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Chávez-Díaz Mercedes P. Luna-Sánchez Rosa M. Vazquez-Arenas Jorge Lartundo-Rojas Luis Hallen José M. Cabrera-Sierra Román 《Journal of Solid State Electrochemistry》2019,23(11):3187-3196
Journal of Solid State Electrochemistry - The passivation mechanism of the film formed on the alloy Ti-6Al-4V was evaluated in Hank’s solution to infer the properties of this alloy as an... 相似文献
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Martinez Jacob A. Gerasimchuk Nikolay N. Mebi Charles A. 《Transition Metal Chemistry》2020,45(8):569-575
Transition Metal Chemistry - A bis(p-toluenethiolato) dinuclear-carbonyl complex with triphenylphosphine coligand, [μ-(SC6H4CH3-p)2Fe2(CO)5(PPh3)], has been synthesized from... 相似文献
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Dr. Esther Roldan-Molina Maria M. Nievas Prof. Jorge A. R. Navarro Prof. J. Enrique Oltra 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(37):8296-8301
A novel concept for the synthesis of halogenated, conjugated dienes is disclosed: the CpTiCl2-catalyzed coupling of keto-alkynes, in the presence of Me3SiBr/Et3N ⋅ HBr. This reaction provided five-, six-, and seven-membered carbocycles, nitrogenated heterocycles, as well as six-membered oxygenated heterocycles leading to a brominated conjugate diene. These products showed high reactivity in the Diels–Alder, Suzuki, and Sonogashira reactions, giving complex chemical structures in only three steps from the corresponding acyclic keto-alkyne. Hopefully, this strategy will pave the way towards the synthesis of bioactive natural products and new materials. 相似文献
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Andreia S. R. Oliveira Patrícia V. Mendonça Arménio C. Serra Jorge F. J. Coelho 《Journal of polymer science. Part A, Polymer chemistry》2020,58(1):145-153
The supplemental activator and reducing agent (SARA) atom transfer radical polymerization (ATRP) mediated by Na2S2O4 in the presence of air, without external deoxygenation or additional oxygen scavengers, is reported for several vinyl monomers: methyl acrylate (MA), n-butyl acrylate (n-BA), methyl methacrylate (MMA), 2-(dimethylamino)ethyl methacrylate (DMAEMA), poly(ethylene glycol) methyl ether acrylate (OEOA), and styrene (Sty). The polymerizations can be conducted in aqueous medium or using organic/water mixtures as solvent, with low concentration of copper, near room temperature. In the absence of any external deoxygenation, several well-defined homopolymers and block copolymers were obtained (Ð < 1.3). The evolution of the oxygen concentration during the polymerizations was monitored with an optical oxygen sensor. The consumption of oxygen prior polymerization in ethanol/water mixtures was attributed to the combined presence of Na2S2O4 and alkyl halide initiator, which led to a lower initiation efficiency (Ieff). This could be overcome by decreasing the headspace volume of the reaction. The system reported exhibited the potential to be scalable, which is very relevant from an industrial standpoint. © 2019 Wiley Periodicals, Inc. J. Polym. Sci. 2020 , 58, 145–153 相似文献
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Díaz Mario G. Andrada Matías F. Vega-Hissi Esteban G. Martinez Juan C. Garro 《Structural chemistry》2019,30(1):237-245
Structural Chemistry - An in silico analysis of the oxidation mechanism of allyl methyl disulfide (AMDS) by hydroxyl radical was achieved at DFT level using B3LYP, CAM-B3LYP, M06-2X, and BMK... 相似文献
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For every Ore extension we construct a chain complex giving its Hochschild homology. As an application we compute the Hochschild and cyclic homology of an arbitrary multiparametric affine space and the Hochschild homology of the algebra of differential operators over this space, in the generic case. 相似文献