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71.
Brückner C Ogikubo J McCarthy JR Akhigbe J Hyland MA Daddario P Worlinsky JL Zeller M Engle JT Ziegler CJ Ranaghan MJ Sandberg MN Birge RR 《The Journal of organic chemistry》2012,77(15):6480-6494
The rational syntheses of meso-tetraaryl-3-oxo-2-oxaporphyrins 5, known as porpholactones, via MnO(4)(-)-mediated oxidations of the corresponding meso-tetraaryl-2,3-dihydroxychlorins (7) is detailed. Since chlorin 7 is prepared from the parent porphyrin 1, this amounts to a 2-step replacement of a pyrrole moiety in 1 by an oxazolone moiety. The stepwise reduction of the porpholactone 5 results in the formation of chlorin analogues, meso-tetraaryl-3-hydroxy-2-oxachlorin (11) and meso-tetraaryl-2-oxachlorins (12). The reactivity of 11 with respect to nucleophilic substitution by O-, N-, and S-nucleophiles is described. The profound photophysical consequences of the formal replacement of a pyrrole with an oxazolone (porphyrin-like chromophore) or (substituted) oxazole moiety (chlorin-like chromophore with, for the parent oxazolochlorin 12, red-shifted Q(x) band with enhanced oscillator strengths) are detailed and rationalized on the basis of SAC-CI and MNDO-PSDCI molecular orbital theory calculations. The single crystal X-ray structures of the porpholactones point at a minor steric interaction between the carbonyl oxygen and the flanking phenyl group. The essentially planar structures of all chromophores in all oxidation states prove that the observed optical properties originate from the intrinsic electronic properties of the chromophores and are not subject to conformational modulation. 相似文献
72.
A few complicated and time-consuming methods are available for the determination of residual fentanyl in Durotep MT transdermal patches, however, their application to clinical settings is limited. The aim of this study was to develop a simple and rapid HPLC-UV method using an ultrafine particle octadecylsilane (ODS) for the determination of residual fentanyl in applied Durotep MT transdermal matrix patches. Patch extraction involved sonicating a shredded Durotep MT patch in acetonitrile for 15 min. Fentanyl separation was completed within 2 min using a 2.3-μm particle ODS column (50 × 4.6 mm i.d.) at a flow rate of 1.5 mL/min. No peaks interfering with fentanyl (1.27 min) and papaverine (0.89 min) as an internal standard were observed. The calibration curve for fentanyl was linear over the range of 0.015-9.0 mg as a Durotep MT patch. The intra- and inter-assay precisions and accuracies of each patch were within 5.3% and 103.9-110.5% and within 8.2% and 97.1-104.3%, respectively. The validated method was applied to determine residual fentanyl in Durotep MT patches used in 35 cancer patients. Although the plasma fentanyl concentration was significantly correlated with its measured absorption rate, the measured absorption rate normalized fentanyl concentration showed a large inter-individual variation. The validated simple and rapid HPLC-UV method established in the present study is helpful for evaluating the absorption rate of fentanyl in patients receiving Durotep MT patches. 相似文献
73.
74.
Boris M. Epelbaum Kiyoshi Shimamura Satoshi Uda Junichi Kon Tsuguo Fukuda 《Crystal Research and Technology》1996,31(8):1077-1084
The μ-PD method originally developed for oxide crystals has been modified and applied for filamentary silicon crystal growth. Our main modification of μ-PD method is concerned with an arrangement of melt permeable feeder which is inserted into the nozzle. The feeder finishes by a sharp tip the diameter of which (is almost the same as that of the desired semiconductor fiber, i.e., less than 150 μm. Silicon fibers were grown from the small liquid pool at the end of the feeder. Three types of crucible-die arrangement were designed and tested. The best results were obtained with the help of inclined insert made of graphite fibers because of its ability to quench oscillations and longer operation life. Fiber crystals, 100 μm in diameter and 70 mm in length, have been grown successfully. Small meniscus stability, operating limits of μ-PD method and silicon carbide formation during the growth process are discussed. 相似文献
75.
Existence of Three Weak Solutions for a Class of Quasi-Linear Elliptic Operators with a Mixed Boundary Value Problem Containing $p(\cdot )$-Laplacian in a Variable Exponent Sobolev Space
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Junichi Aramaki 《Journal of Nonlinear Modeling and Analysis》2024,6(1):107-132
In this paper, we consider a mixed boundary value problem to a class of nonlinear operators containing $p(\cdot )$-Laplacian. More precisely, we are concerned with the problem with the Dirichlet condition on a part of the boundary and the Steklov boundary condition on an another part of the boundary. We show the existence of at least three weak solutions under some hypotheses on given functions and the values of parameters. 相似文献
76.
A sensitive and precise method based on microdiffusion is proposed for the determination of traces of boron in plants. A sealed digestion bomb is used; the powdered sample is dissolved in ZnCl2/AlCl3 solution containing methanol in the teflon vessel and the trimethyl borate formed is collected in sodium hydroxide pellets. The boron, as an ion-associate of the 2,6-dihydroxybenzoic acid complex and malachite green, is extracted into chlorobenzene. At 629 nm, Beer's law is obeyed for the range 0.05–0.5 μg of boron. The accuracy of the proposed method was confirmed by analyzing the Orchard Leaves and Pepperbush standards. 相似文献
77.
Design and Synthesis of 6 α-Corticosteroid Haptens and Their Bovine Serum Albumin(BSA) Conjugates 总被引:1,自引:0,他引:1
The site of attachment of protein carrier to corticosteroids has great influence on the specificity of produced antibody.In order to obtain highly specific and accurate antibodies for bioimmunoassay determination of cortisol,different tether lengths of 60633-corticosteroid haptens and their BSA conjugates were designed and synthesized. 相似文献
78.
Akihiro Ohta Masami Inoue Junichi Yamada Yasuhiko Yamada Teruo Kurihara Toshihiro Honda 《Journal of heterocyclic chemistry》1984,21(1):103-106
Some 2,3-diphenylpyrazine 1-oxides were heated with acetic anhydride to give the corresponding 2,3-di-acetoxy-2,3-dihydro-5,6-diphenylpyrazines. By X-ray diffraction analysis, the configuration of two acetoxyl groups was determined to be trans. 相似文献
79.
Junichi Ishida 《School science and mathematics》1997,97(3):155-162
This study examined the effects of a teaching strategy in which fifth-grade students evaluated the strengths or weaknesses of solution methods to pattern finding problems. The experimental and control group each consisted of thirty four elementary students in Japan who took the pre, post and retention tests. The experimental group showed a significantly better performance on the retention test although no significant differences were observed on the pre and post tests. This result suggests that the evaluation and improvement activity was important as a teaching strategy. 相似文献
80.
The prototype for a ground speed sensor has been designed, fabricated and evaluated. It works on the principle of optical spatial filtering and uses pulse driven light emitting diodes as a source of illumination. The sensor was tested at speeds ranging from 2 to 50 km/h, and an accuracy of 1.5 km/h was obtained with response time of 30 ms, height from ground of from 230 to 370 mm and on various road surfaces. The sensor is viewed as beneficial for use in a vehicle’s antilock braking system and will contribute to traffic safety.Presented at the International Commission of Optics Topical Meeting, Kyoto, 1994. 相似文献