Chemische Bestimmung von Alkohol in Weinen und Destillaten mit Dichromat

Ohne Zusammenfassung     

Zur Frage der Bestimmung des Trockensubstanzgehaltes von St?rkesirupen durch Messung der Refraktion

Ohne Zusammenfassung     

A luminescent probe containing a tuftsin targeting vector coupled to a terbium complex

Orthogonal protection strategies have been used to prepare a series of luminescent and MRI active lanthanide complexes containing a tuftsin targeting vector that are internalised by macrophage cells.     

Lowness for isomorphism,countable ideals,and computable traceability

We show that every countable ideal of degrees that are low for isomorphism is contained in a principal ideal of degrees that are low for isomorphism by adapting an exact pair construction. We further show that within the hyperimmune free degrees, lowness for isomorphism is entirely independent of computable traceability.     

Self-Assembly and Fluorescence of Tetracationic Liquid Crystalline Tetraphenylethene

A series of tetraguanidinium tetraphenylethene (TPE) arylsulfonates with different chain lengths was prepared via ionic self-assembly of tetraguanidinium TPE chloride and the respective methyl arylsulfonates. Liquid crystalline properties were studied by differential scanning calorimetry, polarizing optical microscopy and X-ray diffraction. Tetraguanidinium TPE arylsulfonates with chain lengths of C₈–C₁₂ displayed hexagonal columnar mesophases over a broad temperature range, while derivatives with longer chains showed oblique columnar phases. In solution all compounds displayed aggregation-induced emission behaviour. Temperature-dependent luminescence spectra of the bulk phase of the tetraguanidinium TPE arylsulfonate with C₁₄ side chains revealed a strong luminescence both in the solid state and the oblique columnar mesophase. The emission behaviour was rationalized by a unique combination of restriction of intramolecular rotation of the TPE core, Coulomb interaction between the guanidinium cations and π–π interactions of the anionic arylsulfonate moieties.     

Tuning interfacial charge-transfer excitons at polymer-polymer heterojunctions under hydrostatic pressure

We present photoluminescence spectroscopy of blend thin films of poly(9,9-di-n-octylfluorene-alt-benzothiadiazole) (F8BT) with electron-donating copolymers under hydrostatic pressure. The photoluminescence spectrum of F8BT redshifts by 530+/-60 meV over pressures of 0.1 MPa-8.8 GPa. That of the interfacial charge-transfer exciton redshifts by 270-370 meV over a similar pressure range. Despite the relatively small shift of the charge-transfer exciton, the excited state dynamics at the molecular heterojunction are strongly enhanced due to the decreasing intermolecular distance, leading to favored exciplex emission.