Simultaneous Determination of Sulfonamides Antibiotics in Environmental Water and Seafood Samples Using Ultrasonic-Assisted Dispersive Liquid-Liquid Microextraction Coupled with High Performance Liquid Chromatography

The residues and abuse of antibiotics have seriously endangered ecological balance and human health; meanwhile, antibiotics determination is very difficult because of their low levels and multiple categories in complicated matrices. Appropriate sample pretreatment is usually imperative to enrich (ultra)trace antibiotics and eliminate matrix interference prior to chromatographic analysis. Dispersive liquid-liquid microextraction (DLLME) has become an ideal pretreatment technique owing to its simplicity, effectiveness, low-consumption, etc. In this work, an ultrasonic-assisted DLLME (UA-DLLME) was developed for the simultaneous extraction of seven sulfonamides (SAs) antibiotics in environmental water and seafood samples coupled with HPLC-DAD determination. Several parameters affecting UA-DLLME efficiency were systematically optimized, and consequently the SAs were separated and detected within 14.5 min. The obtained limits of detection (LODs) and limits of quantification (LOQs) ranged from 0.7–7.8 μg/L and 2.4–26.0 μg/L for three water samples (seawater, aquaculture wastewater and lake water) and two seafood samples (pomfrets and shrimps). High recoveries (80.0–116.0%) with low relative standard deviations (0.1–8.1%) were achieved for all the tested samples at three spiked levels. Notably, sulfadimethoxine was found at 24.49 μg/L in one seawater sample. The facile, robust and benign DLLME-HPLC method demonstrated promising perspectives for multiresidue analysis of antibiotics.     

涡旋提取-石墨炉原子吸收光谱法测定土壤中有效态镉

土壤作为农业生产的重要载体,是保障农产品质量安全的关键源头。近年来,随着经济的快速发展,土壤中重金属污染问题日益凸显,已成为世界性的重大环境问题之一。目前针对土壤中重金属的调查分析大多处于总量水平,这并不能全面地评价重金属的生态风险,因为土壤-重金属-生物体之间存在复杂的动态相互作用,土壤中只有部分重金属能被生物体吸收,这部分能被生物体吸收利用的元素以特定的形态存在,这种特定的形态被称之为有效态。土壤中重金属能否被植物吸收主要取决于该元素的有效态[1],因此土壤中重金属有效态含量的测定,对评价和控制其生物毒害作用具有更实际的意义。镉是生物蓄积性强、具有"三致"作用的剧毒元素,会通过食物链富集到人体,从而对人体健康造成危害[2]。目前我国暂未制定土壤中有效态镉的限量标准,关于土壤中有效态镉含量测定方法的研究也较少[3-5],国家标准方法 GB/T 23739-2009(S)《土壤质量有效态铅和镉的测定原子吸收法》前处理采用振荡器低效提取,提取时间长,试剂用量大,提取液根据含量高低选用火焰原子吸收光谱仪或者石墨炉原子吸收光谱仪,操作较繁琐,无法满足批量样品快速分析的要求。文献[3-4]采用超声提取-电感耦合等离子体质谱法,前处理操作简单,但仪器成本较高,方法应用的推广有一定的局限性,且由于土壤样品基体复杂,容易堵塞雾化器导致仪器故障。     

平面区域拟共形变换可微性的可去集

本文研究平面区域上K-qc映射的不可微集合的Hausdorff维数.对任何K＞1,给出了平面区域上一个具体的K-qc映射,它的不可微集合的Hausdorff维数为2.     

EXISTENCE AND ATTRACTIVITY OF ALMOST PERIODIC SOLUTION FOR SHUNTING INHIBITORY CELLULAR NEURAL NETWORKS WITH CONTINUOUSLY DISTRIBUTED DELAYS AND VARIABLE COEFFICIENTS

In this paper, a class of two-dimensional shunting inhibitory cellular neural networks with distributed delays and variable coefficients system is studied. By using the Schauder's fixed point theorem and Lyapunov function, we obtain some sufficient conditions about the existence and attractivity of almost periodic solutions to the above system, and all its solutions converge to such almost periodic solution. An example is given to illustrate that the conditions of our results are feasible.     

新重丰中子同位素239Pa

用50MeV/u ¹⁸O离子同天然铀靶反应产生了新重丰中子同位素²³⁹Pa.用放射化学法从反应产物中分离Pa活性,通过观测²³⁹Pa及子体²³⁹U衰变所得到的结果显示:首次合成和鉴别了新重丰中子核素²³⁹Pa,并测定出²³⁹Pa的半衰期为106±30min.     

Newton's method for sections on Riemannian manifolds: Generalized covariant -theory

One kind of the L-average Lipschitz condition is introduced to covariant derivatives of sections on Riemannian manifolds. A convergence criterion of Newton's method and the radii of the uniqueness balls of the singular points for sections on Riemannian manifolds, which is independent of the curvatures, are established under the assumption that the covariant derivatives of the sections satisfy this kind of the L-average Lipschitz condition. Some applications to special cases including Kantorovich's condition and the γ-condition as well as Smale's α-theory are provided. In particular, the result due to Ferreira and Svaiter [Kantorovich's Theorem on Newton's method in Riemannian manifolds, J. Complexity 18 (2002) 304–329] is extended while the results due to Dedieu Priouret, Malajovich [Newton's method on Riemannian manifolds: covariant alpha theory, IMA J. Numer. Anal. 23 (2003) 395–419] are improved significantly. Moreover, the corresponding results due to Alvarez, Bolter, Munier [A unifying local convergence result for Newton's method in Riemannian manifolds, Found. Comput. Math. to appear] for vector fields and mappings on Riemannian manifolds are also extended.