正龙脑酯而不是异龙脑酯。文章对Ｈ＿２ＳＯ＿４、ＨＣｌＯ＿４、多聚磷酸（ＰＰＡ）和杂多酸（１２－磷钨酸）等催化剂进行了实验考察、对比和评述，表明了自制的ＨＢ催化剂体系具有高选择性合成乙酸正龙脑酯的显著优点，并对其反应机理作了初步探讨。     

硅胶键联MPc的制备及其在氧活化中的作用

过渡金属酞等配合物（MPC）用手均相液相氧化中作催化剂已有不少报导，象许多均相催化剂一样，MPC用于均相反应存在着难于从反应体系中分离出来的问题．把均相配合物催化剂固载在无机氧化物如硅股或有机高分子载体上是解决这一问题的一种方法．我们曾尝试把MP。固载在分子筛载体和硅胶载体上，并用ESR研究其对O2的活化作用[1，2]．本文报导MPc通过共价键键联固载在SiO2上，并研究其对O2的活化作用．1实验部分1．1试剂HSIC13为日本东京化成株式会社产品，二级试剂·发烟硫酸（SO。质量分数大于20％）为分析纯试剂．PCl5为化学纯试…     

Terpolymerization of sulfur dioxide or maleic anhydride with unsaturated compounds under ultraviolet irradiation

The effect of ultraviolet irradiation on the terpolymerization was investigated. In the terpolymerizations of sulfur dioxide–butene-1–acrylonitrile, sulfur dioxide–butene-1–n-butyl acrylate, and maleic anhydride–allyl chloride–acrylonitrile systems, the composition of the terpolymers prepared under ultraviolet irradiation was different from those prepared in the dark. The unit content of sulfur dioxide and butene-1 or of maleic anhydride and allyl chloride in the terpolymer increased under ultraviolet irradiation. The nature of the growing end under ultraviolet irradiation is supposed to be the same as that of the dark polymerization on the basis of the same solvent effect on the terpolymer composition, the rate of polymerization and the molecular weight of polymer. The experimental results suggest that the complex between sulfur dioxide and butene-1 or maleic anhydride and allyl chloride might be excited by ultraviolet light and the excited complex may participate in the terpolymerization.     

Probe metal binding mode of imine covalent organic frameworks: cycloiridation for (photo)catalytic hydrogen evolution from formate

Metalation of covalent organic frameworks (COFs) is a critical strategy to functionalize COFs for advanced applications yet largely relies on the pre-installed specific metal docking sites in the network, such as porphyrin, salen, 2,2′-bipyridine, etc. We show in this study that the imine linkage of simple imine-based COFs, one of the most popular COFs, readily chelate transition metal (Ir in this work) via cyclometalation, which has not been explored before. The iridacycle decorated COF exhibited more than 10-fold efficiency enhancement in (photo)catalytic hydrogen evolution from aqueous formate solution than its molecular counterpart under mild conditions. This work will inspire more functional cyclometallated COFs to be explored beyond catalysis considering the large imine COF library and the rich metallacycle chemistry.

This study describes cyclometallation as a new metal binding mode for imine-based COFs. The iridacycle decorated COF could be used for catalytic hydrogen evolution from aqueous formate solution with high stability and high efficacy.     

Electron-transfer reactions and functionalization of cytochrome P450cam monooxygenase system in reverse micelles

Enzyme-based electron-transfer reactions involved in the cytochrome P450 monooxygenase system were investigated in nanostructural reverse micelles. A bacterial flavoprotein, putidaredoxin reductase (PdR), was activated and shown to be capable of catalyzing the electron transport from NADH to electron-carrier proteins such as cytochrome b5 (tCyt-b5) and putidaredoxin (Pdx) in reverse micelles. Ferric tCyt-b5 in reverse micelles was effectively converted to its ferrous form by the exogenous addition of separately prepared reverse micellar solution harboring PdR and NADH. The fact that direct interactions of macromolecular proteins should be possible in the reverse micellar system encouraged us to functionalize a multicomponent monooxygenase system composed of the bacterial cytochrome P450cam (P450cam), putidaredoxin (Pdx), and PdR in reverse micelles. The successful camphor hydroxylation reaction catalyzed by P450cam was significantly dependent on the coexistence of Pdx, PdR, and NADH but not H2O2, suggesting that the oxygen-transfer reactions proceeded via a "monooxygenation" mechanism. This is the first report of a multicomponent cytochrome P450 system exhibiting enzymatic activity in organic media.