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131.
132.
M. A. Rizzutto N. Added M. H. Tabacniks F. R. Espinoza-Qui?ones S. M. Palacio R. M. Galante R. M. Galante N. Rossi R. A. Welter A. N. Módenes 《Journal of Radioanalytical and Nuclear Chemistry》2006,269(3):727-731
Summary Kulcsszavak (angolul, ha nem azonos az elozovel) 相似文献
133.
John Ginsburg 《Order》1989,6(2):137-157
For a partially ordered setP and an elementx ofP, a subsetS ofP is called a cutset forx inP if every element ofS is noncomparable tox and every maximal chain ofP meets {x}∪S. We letc(P) denote the smallest integerk such that every elementx ofP has a cutsetS with ‖S‖?k: Ifc(P)?n we say thatP has then-cutset property. Our results bear on the following question: givenP, what is the smallestn such thatP can be embedded in a partially ordered set having then-cutset property? As usual, 2 n denotes the Boolean lattice of all subsets of ann-element set, andB n denotes the set of atoms and co-atoms of 2 n . We establish the following results: (i) a characterization, by means of forbidden configurations, of whichP can be embedded in a partially ordered set having the 1-cutset property; (ii) ifP contains a copy of 2 n , thenc(P)?2[n/2]?1; (iii) for everyn>3 there is a partially ordered setP containing 2 n such thatc(P)<c(2 n ); (iv) for every positive integern there is a positive integerN such that, ifB m is contained in a partially ordered set having then-cutset property, thenm?N. 相似文献
134.
Peptidosulfonamides are an emerging group of peptidomimetics with a variety of applications in medicinal chemistry. We present a novel approach to the synthesis of peptidosulfonamides, and apply it to a series of new potential inhibitors of the bacterial peptidoglycan biosynthesis enzymes MurD and MurE. The synthesis was conducted via N-phthalimido β-aminoethanesulfonyl chlorides, which are new building blocks for the synthesis of peptidosulfonamides. In the most crucial step, sulfonic acids or their sodium salts were converted into the corresponding sulfonyl chlorides using an excess of either SOCl2 or SOCl2/DMF, and then coupled to the C-protected amino acid. None of the compounds significantly inhibited MurD, however, some inhibited MurE; one had an IC50 below 200 μM, which constitutes a promising starting point for further development. Molecular modelling simulations were performed on two analogues to investigate the absence of inhibitory activity of the sulfonamide compounds on MurD. 相似文献
135.
136.
An algorithm is introduced and shown to lead to a unique infinite product representation for a given formal power series A(z) with A(0) = 1. The infinite product is , where all bn ≠ 0, rn
, and rn+1 > rn. The degree of approximation by the polynomial (1 + b1zr1) · · · (1 + bnzrn) is also considered. 相似文献
137.
138.
An interesting question in symplectic geometry concerns whether or not a closed symplectic manifold can have a free symplectic circle action with orbits contractible in the manifold. Here we present a c-symplectic example, thus showing that the problem is truly geometric as opposed to topological. Furthermore, we see that our example is the only known example of a c-symplectic manifold having non-trivial fundamental group and Lusternik-Schnirelmann category precisely half its dimension.
139.
140.
Raymond G. Plevey Richard W. Rendell John Colin Tatlow 《Journal of fluorine chemistry》1982,21(2):159-169
Pyridine has been fluorinated over caesium tetrafluorocobaltate(III) (CsCoIIIF4) at 300–400°C to give a mixture of undecafluoro-N-methylpyrrolidine, bis(trifluoromethyl)amine, pentafluoropyridine and several polyfluoropyridines; the product composition depended to some extent on the geometry of the reactor. The fluorinations of pentafluoropyridine, piperidine and undecafluoropiperidine were also investigated. 相似文献