首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   88959篇
  免费   13049篇
  国内免费   9779篇
化学   60809篇
晶体学   1110篇
力学   5677篇
综合类   806篇
数学   10579篇
物理学   32806篇
  2024年   267篇
  2023年   1646篇
  2022年   2763篇
  2021年   3022篇
  2020年   3136篇
  2019年   3136篇
  2018年   2769篇
  2017年   2547篇
  2016年   3775篇
  2015年   3975篇
  2014年   4645篇
  2013年   6189篇
  2012年   7632篇
  2011年   7698篇
  2010年   5432篇
  2009年   5365篇
  2008年   5729篇
  2007年   5083篇
  2006年   4887篇
  2005年   4295篇
  2004年   3434篇
  2003年   2656篇
  2002年   2488篇
  2001年   2143篇
  2000年   1929篇
  1999年   1949篇
  1998年   1575篇
  1997年   1348篇
  1996年   1388篇
  1995年   1216篇
  1994年   1156篇
  1993年   989篇
  1992年   839篇
  1991年   750篇
  1990年   608篇
  1989年   519篇
  1988年   406篇
  1987年   367篇
  1986年   324篇
  1985年   333篇
  1984年   220篇
  1983年   191篇
  1982年   158篇
  1981年   128篇
  1980年   92篇
  1979年   61篇
  1978年   63篇
  1977年   59篇
  1975年   60篇
  1973年   58篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
We examine the influence of relativistic and QED effects on the existence of the 1,3P o H- resonances between n = 2 and 3 hydrogen thresholds, the relativistic and QED corrections and the coupling effects between the high singlet and triplet states are considered as first-order perturbations. We firstly obtain accurate non-relativistic resonant energies and widths of fifteen 1P o resonances, and fifteen 3P o resonances. The fifteen 1P o resonances are classified to be 3 (2, 0) - n ( 4 ? n ? 12) and 3 (1, 1) + n ( 3 ? n ? 8). The fifteen 3P o resonances are classified to be 3 (2, 0) + n ( 3 ? n ? 12) and 3 (1, 1) - n ( 4 ? n ? 8). We found there exist six Feshbach resonances for 3 (2, 0) - n (1P o ) series, four Feshbach resonances for 3 (1, 1) + n (1P o ) series, seven Feshbach resonances for 3 (2, 0) + n (3P o ) series, and three Feshbach resonances for 3 (1, 1) - n (1P o ) series. Received 22 February 2002 Published online 24 September 2002  相似文献   
32.
A novel process comprising the UV‐induced photografting of styrene into poly(tetrafluoroethylene) (PTFE) films and subsequent sulfonation has been developed for preparing proton‐conducting membranes. Although under UV irradiation the initial radicals were mainly generated on the surface of the PTFE films by the action of photosensitizers such as xanthone and benzoyl peroxide, the graft chains were readily propagated into the PTFE films. The sulfonation of the grafted films was performed in a chlorosulfonic acid solution. Fourier transform infrared and scanning electron microscopy were used to characterize the grafted and sulfonated membranes. With a view to use in fuel cells, the proton conductivity, water uptake, and mechanical properties of the prepared membranes were measured. Even through the degree of grafting was lower than 10%, the proton conductivity in the thickness direction of the newly prepared membranes could reach a value similar to that of a Nafion membrane. In comparison with γ‐ray radiation grafting, UV‐induced photografting is very simple and safe and is less damaging to the membranes because significant degradation of the PTFE main chains can be avoided. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2624–2637, 2007  相似文献   
33.
Ronghua Li  Ruiting Chen  Wenji Wang 《Ionics》2002,8(5-6):412-415
Perovskite-type lithium fast ion conductors of Li3xLa0.67−xScyTi1−2yNbyO3 system were prepared by solid state reaction. X-Ray powder diffraction shows that perovskite solid solution form in the ranges of x=0.10, y≤0.10. AC impedance measurements indicate that the bulk conductivities and the total conductivities are of the order of 10−4 S·cm−1 and 10−5 S·cm−1 at 25 °C respectively. The compositions have low bulk activation energies of about 17 kJ/mol in the temperature ranges of 298 – 523 K and total activation energies of about 37 kJ/mol in the temperature ranges of 298 – 523 K.  相似文献   
34.
α‐Cyclodextrin (α‐CD) has been complexed with various poly(ethylene glycol) (PEG) derivatives in aqueous solution. It has been found that the end groups of PEG derivatives affect the complexation kinetics greatly, but have only a little influence on the thermodynamic behavior. By increasing the hydrophobicity of end groups, the complexation speeds up rapidly. On the other hand, the bulky end groups slow down the threading of polymeric guests into the cavity of CD. By changing the hydrophobicity and the size of end groups, the complexation rate can be adjusted in the range of several orders of magnitudes, which should be quite useful in the design of new supramolecular systems. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2050–2057, 2006  相似文献   
35.
We discuss the matrix model in a class of 11D time dependent supersymmetric backgrounds as obtained in [B. Chen, Phys. Lett. B 632 (2006) 393, hep-th/0508191]. We construct the matrix model action through the matrix regularization of the membrane action in the background. We show that the action is exact to all orders of fermionic coordinates. Furthermore we discuss the fuzzy sphere solutions in this background.  相似文献   
36.
The ZnS:Cu,Al,Au (P22G) phosphor powder was bombarded by an electron beam in an O2 ambient, Ar ambient and other mixture of gases. These gases consisted of mixtures of O2 and COx, and O2, COx and Ar gas. Auger electron spectroscopy (AES) was used to monitor changes in the surface composition of the P22G phosphor during electron bombardment. When the P22G phosphor powder was exposed to the electron beam in a water-rich O2 ambient, a chemically limited ZnO layer was formed on the surface. The electron beam degradation of the P22G phosphor powder was also performed in a dry O2 ambient and a layer of ZnSO4 was formed on the surface. The ZnSO4 formation decayed exponentially with time and it is postulated that this was due to the diffusion of the charge reactants through the ZnSO4 film to the reaction interfaces. The P22G phosphor exposed to the electron beam in an Ar ambient and to the other gas mixtures degraded at a lower rate than in the case of the O2 ambient. This suggests that Ar and COx may suppress the degradation of the P22G phosphor powder.  相似文献   
37.
单圈图的最大特征值序   总被引:3,自引:1,他引:2  
陈爱莲 《数学研究》2003,36(1):87-94
主要讨论了单圈图按其最大特征值进行排序的问题,确定了该序的前六个图。  相似文献   
38.
The centrosymmetric binuclear structure of [Pb2(H‐Norf)2(ONO2)4]shows the geometry around each lead(II) atom to be distorted trigonal bipyramidal with Pb–O distances ranging from 2.357(3) to 2.769(4) Å. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
39.
For the linear deterministic system with unknown orders and coefficients adaptive controls are given so that the closed-loop system is stabilized and the unknown parameters are consistently estimated. Moreover, if the parameter estimation is ignored, then the system input and output can be reduced to zero with an exponential rate.This project is supported by the National Natural Science Foundation of China.In Commemoration of the 15th Anniversary of the Acta Mathematicae Applicatae Sinica.  相似文献   
40.
提出了切伦科夫相关时间测量(CCT)中初始粒子在辐射体里产生的δ电子的干扰问题,以及降低干扰的方法. 通过模拟计算给出了北京τ-C工厂探测器初步设计中CCT的π/K分辨本领.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号