Correlation of soft magnetic properties with free volume and medium range ordering in metallic glasses probed by fluctuation microscopy and positron annihilation technique

Amorphous ribbons of different thicknesses of Co_64.5Fe_3.5Si₁₆B₁₄Ni₂ alloy were synthesized using the melt spinning technique by varying wheel speed. The effect of cooling rate on the ribbon thickness and their soft magnetic properties have been studied. The amorphous structure has been characterized in terms of structural free volume and medium range order (MRO) by positron annihilation spectroscopy and fluctuation electron microscopy techniques. Positron lifetime spectra of amorphous samples showed two lifetime components. The first component was found to be correlated with MRO whereas, the second lifetime component was found to be associated with nanovoid type of defects, and the second component was strongly dependent on processing conditions. It could be established that the coercivity of the amorphous samples produced by the rapid solidification technique mainly depends on the defects formed during processing rather than change induced in MRO.     

Preparation of some nickel(II) and copper(II) complexes of the SCHIFF-Base derived from Acetophenone and Ethylenediamine

Preparation and properties of the following Ni^II and Cu^II complexes of the Schiff base derived from acetophenone and ethylenediamine (BAPE) and also of the mixed Ni^II and Cu^II chelates with BAPE and acetylacetone (acac-H) are described: In each case the Schiff base, BAPE, acts as a neutral bidentate ligand. The complexes are characterised by electronic spectra, magnetic susceptibilities, conductivities and elemental analyses. Pseudotetrahedral structure is proposed for M(BAPE)C1₂, while tetragonal structure for [M(BAPE)(acac)(H₂O)₂]C_lO₄ (M = Ni and Cu). The complex [Ni(BAPE) (acac)]ClO₄ has been found to be square planar.     

Three symbol partially balanced arrays

Summary Two methods of construction of partially balanced arrays of strength two and three are presented.     

Quark masses from qq potentials

Assuming confinement and chiral symmetry breaking, we have calculated constituent quark masses from phenomenological q$\text{q}$ potentials by using a BCS-like gap equation.     

Ultrasonic velocity of binary systems at elevated pressures

Various empirical theories of ultrasonic velocity have been applied to three binary liquid mixtures, under pressures up to 200 MPa and their validity have been tested. A pressure dependent study of ultrasonic velocities has been made at 303.15 K. The agreement between theory and experiment is found to be quite satisfactory.     

Cooperativity in multiple unusual weak bonds

This review covers two aspects concerning cooperativity in multiple weak bonds: a summary of literature results and a theoretical study of a complete series of model complexes. All the 15 combination of five weak bonds were explored: hydrogen bonds, hydric bonds, dihydrogen bonds, halogen bonds and ion–π interactions. Since in several cases there were no examples reported, a systematic exploration has been carried out on simple models at the MP2/aug-cc-pVTZ level. The results thus obtained have been analyzed using the atoms in molecules methodology.     

Theory of Weak Modified Electron Acoustic Double Layers and Solitary Waves in Presence of Negative Ions

We have studied the analytic solutions for modified electron acoustic double layers and solitary waves in a four component plasma system viz. two electrons and two ions, one positive and the other negative. It has been shown that DL solution does not exist when the temperatures of the free and the trapped particles are considered to be same for all the free species. On the other hand, DL solutions are found to exist when the effects of the reflected electrons (hot) are considered. The velocity and thickness of the DL have been valculated.     

MyD88-dependent and independent pathways of Toll-Like Receptors are engaged in biological activity of Triptolide in ligand-stimulated macrophages

Background  

Triptolide is a diterpene triepoxide from the Chinese medicinal plant Tripterygium wilfordii Hook F., with known anti-inflammatory, immunosuppressive and anti-cancer properties.