Intermolecular Charge-Transfer Interactions Facilitate Two-Photon Absorption in Styrylpyridine–Tetracyanobenzene Cocrystals

Cocrystals of 4-styrylpyridine and 1,2,4,5-tetracyanobenzene were successfully prepared by supramolecular self-assembly. Donor–acceptor interactions between the molecular components are the main driving force for self-assembly and contribute to intermolecular charge transfer. The cocrystals possess two-photon absorption properties that are not observed in the individual components; suggesting that two-photon absorption originates from intermolecular charge-transfer interactions in the donor–acceptor system. The origin of two-photon absorption in multichromophore systems remains under-researched; thus, the system offers a rare demonstration of two-photon absorption by cocrystallization. Cocrystal engineering may facilitate further design and development of novel materials for nonlinear optical and optoelectronic applications.     

On the Role of Alkali-Metal-Like Superatom Al12P in Reduction and Conversion of Carbon Dioxide

Developing efficient catalysts for the conversion of CO₂ into fuels and value-added chemicals is of great significance to relieve the growing energy crisis and global warming. With the assistance of DFT calculations, it was found that, different from Al₁₂X (X=Be, Al, and C), the alkali-metal-like superatom Al₁₂P prefers to combine with CO₂ via a bidentate double oxygen coordination, yielding a stable Al₁₂P(η²-O₂C) complex containing an activated radical anion of CO₂ (i.e., CO₂^.−). Thereby, this compound could not only participate in the subsequent cycloaddition reaction with propylene oxide but also initiate the radical reaction with hydrogen gas to form high-value chemicals, revealing that Al₁₂P can play an important role in catalyzing these conversion reactions. Considering that Al₁₂P has been produced in laboratory and is capable of absorbing visible light to drive the activation and transformation of CO₂, it is anticipated that this work could guide the discovery of additional superatom catalysts for CO₂ transformation and open up a new research field of superatom catalysis.     

Novel voltage signal at proximity-induced superconducting transition temperature in gold nanowires

We observed a novel voltage peak in the proximity-induced superconducting gold (Au) nanowire while cooling the sample through the superconducting transition temperature. The voltage peak turned dip during warming. The voltage peak or dip was found to originate respectively from the emergence or vanishing of the proximity-induced superconductivity in the Au nanowire. The amplitude of the voltage signal depends on the temperature scanning rate, and it cannot be detected when the temperature is changed slower than 0.03 K/min. This transient feature suggests the non-equilibrium property of the effect. Ginzburg-Landau model clarified the voltage peak by considering the emergence of Cooper pairs of relatively lower free energy in superconducting W contact and the non-equilibrium diffusion of Cooper pairs and quasiparticles.     

A study on the evaluation of cesium removal performance in soil washing process using flocculating agent

Journal of Radioanalytical and Nuclear Chemistry - As a result of nuclear power plant accidents such as Chernobyl and Fukushima, and even their maintenance, the soil is contaminated due to the...     

A novel Pt/C‐catalyzed transfer hydrogenation reaction of p‐benzoquinone to produce p‐hydroquinone using cyclohexanone as an unexpectedly effective hydrogen source

A new method for the production of p‐hydroquinone via a Pt/C‐catalyzed reduction of p‐benzoquinone is developed. Different from the conventional transfer hydrogenation reactions that usually use secondary alcohols such as isopropanol as the hydrogen source, in this work, it is unexpectedly found that cyclohexanone is a more effective hydrogen source than secondary alcohols, even cyclohexanol. This reaction affords acceptable yields of p‐hydroquinone with very high turnover number (1109) of the Pt/C catalyst. A mechanism of this interesting reaction is proposed on the basis of the results of a series of control experiments, GC–MS analysis as well as dynamic studies.     

Optical,electrical, and thermal insulation properties of antimony-doped tin oxide nanoparticles prepared by frozen gel method

Antimony doped tin dioxide (ATO) nanoparticles with different Sb doping contents were prepared by freeze-drying the precursor gel and then calcined procedure. The obtained ATO nanoparticles were characterized by X-ray diffraction, scanning electron microscope, optical and electrical techniques. Results indicated that ATO with 10 mol% Sb doping is optimal, with which had the lowest resistivity and highest transmittance in visible region as well as narrow particle size distribution. Thermal insulation properties of ATO/waterborne polyurethane (WPU) films coating on the glass substrates with different thickness were studied on a DIY heat insulating measurement box and showed that the glass coated with ATO/WPU films possessed better heat-insulating effect than empty glass .     

Lattice Classification by Cut-through Coding

Inspired by engineering of high-speed switching with quality of service, this paper introduces a new approach to classify finite lattices by the concept of cut-through coding. An n-ary cut-through code of a finite lattice encodes all lattice elements by distinct n-ary strings of a uniform length such that for all j, the initial j encoding symbols of any two elements x and y determine the initial j encoding symbols of the meet and join of x and y. In terms of lattice congruences, some basic criteria are derived to characterize the n-ary cut-through codability of a finite lattice. N-ary cut-through codability also gives rise to a new classification of lattice varieties and in particular, defines a chain of ideals in the lattice of lattice varieties.     

The first chlorogenic acid ester saponin from <Emphasis Type="Italic">Lonicera macranthoides</Emphasis>

An original triterpenoid saponin, named lonimacranthoide I, was isolated from the flower buds of Lonicera macranthoides (Caprifoliaceae). It has hederagenin as aglycone. Lonimacranthoide I is a rare chlorogenic acid ester acylated at C-23 of hederagenin. The structure of the saponin was established based on chemical and spectral methods.     

Synthesis of 2-aminooxazolines from isonitriles and iodine

A novel one-pot protocol for the synthesis of substituted 2-aminooxazoline from isonitriles and 2-aminoethanol was developed and the reactions involved imidoyl diiodide intermediates,which were generated by mixing isonitriles and iodine in CH₂C1₂ at room temperature.