Moisture sorption, transport, and hydrolytic degradation in polylactide

Management of moisture penetration and hydrolytic degradation of polylactide (PLA) is extremely important during the manufacturing, shipping, storage, and end-use of PLA products. Moisture transport, crystallization, and degradation, in PLA have been measured through a variety of experimental techniques including size-exclusion chromatography, differential scanning calorimetry, and X-ray diffraction. Quartz crystal microbalance and dynamic vapor sorption experiments have also been used to measure moisture sorption isotherms in PLA films with varying crystallinity. A surprising result is that, within the accuracy of the experiments, crystalline and amorphous PLA films exhibit identical sorption isotherms.     

Formation of ultrashort microwave pulses in coaxial cavities

We describe shaper cavities for the production of ultrashort microwave pulses with a minimum duration of one period of the high-frequency field and a power of several tens of megawatts. Experimental results are presented.Scientific and Research Insititute for Nuclear Physics at S. M. Kirov Polytechnical Institute, Tomsk. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 38, No. 12, pp. 1250–1256, December, 1995.     

Determination of the thermal stresses in anisotropic shells of revolution

Using the relations of the improved model of layered anisotropic shells based on the straight line assumption taking account of the thermal compression over the thickness we obtain a resolvent system of equations for shells whose properties depend on temperature. We carry out a study of the stresses in a two-layer cylindrical shell formed by winding as a function of the winding angle. Translated fromMatematicheskie Metody i Fiziko-Mekhanicheskie Polya, Issue 35, 1992, pp. 82–85.     

2H NMR spectra of 2-(p-heptylbenzoyloxy)-5-(p-heptylbenzenazo)tropone. A new sigmatropic liquid crystal

Liquid crystals incorporating in their molecular framework a seven-membered ring are still relatively rare [1]. Recently the synthesis and thermal behaviour of a series of liquid crystal materials having a tropone moiety in their mesogenic core have been reported [2-4]. These mesogens, based on a 2-(acyloxy)tropone core structure, show intramolecular migration of the acyl substituents between the two oxygen atoms at C-1 and C-2, an effect already known for simple 2-(acyloxy)tropones in their isotropic solutions [5]. This migration involves a concerted [1, 9]-sigmatropic rearrangement [2]. This rearrangement could play a major role in determining the properties of the mesophases: it has been suggested in fact that, because of this rearrangement, the mesogenic molecules acquire a mean rod-like shape which can sustain the mesophase formation [2].     

Numerical solution of the electron distribution function for ECRheating in magnetic mirror

The Fokker-Planck equation is solved with electron cyclotron resonance heating in a magnetic mirror with a fixed electrostatic potential on a loss-cone boundary and ECR heating. A self-consistent calculation of the plasma concentration justifies the fact that the degree of ionization of the ECR plasma is about 10%. The high values of the total electron energy (15-30 eV) are achieved. The electron concentration and the EVDF anisotropy degree are the nonmonotonic functions of the applied MW electric field. The basis for such dependencies is discussed. A linear perturbation analysis of the Vlasov equation together with with Maxwell's equations is briefly reviewed. The criteria for the start of unstable whistler oscillation growth are proposed. Using the simulated distribution function, the regimes where the unstable oscillations should to be taken into account are considered     

Studies on solution cast perfluorocarbonsulfonic acid ionomers

The thermal properties of perfluorocarbonsulfonic acid ionomer films cast from solution and their temperature-dependent far infrared spectra have been investigated. In addition to the endotherms and spectral changes associated with the loss of solvent as the films were heated, a significant exotherm has been observed and assigned to the relaxation associated with rearrangements resulting in partially crystallized phases in insoluble thermally treated membranes. © 1993 John Wiley & Sons, Inc.