A facility for multielemental analysis by PIXE and the19F(p, αγ)16O reaction

Specific advantages with Particle Induced X-Ray Emission are: its (1) multielemental capability, especially when combined with nuclear techniques for lighter elements, (2) speed, (3) low detection limits for small samples and (4) accuracy. To make full use of these advantages, analytical parameters have to be chosen optimally and the facility to be carefully designed. This paper describes an experimental facility constructed to permit continuous development work to optimize the analytical conditions and to allow the gradual implementation of automatic control. Emphasis is also put on the simultaneous use of proton induced gamma rays from fluorine. The features and the performance of the set-up including its accuracy, precision and experimental detection limits are reported.     

The surface tension of concentrated aqueous solutions of 1.1-electrolytes measured by means of Wilhelmy and laser light scattering methods

Surface tension measurements were made on concentrated (<4 moles/kg) aqueous solutions of the following 1.1-electrolytes: KF, KCl, KI, HCl, and HNO₃. Two different measurement techniques were used: the Wilhelmy slide method and a method based on the scattering of laser light by small amplitude liquid surface waves. The surface tension determined by the two methods agrees within ±0.5% and for each solution it is found to vary almost linearly with concentration. The shear viscosity was also measured for these solutions by means of the laser method and a standard flow viscosimeter. The measured values were found to agree within ±5%.     

Synthesis of penicillin analogs, (--)-methyl 6-epi-6-bromobisnorpenicillanate and (+/-)-methyl 6-epi-bromopenicillanate.

The [(4-methoxycarbonylthiazolidino)carbonyl-dihalomethyl]phenylmercury compounds 2a,b and 5a,b have been synthesized. When heated in refluxing bromobenzene they form halogenated penicillin analogs. (--)-Methyl 6-epi-6-bromobisnorpenicillinate (3a) and methyl 6-epi-6-bromopenicillinates (6a,b) have been prepared and isolated.     

Antiproton-proton elastic scattering at 6.2 GeV/c

Antiproton-proton elastic scattering data at 6.2 GeV/c in the range 0.3 (GeV/c)² ? ?t ? 10.0 (GeV/c)² is presented. The experiment, using spark chambers and proportional chambers, was performed at the CERN Proton Synchroton.The dip at about ?t = 0.5 and the structure at about ?t = 2.2 (GeV/c)² are equally strong at 6.2 GeV/c as they are at 5.0 GeV/c. The differential cross sections around 90° c.m. are not very different at 5.0 GeV/c and at 6.2 GeV/c, whereas in the backward region there is a decrease of the order of one magnitude.     

Extraction based on the flow-injection principle: Part 4. Determination of Extraction Constants

A new approach to the determination of extraction constants is described. The aqueous and organic phases, the former containing the counter ion, are pumped continuously as small segments through an extraction coil. The sample ion is introduced into the aqueous phase before it enters the coil, where the ion-pair extraction takes place (during 20 s). After leaving the extraction coil, a certain fraction of the organic phase is pumped through the flow-cell of the spectrophotometer. The extraction constants are calculated by slope analysis from the experimental data (absorbance and counter ion concentration). The constants usually agreed within ±0.1 (log units) with values obtained from batch experiments.     

Characterization of a surface state on TiN(001)

A surface state seen in normal photoemission from TiN(001), at - 2.9 eV relative to the Fermi energy, is associated with the Δ₅ band in the bulk band structure consisting of N p_x/p_y orbitals. As TiN is somewhat ionic, there is a change in the electrostatic potential at the surface and this is large enough to pull a Tamm surface state off the Δ₅ band.     

On the critical point of the alkali metals

From an adjustment of the parameters of the Lennard-Jones potential to fit the effective ion-ion interaction in the alkali metals, their critical volume and temperature are calculated.     

Logarithmic diagrams and gran-curves as an aid in potentiometric titrations in complexometry

A detailed exposition is given of the use of logarithmic diagrams and Gran plots to construct titration curves and to determine accurately the equivalence point in potentiometric complexometric titrations.     

Experimental and theoretical studies of positive pion production on 10B and 40Ca by 163–186 MeV protons

The reactions ${}^{10}\text{B(p}\text{,π}{}^{\mathrm{+}}\text{)}{}^{11}\text{B}$ and ${}^{40}\text{Ca(p}\text{,π}{}^{\mathrm{+}}\text{)}{}^{41}\text{Ca}$ have been studied for proton energies between 163 and 186 MeV. Angular distributions for the ground states and the excited state at 2.13 MeV in ¹¹B are presented. Cross sections calculated in the one-nucleon model, under different assumptions about the interaction Hamiltonian as well as the pion and proton optical potentials, are compared with the experimental distribution from the $\text{1}\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}$ state in ⁴¹Ca.     

Rapid electrochemically induced linkage isomerism in a ruthenium(II) polypyridyl complex

Rapid and complete switching between the N6 and the N5O donor set induced by changing the metal oxidation state has been observed for a new structural motif based on a ruthenium(II) polypyridyl complex.