Einige Probleme im Zusammenhang mit der direkten Bestimmung der spezifischen Wärmen mittels Differential Scanning-Kalorimetrie

The relation between sample mass andDSC-amplitude was investigated under various experimental conditions for vitreous quartz, both as discs and powders. Contrary to other authors³ proportionality has been found up to the highest masses (75 mg) used. A statistical analysis of the data indicates that the accuracy of directC _p-measurements byDSC can be increased by determining the blank value by extrapolation of the amplitudes for several masses to zero mass instead of using the usual procedure, which involves a run with the empty pans. The overall error ofC _p due to instrument errors is estimated not to exceed 2%.     

Laser spectroscopic determination of the 50V quadrupole moment

Using the method of atomic-beam magnetic resonance, detected by laser-induced resonance fluorescence (ABMR-LIRF), the atomic ground-state hyperfine intervals of ⁵⁰V were precisely measured. A quadrupole moment ratio $\text{Q(}{}^{50}\text{V}\text{) / (}{}^{51}\text{V}\text{= ?4.03(3)}$ is obtained which results in $\text{Q(}{}^{50}\text{V}\text{) = +0.21(4)}\text{b}$.     

Einfluß elektrischer Felder auf die Eigenabsorptionskante fester Körper

This paper realizes an idea ofRedfield in a general and quantitative manner: Charged point defects produce local electric fields in a crystal which cause a change in the absorption-constant compared with the absorption-constant of an undisturbed crystal (Franz-Keldysh-effect). Thus one gets a tail in the absorption constant decreasing from the ideal intrinsic absorption edge towards longer wave-lengths. Applying an external fieldF one finds an additional, frequency-dependent absorptionconstantΔα. Its magnitude and spectral distribution depend on the concentration of defects. For external fields smaller than the internal onesΔα∝ F ² holds at all frequencies. The results are compared with those found byFranz.     

Makrocyclische,luftbeständige acht- und sechselektronenliganden für übergangsmetalle

The synthesis of five eight-electron-ligands, two six-electron-ligands and one four-electron-ligand for transition metals is described. These heterocycles contain in each case arsenic and sulfur as heteroatoms, and additionally oxygen in one case.     

Hinreichende Bedingungen bei Differential-Ungleichungen vierter Ordnung

Ohne Zusammenfassung