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191.
Alexander S. Balankin Alireza K. Golmankhaneh Julián Patiño-Ortiz Miguel Patiño-Ortiz 《Physics letters. A》2018,382(23):1534-1539
This Letter is focused on the impact of fractal topology on the transport processes governed by different kinds of random walks on Cantor tartans. We establish that the spectral dimension of the infinitely ramified Cantor tartan is equal to its fractal (self-similarity) dimension D. Consequently, the random walk on the Cantor tartan leads to a normal diffusion. On the other hand, the fractal geometry of Cantor tartans allows for a natural definition of power-law distributions of the waiting times and step lengths of random walkers. These distributions are Lévy stable if . Accordingly, we found that the random walk with rests leads to sub-diffusion, whereas the Lévy walk leads to ballistic diffusion. The Lévy walk with rests leads to super-diffusion, if , or sub-diffusion, if . 相似文献
192.
In vitro AND in vivo UPTAKE OF BENZOPORPHYRIN DERIVATIVE INTO HUMAN AND MINISWINE ATHEROSCLEROTIC PLAQUE 总被引:1,自引:0,他引:1
York N. Hsiang M. Teresa Crespo Anna M. Richter Ashok K. Jain Miguel Fragoso Juli G. Levy 《Photochemistry and photobiology》1993,57(4):670-674
Abstract— Befnzoporphyrin derivative(BPD) has been demonstrated to be fnew potent photosentsitze for photodynamic therapy(PDT). Althought most of wrok on BPD has been focused on its potential applications for cancer tratment, BPD amy have potential clilnical uses in the treatment of artheros clerosis. The purposes of this study was to determine in vitro and vivo uptake of BPD into atherosclerotic plaque. Samples of atherosclerotic human femoral and popliteal arteries were incubated with BPD-monoacid, ring A(BPD-MA) for 1 h in the following concentrations: 1, 5, 10, 20, 30 and 40 μg/mL. fluorescence from all samplesd was determined by chemical etraction with a spectrofluorometer. the tissue concentration for human arteries was 0.37 ± 0.03, 2.78 ± 1.5, 3.6 ± 1.91, 7.15 ± 2.36, 8.06 ± 3.09 and 14.6 ± 4.81 μg/g, respectively. In aeddition, three miniswine were rendered atherosclerotic and given BPD 2.0 mg/ Kg intravenously. The concentration of BPD-MA in miniswine aorta was93–190 ng/g and the plaque/normal ration was 1.7–3.5, for miniswine cartoid artery contained 54 ng/g. this study showed that BPD-MA was taken up in atherosclerotic vesselsd both in vitro and in vivo and mey have potential for PDT of atherosclerosis. 相似文献
193.
Julián Palacios Julio Hernández Pablo Gómez Claudio Zanzi Joaquín López 《Experiments in fluids》2012,52(6):1449-1463
An experimental study of the impact of glycerol/water drops onto a dry glass surface at Reynolds and Weber numbers around the splashing/deposition threshold is presented. Some new observed phenomena that may shed further light on the mechanisms underlying air bubble entrainment and splashing for high-viscosity liquids are presented and discussed. The experiments were recorded with a high-speed camera using two complementary lighting setups that enhance the visualization of different features of the air entrainment phenomena: backlighting with a light diffuser and oblique lighting without diffuser. Besides the ring of micro-bubbles surrounding the central entrapped bubble and the cloud of bubbles entrained as a result of the interaction between a levitated thin film and the solid surface, which have been studied by other authors in previous works, a second ring of micro-bubbles that delimits the outer cloud of bubbles has been detected in our investigation. Attention is mainly focused on analyzing the dependency of the behavior of the two rings of micro-bubbles on the drop impact velocity, the ranges of the relevant dimensionless numbers in which the rings are formed and the existence, in certain impact conditions, of an abrupt increase in the size of the second ring, which substantially modifies the impact outcome. 相似文献
194.
Three new compounds in the AE‐Si‐P (AE = Sr, Eu, Ba) systems are reported. Sr2SiP4 and Eu2SiP4, the first members of their respective ternary systems, are isostructural to previously reported Ba2SiP4 and crystallize in the noncentrosymmetric I4 2d (no. 122) space group. Ba4Si3P8 crystallizes in the new structure type, in P21/c (no. 14) space group, mP‐120 Pearson symbol, Wyckoff sequence e30. In the crystal structures of Sr2SiP4 and Eu2SiP4 all SiP4 tetrahedral building blocks are connected via formation of P–P bonds forming a three‐dimensional framework. In the crystal structure of Ba4Si3P8, Si‐P tetrahedral chains formed by corner‐sharing, edge‐sharing, and P–P bonds are surrounded by Ba cations. This results in a quasi‐one‐dimensional structure. Electronic structure calculations and UV/Vis measurements suggest that the AE2SiP4 (AE = Sr, Eu, Ba) are direct bandgap semiconductors with bandgaps of ca. 1.4 eV and have potential for thermoelectric applications. 相似文献
195.
Site-Selective,Remote sp3 C−H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis
Basudev Sahoo Peter Bellotti Francisco Juliá-Hernández Qing-Yuan Meng Dr. Stefano Crespi Prof. Dr. Burkhard König Prof. Ruben Martin 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(38):9001-9005
A photoinduced carboxylation of alkyl halides with CO2 at remote sp3 C−H sites enabled by the merger of photoredox and Ni catalysis is described. This protocol features a predictable reactivity and site selectivity that can be modulated by the ligand backbone. Preliminary studies reinforce a rationale based on a dynamic displacement of the catalyst throughout the alkyl side chain. 相似文献
196.
Julián López-Gómez Toshitaka Nagai Tetsuya Yamada 《Archive for Rational Mechanics and Analysis》2013,207(1):159-184
We consider the Cauchy problem for a parabolic–elliptic system in ${\mathbb{R}^2}$ , which is amathematical model of chemotaxis and also amodel of self-attracting particles. In the critical mass case, we determine the basin of attraction of the steady-states for the Cauchy problem through a Lyapunov functional. 相似文献
197.
José A. Otero Reinaldo Rodríguez-Ramos Julián Bravo-Castillero Raúl Guinovart-Díaz Federico J. Sabina G. Monsivais 《International Journal of Solids and Structures》2013,50(3-4):609-622
A parallel fiber-reinforced periodic elastic composite is considered with transversely iso-tropic constituents. Fibers with circular cross section are distributed with the same periodicity along the two perpendicular directions to the fiber orientation, i.e., the periodic cell of the composite is square. The composite exhibits imperfect contact, in particular, spring type at the interface between the fiber and matrix is modeled. Effective properties of this composite for in-plane and anti-plane local problems are calculated by means of a semi-analytic method, i.e. the differential equations that described the local problems obtained by asymptotic homogenization method are solved using the finite element method. Numerical computations are implemented and comparisons with exact solutions are presented. 相似文献
198.
Eduardo López-López Federico J. Sabina Raúl Guinovart-Díaz Julián Bravo-Castillero Reinaldo Rodríguez-Ramos 《International Journal of Solids and Structures》2013,50(16-17):2573-2583
The overall properties of a binary elastic periodic fiber-reinforced composite, with transversely isotropic constituents in an anti-plane-strain deformation state, are studied here for a cell periodicity of square type. This analysis considers four different orientations of the axis of transverse isotropy of constituents with respect to the direction of fibers. Each case is characterized by very simple closed-form expressions for the effective coefficients, which were obtained using the asymptotic homogenization method. Local problems defined on a periodic square unit cell are solved using Weierstrassian and Natanzon’s functions and perturbation theory relative to small anisotropy. In the isotropic limit, comparison with rigorous bounds and some well-known mixing rules are made. Also, comparisons with finite element calculations show that the derived closed-form formulae provide excellent results even for large anisotropy. 相似文献
199.
de Souza Caroline Gondim Martins Fátima Itana Chaves Custódio Zocolo Guilherme Julião Figueiredo José Edson Fontes Canuto Kirley Marques de Brito Edy Sousa 《Analytical and bioanalytical chemistry》2018,410(26):6827-6836
Analytical and Bioanalytical Chemistry - The rapid and accurate quantification of lipopeptide families in biological samples are challenging. We present the development and validation of a method... 相似文献
200.
Diana Julião Ana C. Gomes Martyn Pillinger Rita Valença Jorge C. Ribeiro Isabel S. Gonçalves Salete S. Balula 《应用有机金属化学》2020,34(4):e5490
Regulations on the permissible levels of sulfur in transportation fuels are becoming ever more strict, with a global shift towards “zero sulfur” fuels, and the revamp of existing hydrodesulfurization (HDS) facilities to meet these lower caps is cost-prohibitive. Metal-catalyzed sulfoxidation chemistry is viewed as an economically viable desulfurization strategy that could complement conventional HDS technology. In the present work, the complex [η5-IndMo(CO)3Me] ( 1 ) (Ind = indenyl) was employed in the catalytic oxidative desulfurization (CODS) of model and real liquid fuels, using aqueous hydrogen peroxide (H2O2) as oxidant. After optimization of the CODS reaction parameters (diesel/H2O2 ratio, catalyst amount, temperature), a high-sulfur (2000 ppm) model diesel containing benzothiophene, dibenzothiophene, 4-methyldibenzothiophene and 4,6-dimethyldibenzothiophene could be completely desulfurized within 2 hr under solvent-free conditions or in the presence of the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF6) as extraction solvent. The catalyst formed under solvent-free conditions could be recycled without a significant decrease in desulfurization activity. The high performance of the CODS system was verified in the sulfur removal from a commercial untreated diesel fuel with a sulfur content of 2300 ppm, and a jet fuel with a sulfur content of 1100 ppm. Solvent-free CODS in combination with initial/final extraction gave desulfurization efficiencies of 70% for the diesel fuel and 55% for the jet fuel. CODS with [BMIM]PF6 in combination with initial/final extraction led to a sulfur removal of 95.9% for the diesel fuel, which is one of the best results yet reported for ODS of commercial diesels. 相似文献