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971.
Mixed crystals of Li[Kx(NH4)1−x]SO4 have been obtained by evaporation from aqueous solution at 313 K using different molar ratios of mixtures of LiKSO4 and LiNH4SO4. The crystals were characterized by Raman scattering and single-crystal and powder X-ray diffraction. Two types of compound were obtained: Li[Kx(NH4)1−x]SO4 with x?0.94 and Li2KNH4(SO4)2. Different phases of Li[Kx(NH4)1−x]SO4 were yielded according to the molar ratio used in the preparation. The first phase is isostructural to the room-temperature phase of LiKSO4. The second phase is the enantiomorph of the first, which is not observed in pure LiKSO4, and the last is a disordered phase, which was also observed in LiKSO4, and can be assumed as a mixture of domains of two preceding phases. In the second type of compound with formula Li2KNH4(SO4)2, the room-temperature phase is hexagonal, symmetry space group P63 with cell-volume nine times that of LiKSO4. In this phase, some cavities are occupied by K+ ions only, and others are occupied by either K+ or NH4+ at random. Thermal analyses of both types of compounds were performed by DSC, ATD, TG and powder X-ray diffraction. The phase transition temperatures for Li[Kx(NH4)1−x]SO4x?0.94 were affected by the random presence of the ammonium ion in this disordered system. The high-temperature phase of Li2KNH4(SO4)2 is also hexagonal, space group P63/mmc with the cell a-parameter double that of LiKSO4. The phase transition is at 471.9 K. 相似文献
972.
A. Canal Neto F. E. Jorge M. De Castro 《International journal of quantum chemistry》2002,88(2):252-262
We have generated Gaussian basis sets (GBSs) for the neutral and the first 20 cations members of the isoelectronic series of each ground state atom from He to Ne with the improved generator coordinate Hartree–Fock (IGCHF) method. For all atomic species studied here, our total energy errors are smaller than those calculated by the original GCHF method using GBSs of the same sizes. The largest difference between our total energy results and those computed with a numerical Hartree–Fock approach is equal to 215 μhartree for Co17+. We also compare the ionization potentials obtained with the IGCHF with the corresponding experimental values. © 2002 Wiley Periodicals, Inc. Int J Quantum Chem 88: 252–262, 2002 相似文献
973.
P. Bermejo-Barrera Antonio Moreda-Piñeiro Jorge Moreda-Piñeiro Adela Bermejo-Barrera 《Analytical and bioanalytical chemistry》1998,360(6):712-716
The use of Ir, W and Zr-coated graphite tubes, as permanent chemical modifiers, was studied for the determination of chromium in human scalp hair by ETAAS using the slurry sampling technique. The use of Mg(NO3)2 and Pd, as aqueous chemical modifiers, was also investigated and compared to the use of the permanent chemical modifiers. Scalp hair samples were pulverized using a Zr vibrational ball mill, (mean particle diameter of 0.8 μm) and suspended in ultrapure water. The lowest limit of detection, 44.5 μg kg–1,was achieved for the use of W-coated graphite tubes. The repeatability of the overall procedures (slurry preparation and ETAAS determination) were 15.7, 14.5 and 16.7% for W- and Zr-coated graphite tubes and Mg(NO3)2, respectively. The methods were applied to several reference materials, CRM 397 (human hair), DOLT-1 (dogfish liver) and DORM-1 (dogfish muscle), and the results obtained were in agreement to the certified values. Finally, the methods were applied to several human scalp hair samples from healthy adults. 相似文献
974.
Pilar Bermejo-Barrera Jorge Moreda-Piñeiro Antonio Moreda-Piñeiro Adela Bermejo-Barrera 《Mikrochimica acta》1996,124(1-2):111-122
A comparative study of different chemical modifiers in graphite furnace atomic absorption spectrometry for the direct determination of mercury in sea water samples, in synthetic sea water sample of high (72.8%) and low 34.2%) salinity and in aqueous solutions, was carried out. The use of reduced palladium produces better results. The mixture of palladium nitrate and ascorbic acid, gives the best limit of detection (1.9 gl–1). The use of reduced palladium and magnesium nitrate produced excellent recoveries (close to 100%) in the whole salinity range for all mercury concentration tested. The use of palladium nitrate alone or combined with magnesium nitrate gave good recoveries with respect to a real sea water sample for low salinities. The interference from the major components of sea water were completely removed by using reduced palladium and magnesium nitrate modifiers. Thus, a single calibration curve with synthetic sea water may be applied to the analysis of sea water samples of widely differing salinities. 相似文献
975.
B. I. Kharisov U. Ortiz Mendez J. Rivera de la Rosa 《Russian Journal of Coordination Chemistry》2006,32(9):617-631
Conditions for synthesizing unsubstituted phthalocyanine and its metal complexes from phthalonitrile at low temperatures (0–50°C) are optimized. Phthalocyanine and phthalocyaninates are produced under these conditions using activated Rieke metals, metals on inert substrate, sources of “soluble” metals in the form of unstable metal complexes, zeolites, solid-phase electrosynthesis of phthalonitrile, and UV irradiation. The use of pyrophoric metals is found to be the most efficient due to a large number of defects in their structure favoring the initial stage of phthalonitrile cyclization on a metal matrix. The suggested mechanism of formation of phthalocyanine macrocycle assumes participation of metal agglomerates occurring in activated metals. 相似文献
976.
Castillo-Tejas J Alvarado JF González-Alatorre G Luna-Bárcenas G Sanchez IC Macias-Salinas R Manero O 《The Journal of chemical physics》2005,123(5):054907
Nonequilibrium molecular-dynamics simulations are performed for linear and branched chain molecules to study their rheological and structural properties under simple shear and Poiseuille flows. Molecules are described by a spring-monomer model with a given intermolecular potential. The equations of motion are solved for shear and Poiseuille flows with Lees and Edward's [A. W. Lees and S. F. Edwards, J. Phys. C 5, 1921 (1972)] periodic boundary conditions. A multiple time-scale algorithm extended to nonequilibrium situations is used as the integration method, and the simulations are performed at constant temperature using Nose-Hoover [S. Nose, J. Chem. Phys. 81, 511 (1984)] dynamics. In simple shear, molecules with flow-induced ellipsoidal shape, having significant segment concentrations along the gradient and neutral directions, exhibit substantial flow resistance. Linear molecules have larger zero-shear-rate viscosity than that of branched molecules, however, this behavior reverses as the shear rate is increased. The relaxation time of the molecules is associated with segment concentrations directed along the gradient and neutral directions, and hence it depends on structure and molecular weight. The results of this study are in qualitative agreement with other simulation studies and with experimental data. The pressure (Poiseuille) flow is induced by an external force F(e) simulated by confining the molecules in the region between surfaces which have attractive forces. Conditions at the boundary strongly influence the type of the slip flow predicted. A parabolic velocity profile with apparent slip on the wall is predicted under weakly attractive wall conditions, independent of molecular structure. In the case of strongly attractive walls, a layer of adhered molecules to the wall produces an abrupt distortion of the velocity profile which leads to slip between fluid layers with magnitude that depends on the molecular structure. Finally, the molecular deformation under flow depends on the attractive force of the wall, in such a way that molecules are highly deformed in the case of strong attracting walls. 相似文献
977.
Carlos G. Bruhin Jorge M. Piwonka Mauricio O. Jerardino Gladys M. Navarrete Paulina C. Maturana 《Analytica chimica acta》1987
An electrothermal atomic-absorption procedure with the L'vov platform and a simple five- or ten-fold sample dilution with a matrix-modifier solution containing diammonium hydrogenphosphate, Triton X-100 and nitric acid, is described for the direct determination of relatively low levels of lead in heparinized blood. The graphite-furnace parameters and matrix-modifier composition are optimized. Sensitivity, imprecision, accuracy and detection limit are reported. Results obtained by standard addition for ten human blood samples (30–400 μg l?1 lead) were confirmed by an extraction/flame atomic-absorption reference method. Differences in mean lead values ranged from 2 to 31 μg l?1 with 5.1% mean relative difference. The mean relative standard deviations for consecutive and between-day determinations were 4.6 and 9%, respectively. Accuracy was verified by analyzing six bovine-blood standards certified for lead in the range 70–1100 μg l?1; deviations of found concentrations from expected values ranged from 0 to 44 μg l?1 with 4.3% mean relative error. Recovery experiments done with human blood gave 104% (90–121%) of the added lead. The method offers several advantages for routine application in comparison with the extraction/flame atomic-absorption procedure. 相似文献
978.
Bermejo-Barrera P Moreda-Piñeiro J Moreda-Piñeiro A Bermejo-Barrera A 《Analytical and bioanalytical chemistry》1996,355(2):174-179
A comparative study of different chemical modifiers for the direct determination of arsenic in real and in synthetic sea water samples of high (72.8 per thousand ) and low (34.2 per thousand ) salinity was carried out. The use of lanthanum chloride and magnesium nitrate (LOD=3.0 microg l(-1)) offers good recoveries for low salinities, while for high salinities an enhancement higher than 200% was obtained, rendering this method unsuitable for sea water samples. The use of silver nitrate (LOD=2.0 microg l(-1)) produces unfavourable analytical recoveries, around 150 and 300% for synthetic sea water of low and high salinity. Zirconium oxychloride (LOD=1.8 microg l(-1)) and palladium nitrate alone or combined with magnesium nitrate and reducing agents (LOD=1.1-1.3 microg l(-1)) produce analytical recoveries close to 100% for all arsenic concentration tried over all salinities; thus, a single calibration curve using aqueous standard solutions may be applied to the analysis of sea water samples over all salinities. Finally, the addition of reducing agents and magnesium nitrate to palladium does not improve the sensitivity. 相似文献
979.
González-Núñez ME Mello R Royo J Asensio G Monzó I Tomás F López JG Ortiz FL 《The Journal of organic chemistry》2004,69(26):9090-9099
The detailed study of the oxidation of thianthrene 5-oxide (1) with methyl(trifluoromethyl)dioxirane (5b) in different solvents and in the presence of (18)O isotopic tracers is reported. Thianthrene 5-oxide (1) is a flexible molecule in solution, and this property allows for transannular interaction of the sulfoxide group with the expected zwitterionic 7 and hypervalent 10-S-4 sulfurane 9 intermediates formed in the oxidation and biases the course of the reaction toward the monooxygenation pathway. 相似文献
980.
This work was aimed at identifying nucleotide polymorphic sites in a 359 bp region of the cytochrome b (cytb) mitochondrial gene of Iberian cattle (Bos taurus). This region is widely used as target in polymerase chain reaction-restriction fragment length polymorphism (PCR-RFLP) species identification studies in foodstuffs destined for human and animal consumption. Two different coexisting restriction patterns were observed in four of the six animals studied when the 359 bp DNA fragment was cleaved with PalI, HinfI, MvaI, RsaI, or MboI. The amplification of both genotypes with the mitochondrial-specific primers L14735 and H15149 revealed the absence of nuclear pseudo-cytb genes, confirming the existence of mitochondrial heteroplasmy. The two coexisting mtDNA fragments were selectively sequenced in PCR extracts in which one genotype predominated over the other, both exhibiting a sequence variation of 10.4%. From the 37 nucleotide mismatches observed between genotypes, 32 were transitions and five were transversions. While 31 of the nucleotide mismatches between genotypes resulted to be conservative at the amino acid level, six changes implied amino acid substitutions, five of them being located in the variable transmembrane region. Genetic analysis suggests the presence of an Asian background in the mitochondria of Iberian cattle: while one of the genotypes matched the published sequence for Bos taurus, the other genotype clustered with a B. primigenius indicus animal and close to an Asian Bos taurus animal. These results also suggest that a number of current PCR-RFLP species identification methods based on cytb sequences may not be reliable for the accurate detection and identification of bovine material: an alternative battery of enzymes consisting of MmeI, NlaIV, and AluI is proposed. 相似文献