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81.
Gerd Teschke Mariya Zhariy Maria Joana Soares 《Mathematical Methods in the Applied Sciences》2008,31(5):575-587
We develop a regularization technique for Perona–Malik diffusion equations that relies on multiresolution techniques. The main result of this paper is to show that the chosen discretization overcomes the ill posedness of the nonlinear Perona–Malik model. The resulting algorithm is tested and the results are compared with pixel‐based methods. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
82.
Henrique E. Toma Tulio E. Chavez-Gil Reginaldo C. Rocha Hercílio R. Rechenberg 《Journal of inclusion phenomena and macrocyclic chemistry》1999,34(1):57-68
A novel multibinding species has been obtained by attaching four aliphatic polyamine chains to an iron(II)-polyimine centre, derived from 2,6-diacetylpyridine. Molecular simulations for the complex corroborate the evidence from 1H NMR spectroscopy of a symmetric structure, with the four polyamines displaying a tetrahedral arrangement around the metal centre. The protonated polyamine complex interacts with hexacyanoferrate(II) ions, leading to an inclusion compound which has been characterized based on vibrational and Mössbauer spectroscopy, and on cyclic voltammetry. 相似文献
83.
Slavomíra Doktorovová Joana Araújo Marisa L. Garcia Erik Rakovský Eliana B. Souto 《Colloids and surfaces. B, Biointerfaces》2010,75(2):538-542
The aim of this study was to develop nanostructured lipid carriers (NLC) for topical delivery of fluticasone propionate (FP) with the aim to further improve the safety profile and decrease the adverse-side effects commonly reported in topical corticotherapy. NLC are colloidal drug-carriers consisting of a blend of a solid lipid and a small amount of liquid lipid since these carriers have proved to be effective in epidermal targeting in particular of glucocorticoids. NLC consisting of glyceryl palmito-stearate, and PEG-containing medium chain triglycerides mixture, stabilised by polysorbate 80 and soybean phosphatidylcholine were prepared. A mean particle size between 380 and 408 nm and entrapment efficacy of 95% were obtained for FP-loaded NLC. The crystallinity and polymorphic phase behaviour of FP-free and FP-loaded NLC were examined by differential scanning calorimetry and wide angle X-ray diffraction. Results revealed a low-crystalline structure and confirmed the incorporation of FP into the particles. The suitability of PEG-containing liquid lipids to form the lipid matrix of NLC was also confirmed. 相似文献
84.
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86.
Cláudia M. Morais Valérie Montouillout Michael Deschamps Dinu Iuga Franck Fayon Filipe A. A. Paz João Rocha Christian Fernandez Dominique Massiot 《Magnetic resonance in chemistry : MRC》2009,47(11):942-947
From one‐ to two‐ and three‐dimensional MAS NMR solid‐state experiments involving 31P and 27Al, we show that the structure of microporous alumino‐phosphate AlPO4‐40 contains at least four times more sites than expected, and we attribute two types of AlIV sites. The newly described 27Al‐31P MQ‐HMQC opens new possibilities of describing details of three‐dimensional bounded networks. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
87.
This work proposes a Progressive Assisted Sorting Algorithm (PASA) based on a multicriteria evaluation ELECTRE-type method.
The purpose of the PASA is to aid a decision maker to progressively sort a set of alternatives into a set of categories, which
we considered are ordered (ordinal sorting), following a consistency principle. We consider the principle that if an alternative
outranks (is as good as) a second one, then it must belong to the same category or to a better category. The set of alternatives
already sorted by the decision maker will implicitly define the categories, and will constrain the range of categories where
other alternatives may be sorted. We show how the same idea may be used in an aggregation/disaggregation approach, considering
some parameters of ELECTRE are not fixed a priori, but are constrained only by the examples provided. In this context, we
establish a “convex-shape property” stating that the range of possible categories for an alternative is always an interval
of categories. A discussion contrasting this approach with ELECTRE TRI is included in the conclusions. 相似文献
88.
Determination of surface ζ‐potential and isoelectric point of carbon surfaces using tracer particle suspensions
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Joana M. Vasconcelos Federico Zen James A. Behan Paula E. Colavita 《Surface and interface analysis : SIA》2017,49(8):781-787
Carbon materials are widely used in a range of applications from biomaterials to sensing and electronics. Many of these applications rely on the ability to control carbon/water interfacial properties, in particular, surface charge density. This work reports a study of the electrokinetic properties of amorphous carbon thin films as a function of pH and surface chemistry. Surface ζ‐potential (SZP) and isoelectric point were determined using the tracer particle method. Initially, the use of sulfonated and amine‐terminated latex bead suspensions as tracer particles for the determination of SZP of reference polymer surfaces was validated. The tracer particle method was then applied to the determination of SZP and isoelectric point of macroscopic carbon surfaces with different surface chemistry. Highly graphitic and sp3‐rich hydrogenated carbon surfaces were found to display negative SZP, as expected for hydrophobic surfaces. The isoelectric point of the most highly graphitic surface was found to be pHiso = 3.7. Surface oxidation of these films resulted in a decrease of SZP at all pH values and in a downshift of pHiso to values lower than 1.5, consistently with the presence of surface acidic groups arising from oxidation. Results indicate that the specific choice of acid/base chemistry for the tracer particles does not significantly affect either SZP or pHiso determinations. These results show that the tracer particle method in combination with widely available latex beads as tracers can be applied for the determination of carbon SZP as a function of pH. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
89.
Thales R. de Moura Sahra L. Cavalcanti Paulo R. D. V. de Godoy Elza T. Sakamoto-Hojo Fillipe V. Rocha Eduardo T. de Almeida Victor M. Deflon Antonio E. Mauro Adelino V. G. Netto 《Transition Metal Chemistry》2017,42(6):565-574
Complexes of the type cis-[PdX2(imzt)(PPh3)] {imzt = imidazolidine-2-thione; PPh3 = triphenylphosphine; X = Cl (1), Br (2), I (3), SCN (4)} have been synthesized and characterized by elemental analyses, molar conductance, IR and 1H NMR spectroscopies. The complex 1·MeOH was obtained from the reaction of [PdCl2(CH3CN)2], imidazolidine-2-thione and triphenylphosphine in CHCl3/CH3OH. Complexes 2·MeOH, 3 and 4 were prepared by metathesis of the chlorido ligands in 1 with bromide, iodide and thiocyanate, respectively. Elemental analyses showed good agreement with the expected mononuclear compositions, while the molar conductivities of the complexes in DMF were consistent with their nonelectrolytic nature. NMR spectra confirmed coordination of the imidazolidine-2-thione and triphenylphosphine ligands. Single-crystal X-ray diffraction determination of 1·CH3OH showed that the coordination geometry around PdII is nearly square planar, with the chlorido ligands in a cis configuration. All four complexes have been tested in vitro by XTT assay for their cytotoxicity against human glioblastoma cell line (U87MG). The binding of 1 with guanosine was studied by 1H NMR spectroscopy, revealing that the coordination takes place via N7. 相似文献
90.
Application of X-ray diffraction, micromagnetic and hole drilling methods for residual stress determination in a ball bearing steel ring 总被引:1,自引:0,他引:1
C. O. D. Martins Ph.D. T. R. Strohaecker A. S. Rocha T. K. Hirsch 《Experimental Mechanics》2005,45(4):344-350
A basic understanding of distortion problems requires the analysis of a complete manufacturing process including an almost
complete overview of residual stress states in the component during each production step. To reduce the measurement time in
the future, three measurements methods (X-ray diffraction, micromagnetic and blind hole drilling methods) have been used to
analyze residual stress states in machined AISI 52100 ball bearing rings. X-ray diffraction was used as a state-of-the-art
method for machining induced residual stresses with pronounced gradients. The ring exhibited a complex residual stress state
with high tensile residual stresses at the surface, a strong gradient in depth, and also showed some variation along the outer
circumference due to a superimposition of machining induced residual stresses and effects from the clamping device process.
Due to this surface state, micromagnetic signals depend on the analyzing frequency. A calibration of the signals was only
possible with the X-ray diffraction data. The results of the three different measurement methods correlate reasonably well. 相似文献