This work demonstrates that liquid phase deposition (LPD) technique provides a novel approach to the immobilization of hemoglobin (Hb) in TiO(2) film for studying the direct electron transfer of Hb. Using the LPD process, a hybrid film composed of Hb, TiO(2) and sodium dodecylsulfonate (SDS) is successfully prepared on the electrode surface. The surface morphology of as-deposited Hb/SDS/TiO(2) film shows a flower-like structure. The cyclic voltammetric measurement indicates that the LPD hybrid film facilitates the electron transfer of Hb, which yields a pair of redox peaks prior to the characteristic voltammetric peaks of TiO(2). Due to the electrocatalytic activity of Hb towards H(2)O(2), the Hb/SDS/TiO(2) hybrid LPD film can be utilized as an H(2)O(2) sensor, showing a sensitive response linearly proportional to the concentration of H(2)O(2) in the range of 5.0×10(-7)-4.0×10(-5) mol/L. At the same time, the Hb/SDS/TiO(2) hybrid film preserves the photoelectrochemical activity of TiO(2). The photovoltaic effect on the electrochemical behavior of Hb/SDS/TiO(2) film is observed after long-time UV irradiation on the film, which could improve the calibration sensitivity for H(2)O(2). 相似文献
A nitrogen-rich segment in a fulvic acid (FA) from Pony Lake, a coastal pond in Antarctica, was investigated by (15)N and (13)C{(14)N} solid-state NMR techniques. As reported previously, the (13)C{(14)N} spectrum of C bonded to N exhibits a peak at 157 ppm that is assigned to an sp(2)-hybridized carbon bonded to at least two nitrogen atoms. This segment contains 48% of all N in the sample. (15)N NMR shows distinct signals, 20 ppm upfield and downfield from the typical peptide resonance; dipolar dephasing confirmed that they are due to protonated N. The well-resolved downfield peak, which accounts for 1/4 of the spectral area, cannot be assigned to aromatic heterocycles, such as purines, because the fraction of aromatic C bonded to N in this sample is very small. Analysis of (15)N chemical-shift trends and (15)N NMR of model compounds, such as arginine and its derivatives, excludes assignment to a guanidinium ion or to substituted guanidino groups. Similarly, ureido groups, -NH-CO-NH-, that are not bonded to a second C = O do not match the observed (15)N peaks in the FA, since both N resonate upfield from the peptide resonance. On the other hand, all chemical shifts are matched within the observed range by the -C(alkyl)-NH-CO-NH-CO-C structure found in two nonaromatic heterocycles, hydantoin and dihydrouracil. The five-membered hydantoin ring, which is found in the purine metabolite allantoin, provides a better match than the six-membered dihydrouracil ring. Regular uracil or thymine fails to produce adequate agreement with observed chemical shifts. 相似文献
The Co-modified CeO2-TiO2 catalyst prepared by facile co-precipitation was used for efficient elemental mercury oxidation in flue gas. Results indicated that Co doping greatly enhanced the activity and SO2 resistance of the CeO2-TiO2 catalyst. In the presence of 5% O2, 500 ppm NO, 800 ppm SO2 and 3% H2O at 200 °C, the Hg0 removal efficiency of CeCo3/Ti could maintain at about 87% for a relatively long time. Characterizations of catalysts (BET, XRD, Raman spectroscopy, TEM, H2-TPR, O2-TPD, XPS, TG-MS and SO2-DRIFTS) were carried out to reveal the mechanism of Co modification on the redox ability, SO2 resistance and resultant mercury oxidation removal performance of catalyst. It was found that an interaction of Ce with Co promoted the dispersion of CeO2, increased chemisorbed oxygen concentration, and improved the oxygen storage capacity and the reducibility of catalyst, which was beneficial to the improvement of Hg0 oxidation removal. Hg0 would adsorb onto the catalyst and react with surface active oxygen species replenished by gas-phase O2 to be oxidized via Mars-Maessen mechanism. SO2 consumed the surface active oxygen species and resulted in the reduction of Ce4+ to Ce3+, which induced the deactivation of catalyst. The introduced Co in CeO2-TiO2 catalyst exerted the function of protecting Ce4+ from being poisoned by SO2 and thus promoted the sulfur resistance and Hg0 removal performance of the catalyst in the presence of SO2. 相似文献
Summary: A novel crosslinkable dendritic polymer has been synthesized by the thermal polymerization of peripheral aryl trifluorovinyl ether moieties of a highly fluorinated dendrimer. The resulting perfluorocyclobutane(PFCB)‐containing dendritic polymer exhibited excellent processability, low optical loss (0.36 dB · cm−1 at 1 310 nm with 1% dye doping), high thermal stability, and good solvent resistance for waveguide‐based photonic applications.
Structure of the crosslinkable fluorinated dendrimer synthesized. 相似文献
We present an integral-closed algorithm for solving a Langevin equation driven by an additive colored noise. Both the mean first passage time in a bistable system and the diffusion current in a titled periodic potential are calculated and the comparison with existing algorithms is carried out. The dependence of the numerical results on the time steps is studied. Our algorithm is shown to have high accuracy and stability. 相似文献
ABSTRACTIn this paper, we establish the asymptotic boundary of traveling waves (first-component) in a discrete diffusive epidemic model, whose existence is well-known. Meanwhile, we derive the nonexistence of traveling wave solutions with non-positive wave speed. We solve two open problems left in two papers [Fu et al., Nonlinear Convex A. 17 (2016), pp. 1739–1751; Wu, J. Differential Equations 262 (2017), pp. 272–282]. 相似文献