全文获取类型
收费全文 | 2126篇 |
免费 | 127篇 |
国内免费 | 7篇 |
专业分类
化学 | 1809篇 |
晶体学 | 13篇 |
力学 | 28篇 |
数学 | 228篇 |
物理学 | 182篇 |
出版年
2023年 | 31篇 |
2022年 | 50篇 |
2021年 | 84篇 |
2020年 | 93篇 |
2019年 | 67篇 |
2018年 | 35篇 |
2017年 | 42篇 |
2016年 | 84篇 |
2015年 | 92篇 |
2014年 | 88篇 |
2013年 | 123篇 |
2012年 | 161篇 |
2011年 | 199篇 |
2010年 | 111篇 |
2009年 | 90篇 |
2008年 | 141篇 |
2007年 | 118篇 |
2006年 | 105篇 |
2005年 | 86篇 |
2004年 | 80篇 |
2003年 | 56篇 |
2002年 | 40篇 |
2001年 | 17篇 |
2000年 | 11篇 |
1999年 | 12篇 |
1998年 | 10篇 |
1997年 | 7篇 |
1996年 | 15篇 |
1995年 | 6篇 |
1994年 | 11篇 |
1993年 | 14篇 |
1992年 | 7篇 |
1991年 | 10篇 |
1990年 | 7篇 |
1988年 | 10篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1985年 | 14篇 |
1984年 | 11篇 |
1982年 | 18篇 |
1981年 | 8篇 |
1980年 | 7篇 |
1979年 | 11篇 |
1978年 | 7篇 |
1977年 | 6篇 |
1976年 | 14篇 |
1975年 | 5篇 |
1974年 | 5篇 |
1973年 | 9篇 |
1930年 | 3篇 |
排序方式: 共有2260条查询结果,搜索用时 15 毫秒
141.
142.
143.
H.C. Hemaka Bandalusena William B. Zimmerman Julia M. Rees 《ournal of non Newtonian Fluid Mechanics》2010,165(19-20):1302-1308
This paper analyzes flow of a power-law fluid in a microfluidic device for the purpose of discovering an algorithm for rheometry. Previous investigations have shown that measurement of the velocity field or the pressure field and the inlet flow rate in a microfluidic T-junction allow determination of rheological parameters uniquely. However, the range of shear induced within the flow domain was limited by the constant pressure drop applied across the micro-device. To avoid this control restriction and further develop our inverse technique, a constant flow rate system was investigated. With this configuration, the flow rate can be set appropriately to achieve a desired shear range and the rheological parameters can be inferred from the measurement of mean pressure at the inlet and at the junction. By assuming creeping flow conditions and the existence of a Hagen-Poiseuille-like law for the relationship between the pressure drop and the volumetric flow rate, the analysis produces an algorithm that is self-consistent (demonstrates the Hagen-Poiseuille law) and permits the inference of the power-law parameters from the ratio of any two field variables measured over a region (averaged), the pressure drop, and the volumetric flow rate. 相似文献
144.
Victoria A. Piunova Hans W. Horn Gavin O. Jones Julia E. Rice Robert D. Miller 《Journal of polymer science. Part A, Polymer chemistry》2016,54(4):563-569
This study reports an application of trichloroethanol (TCE) as a bifunctional initiator for the synthesis of block copolymers (BCPs) by organocatalyzed ring‐opening polymerization (OROP) and atom transfer radical polymerization (ATRP). TCE was employed to synthesize a low dispersity poly (valerolactone) macroinitiator, which was subsequently used for the ATRP of tert‐butyl methacrylate. While it is known that TCE can serve as an initiator in ATRP, the ability to induce polymerization under OROP is reported for the first time. The formation of well‐defined BCPs was confirmed by gel permeation chromatography and 1H NMR. Computational studies were performed to obtain a molecular‐level understanding of the ring‐opening polymerization mechanism involving TCE as initiator. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 563–569 相似文献
145.
146.
147.
148.
Minimalistic Ditopic Ligands: An α‐S,N‐Donor‐Substituted Alkyne as Effective Intermetallic Conjugation Linker 下载免费PDF全文
Julia Rüger Christopher Timmermann Dr. Alexander Villinger Alexander Hinz Dr. Dirk Hollmann Prof. Dr. Wolfram W. Seidel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(32):11191-11195
The capability of donor‐substituted alkynes to link different metal ions in a side‐on carbon donor‐chelate coordination mode is extended from the donor centers S and P to the second period element N. The complex [Tp′W(CO)2{η2‐C2(S)(NHBn)}] (Tp′=hydrido‐tris(3,5‐dimethylpyrazolyl)borate, Bn=benzyl) bearing a terminal sulfur atom and a secondary amine substituent is accessible by a metal‐template synthesis. Subsequent deprotonation allowed the formation of remarkably stable heterobimetallic complexes with the [(η5‐C5H5)Ru(PPh3)] and the [Ir(ppy)2] moiety. Electrochemical and spectroscopic investigations (cyclic voltammetry, IR, UV/Vis, luminescence, EPR), as well as DFT calculations, and X‐ray structure determinations of the W–Ru complex in two oxidation states reveal a strong metal–metal coupling but also a limited delocalization of excited states. 相似文献
149.
Fischer J Hammerschmidt K Cheney DL Seyfarth RM 《The Journal of the Acoustical Society of America》2002,111(3):1465-1474
The acoustic structure of loud calls ("wahoos") recorded from free-ranging male baboons (Papio cynocephalus ursinus) in the Moremi Game Reserve, Botswana, was examined for differences between and within contexts, using calls given in response to predators (alarm wahoos), during male contests (contest wahoos), and when a male had become separated from the group (contact wahoos). Calls were recorded from adolescent, subadult, and adult males. In addition, male alarm calls were compared with those recorded from females. Despite their superficial acoustic similarity, the analysis revealed a number of significant differences between alarm, contest, and contact wahoos. Contest wahoos are given at a much higher rate, exhibit lower frequency characteristics, have a longer "hoo" duration, and a relatively louder "hoo" portion than alarm wahoos. Contact wahoos are acoustically similar to contest wahoos, but are given at a much lower rate. Both alarm and contest wahoos also exhibit significant differences among individuals. Some of the acoustic features that vary in relation to age and sex presumably reflect differences in body size, whereas others are possibly related to male stamina and endurance. The finding that calls serving markedly different functions constitute variants of the same general call type suggests that the vocal production in nonhuman primates is evolutionarily constrained. 相似文献
150.
Brezger B Hackermüller L Uttenthaler S Petschinka J Arndt M Zeilinger A 《Physical review letters》2002,88(10):100404
We demonstrate a near-field Talbot-Lau interferometer for C70 fullerene molecules. Such interferometers are particularly suitable for larger masses. Using three free-standing gold gratings of 1 microm period and a transversally incoherent but velocity-selected molecular beam, we achieve an interference fringe visibility of 40% with high count rate. Both the high visibility and its velocity dependence are in good agreement with a quantum simulation that takes into account the van der Waals interaction of the molecules with the gratings and are in striking contrast to a classical moiré model. 相似文献