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141.
142.
Photoacoustic amplitude and phase measurements have been carried out near the superconducting transition temperature in the
highT
csuperconductor YBa2Cu3O7. In both the samples investigated, the photoacoustic phase undergoes an anomalous step-like decrease aroundT
c≈ 96 K and increases at lower temperatures. A clear temperature hysteresis for the phase change has been noticed. No anomalous
variation has been observed in the amplitude values. Neither phase nor amplitude shows any anomaly in a non-superconducting
sample of the same composition. 相似文献
143.
144.
Tze Chi Jao Munmaya K. Mishra Isaac D. Rubin Jean Duhamel Mitchell A. Winnik 《Journal of Polymer Science.Polymer Physics》1995,33(8):1173-1181
Pyrene-labeled functionalized ethylene-propylene (EP) copolymer was prepared by grafting 1-pyrenebutyrylhydrazine onto EP copolymer through maleic anhydride pendants. The EP copolymer contained 60 mol % ethylene; its weight-average molecular weight (Mw) was 148,000. The pyrene-labeled amide functionalized EP copolymer, PA-EP(60/40), was made to simulate the amine functionalized EP copolymers that are commonly used as dispersant additives in motor oils. UV absorption spectra, fluorescence emission and excitation spectra, and fluorescence decay profiles of the pyrene were studied to determine the copolymer conformation and dynamics in methylcyclohexane and tetrahydrofuran (THF). The pyrene fluorescence characteristics of PA-EP(60/40) were highly dependent on the solvent. The dependence of fluorescence emission intensity on the excitation wavelength was large in methylcyclohexane and moderate in THF. A frequency shift of about 2 nm was observed between the excitation spectrum obtained with the emission line at 377 nm and that at 550 nm in the methylcyclohexane solutions, but no shift was found in the corresponding tetrahydrofuran solutions. The ratios of the preexponential factors (a21/a22) of the excimer decays obtained in both methylcyclohexane and THF solutions were different from ?1.0. However, the deviation of the excimer formation process from the Birks scheme is small in THF but large in methylcyclohexane. In addition, the Huggins constants obtained from intrinsic viscosity measurements of the PA-EP(60/40) copolymer solutions suggest that copolymer aggregation occurs in methylcyclohexane but not in THF. H-bonding between two pyrene-containing pendants is apparently the main driving force for the formation of the ground state pyrene complex. THF is found to be effective in inhibiting the H-bonding formation. © 1995 John Wiley & Sons, Inc. 相似文献
145.
Applications of Mathematics - In this paper, we consider the direct and inverse problem for time-fractional diffusion in a domain with an impenetrable subregion. Here we assume that on the boundary... 相似文献
146.
M. C. P. Isaac V. R. Vanin O. A. M. Helene 《Zeitschrift für Physik A Hadrons and Nuclei》1990,335(3):243-246
The Internal Bremsstrahlung Electron Capture spectrum from55Fe was measured with a HPGe detector. The total spectrum was unfolded taking into account the secondary detection effects and agrees with Glauber and Martin calculations. The measured intensity relative to K capture in the range 35 to 231 keV is 3.24(6)·10?5 while the calculated one is 3.20·10?5. TheQ value for the electron capture was deduced as 230.7(19) keV. 相似文献
147.
German Urbina-Villalba Estrella Rogel Maria Lupe Márquez Isaac Reif 《Journal of computer-aided molecular design》1994,8(3):273-282
Summary The semiempirical MNDO method has been used in order to examine the variation of the molecular properties of hydrocarbons CnH2n+2 (with 1n19) and ethylene oxide chains CH3(CH2CH2O)mCH3 (with 1m19) as a function of their molecular length. Least-square fits of those properties have been calculated, along with two mathematical relations between the hydrophile-lipophile balance of alkyl-phenol ethoxylated surfactants and (1) the ratio of molecular lengths between their lipophilic and hydrophilic branches; (2) the intermolecular energies between the molecules of surfactant, water and hexane. 相似文献
148.
Abstract— The quantum yields and lifetimes of the fluorescence of tyrosine and tryptophan were determined in D2O-H2O and glycerol-H2O solvent mixtures of varying composition from 10 vol.% to 100% H2O at 15°C. Forboth amino acids the ratio of the quantum yields in D2O and H2O (i.e., qD/qH) was smaller than the ratio of the corresponding lifetimes (D/H). For tyrosine the ratio of the quantum yields in glycerol and H2O (qG/qH) was also smaller than the corresponding G/H ratio, but for tryptophan qG/gHG/H. The proximity of the q vs. plots for tyrosine in the two solvent mixtures indicates that at 15°C neither D2O nor glycerol, in the pure state or when diluted with H2O, quench tyrosine significantly. However, H2O quenches tyrosine by a dynamic process, which increases both the radiative and the nonradiative rate constant. The quenching action is attributed to a tyrosine-H2O exciplex, whose formation is independent of bulk viscosity and dielectric constant. Unlike tyrosine, tryptophan is quenched weakly by D2O by a static process at 15°C (i.e., involving no change in), but H2O quenches tryptophan much more efficiently by a dynamic process, which involves the nonradiative rate constant, but not the radiative constant. These results are explained on the basis of electrostatic complexation of the ammonium group to the carbon atom adjacent to the ring nitrogen with a lifetime which is longer thanin D2O but shorter thanin H2O, with solvent reorientation possibly also being an important factor in the quenching. This explanation is consistent with the fact that concentrated (8 M) urea increases q andof aqueous tryptophan ? 15–20%, while guanidine hydrochloride (6.4 M) has the opposite effect, i.e., it decreases q and t of tryptophan ? 15–20%, and with the fact that neither 8 M urea nor 6.4 M guanidine hydrochloride affects any fluorescence parameter of tyrosine at all. 相似文献
149.
Undergoes elimination on treatment with m-chloroperbenzoic acid, performic acid or SO2CI2/NaOCI, while iodine is retained in the novel peracid dehydrogenation of . 相似文献
150.
Abstract Phototropism is a common property of plants, but it is not known if different species use the same photoreceptor for their response. We have determined fluence-response relations for phototropism in response to brief, broad-band blue irradiation for four plant species grown under red light (Amaranthus paniculatus, Linum usitatissimum, Vigna radiata and Medicago sativa) and compared these to ones previously obtained for Pisum sativum and Zea mays, grown under similar conditions. Curves for all species showed a bell-shaped dependence on fluence, a characteristic of first positive curvature as originally defined for the Avena coleoptile, and had a similar optimal fluence, near 3 H.mol m?2. We have obtained an action spectrum in the blue and UV spectral regions for first positive phototropism of the hypocotyl of alfalfa grown under red light. Fluence-response curves at wavelengths between 300 and 500 nm were nearly identical in shape and magnitude; whereas below 300 nm, their slopes and maximum curvatures were reduced. The action spectrum showed that activity rose sharply at wavelengths below 500 nm, peaked at 450 nm with shoulders on either side of that peak, and had lesser peaks at 380 and, in the far ultraviolet, at 280 nm. This action spectrum was very similar to ones in the literature (obtained between 350 and 500 nm) for first and second positive phototropism of oat coleoptiles. We conclude that the same photoreceptor mediates phototropism in oat and alfalfa. 相似文献