Synthesis and characterization of phthalazinone‐based poly(aryl ether ketone) derived from 4,4′‐dichlorobenzophenone

As distinguished from the conventional preparation of poly(aryl ether ketone)s utilizing 4,4′‐difluorobenzophenone, a novel synthetic method of high molecular weight poly(phthalazinone ether ketone) derived from 4,4′‐dichlorobenzophenone was studied. Reaction conditions to get high molecular weight polymer were investigated in details. Experimentally, sulfolane was chosen as the reaction media and high molecular weight polymer could be obtained in 7–8 hr at 210°C. The cyclic oligomers in the polymer product reduced to below 3.0% when the concentration of the reactant is 1.6–1.7 g/ml. Fourier transform infrared (FT‐IR), ¹H NMR, and elemental analysis were used to confirm the structure of the obtained polymer. The amorphous polymer showed reasonable solubility in selective solvent, such as chloroform and N‐methyl‐2‐pyrrolidone, and tough, flexible, and transparent thin film can be readily prepared from their N‐methyl‐2‐pyrrolidone solution. The obtained polymer showed high glass transition temperature (T_g) up to 261°C detected by differential scanning calorimetry (DSC), and the temperature of 5% weight loss under nitrogen higher than 500°C detected by thermal gravimetric analysis (TGA), indicating its excellent thermal stability. Copyright © 2011 John Wiley & Sons, Ltd.     

地质灾害预警预报模型设计与应用

基于地质灾害的多样性及其变化的随机性和非稳定性特点,本文综合利用数学算法和GIS技术,设计了地质灾害预警模型,分析了诱发地质灾害的地形、地貌、气象、水文等几方面的因素,并根据这些因素的特点,选取不同的样本对其进行量化处理,运用主成分分析法,计算了各个因素导致地质灾害发生的权重指数及各监测站点的易发级别。在此基础上,基于GIS技术、采用泰森多边形法等将站点的易发级别转换成面的易发级别,运用日降雨量、降雨强度等指标计算出地质灾害发生的概率,通过区域化易发等级图与降雨图的叠加分析,采用地质气象偶合方法,实现了地质灾害预测。在某省案例区的研究表明,本研究设计的地质灾害预警模型具有较高的预警精度(预警结果80%符合实际情况)。     

新型含环己烯结构的甲基二氮杂萘联苯型聚醚酮的合成及表征

合成了一种新型聚合单体 1 甲基 4,5 二 (4 氯代苯甲酰基 )环己烯 ,并与 4 (3 ,5 二甲基 4 羟基苯基 ) 2 ,3 二氮杂萘 1 酮单体经亲核取代反应 ,成功地合成了含环己烯结构的杂环联苯型聚醚酮聚合物 .用FT IR、1H NMR、DSC、X 射线衍射等方法对聚合物进行了表征 ,并研究了聚合物的溶解性能 .结果表明 ,聚合物是一种具有较高的玻璃化温度的可溶性无规共聚物 .聚合物含有不饱和双键结构 ,是一种反应性高分子     

反相高效液相色谱法检测辣椒酱中的苏丹红染料

采用反相高效液相色谱法检测辣椒酱中的苏丹红染料．辣椒酱经正己烷-丙酮溶剂提取,用氧化铝层析柱进行固相萃取净化,用紫外可见光检测器检测,选择ZorbaxSB—C18色谱柱检测苏丹红Ⅰ、苏丹红Ⅱ、苏丹红Ⅲ和苏丹红Ⅳ,加标回收率为91％～95％,测定结果的相对标准偏差为0．89％～1．79％。     

DMF体系中Cu2O球晶的制备及形貌分析

以N,N-二甲基甲酰胺(DMF)为溶剂,通过改变铜源和表面活性剂,调控反应参数,溶剂热条件下制备了三维十字形、空心及实心的Cu₂O球晶。利用XRD、SEM等表征手段,分析探讨了工艺条件变化对Cu₂O球晶形貌的影响。研究表明,随着DMF浓度的增大,体系的还原能力增强,Cu⁺增多,溶液的过饱和度增大,Cu₂O晶体集合体形态由晶体结构控制的各向异性与对称性的球晶逐渐向各向同性球晶演变。十二烷基硫酸钠(SDS)、十六烷基三甲基溴化铵(CTAB)、聚乙烯吡咯烷酮(PVP)等表面活性剂有助于降低溶液的过饱和度,增加结晶质的表面扩散能力,有利于规则形态Cu₂O晶粒的形成。反应体系中,Cu(Ac)₂·H₂O水解生成的羧基与DMF中的甲酰基在高温下发生脱羧反应产生CO₂气体以及SDS发泡作用产生的气体是形成空心Cu₂O球晶的重要原因。     

周期性管柱信道的声波通信技术研究综述

井下声波通信技术利用周期性管柱信道实时传输声波数据,相比于其他通信方式,具有适应性好、复杂度低、传输效率高等优点,在随钻地质导向、油水井监测等方面有广阔的应用前景,是发展智能油田的关键技术之一。本文主要综述上世纪90年代以来关于信道物理模型、信道容量、声信号调制与接收方法等关键问题的研究历程,并对通信系统的设计要点与国内外相关产品的现场应用进行梳理,为后续的技术改进提供依据。     

基于走航观测的长江口邻近海域悬浮颗粒物高频变化研究

基于2018年5月27日—31日长江口邻近海域的海洋科学综合调查，利用船载走航式表观光谱观测系统进行了定点及连续光谱测量，结合快速多参数水质仪和声学多普勒流速剖面仪同步观测结果，研究了悬浮颗粒物(SPM)的高频变化特征及其影响因素。研究结果表明，长江口邻近海域SPM浓度存在高频变化特征，且受潮汐作用影响显著。在退潮周期内，其浓度在定点站位内有明显的先上升后下降过程，且浓度高值与高流速相对应。断面走航观测显示，SPM在短时间内变化特征存在明显的空间差异。在水深较浅的区域中局地再悬浮过程的作用明显，且SPM浓度与流速之间有着良好的对应关系，而在水深较深、离岸较远的区域中SPM浓度的变化则可能与长江冲淡水过程相关。     

MOVPE Growth and Fabrication of 1.3μm High Power InGaAsP-InP Polarization-Insensitive Superluminescent Diodes with Complex Strained Quantum Wells

High power polarization-insensitive InGaAsP-InP multiple quantum well (MQW) superluminescent diodes (SLD's) emitting at 1.3μm were investigated. A combination of tensile strained and compressively strained quantum wells called complex strained MQW were used in a single active layer in order to obtain polarization insensitivity. Low-pressure metalorganic chemical vapor phase epitaxy was used for crystal growth. High resolution X-ray diffraction and photoluminescence spectra showed excellent crystal quality. The SLD's were fabricated to ridge waveguide structure with 7° tilted cavity, the two facets were coated with two layers anti-reflection TiO₂/SiO₂ films, residual facet reflectivity was found to be less than 0.04%. The SLD's exhibited a up to 18.8 mW optical output power and less than 1 dB polarization dependence of output power with a less than 0.5 dB optical spectra modulation at 250 mA.     

超变形转动带的自旋指定与实验测定的比较

按照转动带自旋指定的3种方案,分析了A～190区偶偶核中已测到的超变形带. 对于¹⁹⁴Hg(1)和¹⁹⁴Pb(1),分析给出的自旋指定与实验值完全一致. 有理由认为,其它10条超变形带的自旋指定也是可信的,否则要重新审查现有的转动谱理论,而这些理论对于正常形变核转动带已证明是完全正确的.     

Flexible,high-wettability and thermostable separator based on fluorinated polyimide for lithium-ion battery

To meet the booming demands for lithium-ion battery (LIB), it is practically significant to promote its electrochemical performance and safety. In our work, a novel kind of flexible membrane as separator for LIB is prepared via phase inversion method with soluble polyimide (SPI) containing trifluoromethyl substituent, which is synthesized from 1,4-bis(4-amino-2-trifluoromethylphenoxy)benzene (6FAPB) and 4,4′-oxydiphthalic anhydride (ODPA). The SPI separator shows 5% weight loss temperature (T_d5%) of 535 °C and maintains intrinsic dimension even after heating at 200 °C. The SPI membrane depicts a sponge-like structure with abundant interconnected pores and delivers a dominant porosity (67%). The SPI membrane displays desired electrolyte wettability, validated by contact angle tests (16.2° and 46.8° for SPI membrane and PE separator, respectively) and electrolyte uptake tests (420 and 132% for SPI membrane and PE separator, respectively). The LIB with SPI membrane as separator exhibits nice ionic conductivity (0.92 mS cm^?1) than that with PE separator (0.30 mS cm^?1), and therefore affords better electrochemical performance, such as cycling stability and rate capability.