Is life improbable?

E. P. Wigner's argument that the probability of the existence of self-reproducing units, e.g., organisms, is zero according to standard quantum theory is stated and analyzed. Theorems are presented which indicate that Wigner's mathematical result in fact should not be interpreted as asserting the improbability of self-reproducing units.     

Expedient synthesis of villosin and its isomer (E)-labda-8(17),12,14-trien-15(16)-olide

The synthesis of the title compounds has been achieved in concise, highly regiocontrolled fashion from commercially available (+)-sclareolide. In addition, we offer evidence that the structure of a newly reported natural product from Zingiber ottensii is incorrect.     

On then-cutset property

For a partially ordered setP and an elementx ofP, a subsetS ofP is called a cutset forx inP if every element ofS is noncomparable tox and every maximal chain ofP meets {x}∪S. We letc(P) denote the smallest integerk such that every elementx ofP has a cutsetS with ‖S‖?k: Ifc(P)?n we say thatP has then-cutset property. Our results bear on the following question: givenP, what is the smallestn such thatP can be embedded in a partially ordered set having then-cutset property? As usual, 2 ⁿ denotes the Boolean lattice of all subsets of ann-element set, andB _n denotes the set of atoms and co-atoms of 2 ⁿ . We establish the following results: (i) a characterization, by means of forbidden configurations, of whichP can be embedded in a partially ordered set having the 1-cutset property; (ii) ifP contains a copy of 2 ⁿ , thenc(P)?2^[n/2]?1; (iii) for everyn>3 there is a partially ordered setP containing 2 ⁿ such thatc(P)<c(2 ⁿ ); (iv) for every positive integern there is a positive integerN such that, ifB _m is contained in a partially ordered set having then-cutset property, thenm?N.     

Infinite products for power series

An algorithm is introduced and shown to lead to a unique infinite product representation for a given formal power series A(z) with A(0) = 1. The infinite product is , where all b_n ≠ 0, r_n , and r_n+1 > r_n. The degree of approximation by the polynomial (1 + b₁z^r₁) · · · (1 + b_nz^r_n) is also considered.     

A C-symplectic free -manifold with contractible orbits and

An interesting question in symplectic geometry concerns whether or not a closed symplectic manifold can have a free symplectic circle action with orbits contractible in the manifold. Here we present a c-symplectic example, thus showing that the problem is truly geometric as opposed to topological. Furthermore, we see that our example is the only known example of a c-symplectic manifold having non-trivial fundamental group and Lusternik-Schnirelmann category precisely half its dimension.

     

Fluorinations with complex metal fluorides. Part 6 [1] fluorination of yridine and related compounds with caesium tetrafluorocobaltate(III) [2]

Pyridine has been fluorinated over caesium tetrafluorocobaltate(III) (CsCo^IIIF₄) at 300–400°C to give a mixture of undecafluoro-N-methylpyrrolidine, bis(trifluoromethyl)amine, pentafluoropyridine and several polyfluoropyridines; the product composition depended to some extent on the geometry of the reactor. The fluorinations of pentafluoropyridine, piperidine and undecafluoropiperidine were also investigated.