全文获取类型
收费全文 | 10841篇 |
免费 | 1592篇 |
国内免费 | 1264篇 |
专业分类
化学 | 7652篇 |
晶体学 | 149篇 |
力学 | 693篇 |
综合类 | 87篇 |
数学 | 1324篇 |
物理学 | 3792篇 |
出版年
2024年 | 44篇 |
2023年 | 254篇 |
2022年 | 367篇 |
2021年 | 389篇 |
2020年 | 427篇 |
2019年 | 465篇 |
2018年 | 398篇 |
2017年 | 394篇 |
2016年 | 528篇 |
2015年 | 534篇 |
2014年 | 591篇 |
2013年 | 811篇 |
2012年 | 902篇 |
2011年 | 970篇 |
2010年 | 687篇 |
2009年 | 613篇 |
2008年 | 756篇 |
2007年 | 626篇 |
2006年 | 568篇 |
2005年 | 416篇 |
2004年 | 378篇 |
2003年 | 279篇 |
2002年 | 311篇 |
2001年 | 212篇 |
2000年 | 204篇 |
1999年 | 258篇 |
1998年 | 182篇 |
1997年 | 131篇 |
1996年 | 141篇 |
1995年 | 133篇 |
1994年 | 99篇 |
1993年 | 108篇 |
1992年 | 89篇 |
1991年 | 86篇 |
1990年 | 77篇 |
1989年 | 58篇 |
1988年 | 42篇 |
1987年 | 36篇 |
1986年 | 21篇 |
1985年 | 33篇 |
1984年 | 21篇 |
1983年 | 14篇 |
1982年 | 12篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1978年 | 5篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1957年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
911.
In this paper we generalize gradient estimates in Lp space to Orlicz space for weak solutions of elliptic equations of p-Laplacian type with small BMO coefficients in δ-Reifenberg flat domains. Our results improve the known results for such equations using a harmonic analysis-free technique. 相似文献
912.
Yuru Zou Yuanyuan Yao Wenxia Li 《Journal of Mathematical Analysis and Applications》2008,340(2):1422-1432
Based on a scheme by Lau and Ngai, a sufficient and necessary condition for an IFS of contractive similitudes to satisfy the open set condition is given. A class of Sierpinski carpets with parameters (λ1,λ2) is then investigated. 相似文献
913.
Yi-Ching Yao 《Annals of the Institute of Statistical Mathematics》1987,39(1):377-383
Summary The problem of testing for constant hazard against a change-point alternative is considered. It is shown that this problem
is related to another one in quality control. Based on this relationship, a test is proposed. The main advantages of this
test are its computational simplicity and the ready availability of small and large sample distribution theory. 相似文献
914.
The variation of macroporous morphology has been studied for the titania (TIO2) films prepared by a sol-gel dip-coating method from the system containing poly(ethylene glycol) (PEG) under the addition of various types of organic solvents. The influence of externally-added solvent is interpreted by considering the compatibility between PEG and the solvent mixture, the volatility of the solvent mixture, and the polycondensation rate of titania oligomers. The macroscopic domain formation is remarkable when the compatibility between the solvent mixture and PEG is relatively poor and the boiling point of external solvent is relatively low. 相似文献
915.
916.
Guoping Yao Huaiyuan Zhang Chunhui Deng Haojie Lu Xiangmin Zhang Pengyuan Yang 《Rapid communications in mass spectrometry : RCM》2009,23(22):3493-3500
In the work, 4‐mercaptophenylboronic acid (4‐MPBA)‐functionalized gold nanoparticles were synthesized via a facile approach. At first, gold nanoparticles (about 50 nm) were prepared by a simple and convenient hydrothermal method based on a polyol process. Then, gold nanoparticles were modified with 4‐MPBA by the well‐known reaction of Au with the thiol groups. The MPBA‐functionalized gold nanoparticles were characterized by Fourier transform infrared spectra and UV/Vis adsorption spectra. Due to the fact that the boronic acid group on the surface of 4‐MPBA‐modified gold particles can form tight yet reversible covalent bonds with glycopeptides containing cis‐1,2‐diols groups, the MPBA‐modified gold nanoparticles were successfully applied to selective enrichment of glycopeptides. Isolation and enrichment of glycopeptides in a standard protein (asialofetuin and horseradish peroxidase) digestion and a complex sample were performed using MPBA‐modified gold nanoparticles, followed by matrix‐assisted laser desorption/ionization quadruple ion trap time‐of‐flight (MALDI‐QIT‐TOF) mass spectrometric analysis. The experimental results demonstrated that MPBA‐modified gold nanoparticles synthesized by the facile approach have the powerful potential for selective enrichment of glyciopeptides, and can be an alternative tool in glycoproteomics. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
917.
918.
919.
Yao Chen Panpan Sun Tiancheng Li Yin Zou Yiyong Huang Yongcun Shen 《Tetrahedron letters》2018,59(25):2399-2402
Asymmetric Michael addition between 3-ethyl carboxylate substituted pyrazolones and 5-alkenylthiazolones catalyzed by a series of chiral bifunctional hydrogen bonding organocatalysts was investigated. Good yields (up to 96%) and excellent enantioselectivities (up to 99% ee) were achieved by using a squaramide containing piperidine group derived from (1S, 2S)-cyclohexanediamine. This strategy provides facile access to a diverse library of thiazole-pyrazolone derivatives with potential bioactivity. 相似文献
920.
Dr. Guanzhao Wu Yangxue Liu Hossein Rouh Liulei Ma Yao Tang Sai Zhang Peng Zhou Jia-Ying Wang Shengzhou Jin Dr. Daniel Unruh Dr. Kazimierz Surowiec Prof. Dr. Yanzhang Ma Prof. Dr. Guigen Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(30):8013-8020
The first asymmetric catalytic approach to multilayer 3D chirality has been achieved by using Suzuki-Miyaura cross-couplings. New chiral catalysts were designed and screened under various catalytic systems that proved chiral amide-phosphines to be more efficient ligands than other candidates. The multilayer 3D framework was unambiguously determined by X-ray structural analysis showing a parallel pattern of three layers consisting of top, middle and bottom aromatic rings. The X-ray structure of a catalyst complex, dichloride complex of Pd-phosphine amide, was obtained revealing an interesting asymmetric environment nearby the Pd metal center. Three rings of multilayer 3D products can be readily changed by varying aromatic ring-anchored starting materials. The resulting multilayer products displayed strong luminescence under UV irradiation and strong aggregation-induced emission (AIE). In the future, this work would benefit not only the field of asymmetric synthesis but also materials science, in particular polarized organic electronics, optoelectronics and photovoltaics. 相似文献