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11.
Harada T Nakagawa Y Ogura T Yamada Y Ohe T Miyagawa H 《Journal of chemical information and modeling》2011,51(2):296-305
Insect growth is regulated by the orchestrated event of ecdysteroids and their receptor proteins. Agonists/antagonists of ecdysteroid receptor are predicted to disrupt normal growth, providing good candidates of new insecticides. A database of over 2 million compounds was subjected to a shape-based virtual screening cascade to identify novel nonsteroidal hits similar to the known EcR ligand ponasterone A. Testing revealed micromolar hits against two strains of insect cells. Docking experiments against EcR were used to support the predicted binding mode of these ligands based on their overlay to ponasterone A. 相似文献
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Sorption and diffusion of Sr were examined using a typical Japanese bentonite. The experimental results showed that Sr sorption
on the bentonite had linear relationship between the equilibrium Sr concentration and Sr sorption amount, i.e., Henry’s type
of sorption, in wide initial Sr concentration from 1.1×10−9 to 1.1×10−4 mol L−1 at pH 10. The Sr sorption also indicated pH dependence in pH range between 2 and 12. Sorption modelling calculation indicated
that cation-exchange reactions contributed to Sr sorption in the pH range studied and a surface complexation reaction was
predominant above pH 8. Diffusion of Sr in loosely compacted bentonite bed was described by pore and surface diffusion and
surface complexation of Sr. Chemical-transport calculations reproduce the diffusion data at pH 5 using the cation-exchange
parameters obtained in the analysis of the batch sorption experiment. 相似文献
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Fluctuations of the electric field, the charged particle density, the electron temperature and the plasma potential are simultaneously measured by a probe in the positive column of helium glow discharge at a few torr gas pressure by exciting a small amplitude ionization wave. It is proposed that these values can be determined by analyzing the probe current. 相似文献
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Bis(azafulvene) was isolated in 55% yield by the reaction of 4 equivalents of phenyllithium with 5,5'-diformyl-3,3',4,4'-tetraethyl-2,2'-bipyrrole followed by quenching with acetic anhydride. Unstable bis(azafulvene)s were obtained in much higher yields by dehydrating 5,5'-bis(hydroxymethyl) derivatives of 2,2'-bipyrrole and gem-dimethyl-2,2'-dipyrrylmethane with (Boc)2O-DMAP at room temperature. X-Ray crystallography of two bis(azafulvene)s is reported. 相似文献
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[reaction: see text] The reaction of heteroaromatic compounds with propargylic carboxylates in the presence of a catalytic amount of [RuCl(2)(CO)(3)](2) or PtCl(2) gives trienes in good yields. The key intermediate is an electrophilic (1-acetoxylvinyl)carbene complex generated from the activated propargylic acetates with transition metals. 相似文献
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Stefan?KunisEmail author H.?Michael?M?ller Thomas?Peter Ulrich?von der?Ohe 《Journal of Fourier Analysis and Applications》2018,24(5):1306-1318
The parameter reconstruction problem in a sum of Dirac measures from its low frequency trigonometric moments is well understood in the univariate case and has a sharp transition of identifiability with respect to the ratio of the separation distance of the parameters and the order of moments. Towards a similar statement in the multivariate case, we present an Ingham inequality which improves the previously best known dimension-dependent constant from square-root growth to a logarithmic one. Secondly, we refine an argument that an Ingham inequality implies identifiability in multivariate Prony methods to the case of commonly used max-degree by a short linear algebra argument, closely related to a flat extension principle and the stagnation of a generalized Hilbert function. 相似文献