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排序方式: 共有1182条查询结果,搜索用时 15 毫秒
91.
Tsai WH Chuang HY Chen HH Wu YW Cheng SH Huang TC 《Journal of chromatography. A》2010,1217(49):7812-7815
A simple sugaring-out assisted liquid-liquid extraction method combined with high-performance liquid-chromatography with fluorescence detection (HPLC-FL) was developed for the extraction and determination of sulfonamides in honey. Sample preparation consisted of acid hydrolysis to release sugar-bound sulfonamides. After derivatization with fluorescamine, the derivatives were partitioned into the organic layer under the honey (sugar)/water/acetonitrile system. The clear organic extract obtained by centrifugation could be injected into the HPLC system either directly or after dilution. Linearity was obtained with the coefficient of determination (R(2)) higher than 0.998 from 2 to 200 ng/mL. Under the optimal conditions, recoveries were determined for honey fortified at three levels (5, 20, and 100 ng/g) were 80.9-99.6% with coefficients of variation of 0.3-4.4%. Limits of detection for the sulfonamides studied were found to range from 0.6 to 0.9 ng/g. 相似文献
92.
Existing atomistic simulation techniques to study grain boundary motion are usually limited to either high velocities or temperatures and are difficult to compare to realistic experimental conditions. Here we introduce an adapted simulation method that can access boundary velocities in the experimental range and extract mobilities in the zero driving force limit at temperatures as low as ~0.2T(m) (T(m) is the melting point). The method reveals three mechanistic regimes of boundary mobility at zero net velocity depending on the system temperature. 相似文献
93.
94.
Volume polarization holographic recording in phenanthrenequinone-doped poly (methyl methacrylate) photopolymer is obtained. Photoinduced birefringence in a 2 mm thick sample is measured by a phase-modulated ellipsometry. The birefringence induced in this material by linearly polarized beam at 514 nm reaches 1.2×10(-5). In addition, ability for recording volume polarization grating using two different polarization configurations is demonstrated and compared. The experimental results show that the diffraction efficiency of the hologram reaches to ~40% by using two orthogonal circularly polarized beams. 相似文献
95.
In this paper, we consider a generalized model of the two friction models, both of which have two different types of control forces with time-delayed feedback proposed by Ashesh Sara et al. By taking the time delay as the bifurcation parameter, we discuss the local stability of the Hopf bifurcations. Under some condition, the generalized model harbors a phenomenon that the equilibrium may undergo finite switches from stability to instability to stability and finally become unstable. By applying the method introduced by Faria and Magalhaes, we compute the normal form on the center manifold to determine the direction and stability of the Hopf bifurcations. Numerical simulations are carried out and more than one periodic solutions may exist according to the bifurcation diagram given by BIFTOOL. Finally a brief conclusion is presented. 相似文献
96.
Trade credit financing plays a vital role in current business operations. Vendors extend payment dates to encourage sales, and buyers are not required to pay immediately after receiving products. This is equivalent to receiving a price reduction. Besides, buyers reduce their need for capital from bank loans. In addition, a number of defective products are produced during the production process. The number of defective items influences the on-hand inventory levels of buyers, service levels, and frequency of orders. To ensure that the analysis incorporates a realistic production environment, we developed an integrated inventory model with a two-part trade credit and considered an imperfect production process that can be improved by capital investment. The objective was to determine the optimal ordering, shipping, and quality improvement policies to maximize joint total profit. An iterative algorithm was established to determine the optimal strategy. Furthermore, a sensitivity analysis was conducted to examine the effects of changing parameter values on the optimal solution. 相似文献
97.
A novel variable-sized block encoding with threshold control for colour image quantization (CIQ) is presented in this paper.
In CIQ, the colour palette used has a great influence on the reconstructed image quality. Typically, a higher image quality
and a larger storage cost are obtained when a larger-sized palette is used in CIQ. To cut down the storage cost while preserving
quality of the reconstructed images, the threshold control policy for quadtree segmentation is used in this paper. Experimental
results show that the proposed method adaptively provides desired bit rates while having better image qualities comparing
to CIQ with the usage of multiple palettes of different sizes. 相似文献
98.
Yu‐Liang Yang Dr. Wen‐Ying Liao Wan‐Yun Liu Chih‐Chuang Liaw Dr. Chia‐Ning Shen Dr. Zih‐You Huang Shih‐Hsiung Wu Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(43):11573-11580
Six photosensitive polyketides, malbranpyrroles A–F, were discovered from the thermophilic fungus Malbranchea sulfurea by using intact‐cell desorption/ionization on silicon mass (ICD‐MS) and LC‐SPE‐NMR. These two strategies facilitate the searching and structural determination of unstable natural products. The ICD‐MS indicated that only brown hyphae of M. sulfurea can produce malbranpyrroles. The biosynthetic pathway of malbranpyrroles was evidenced by 13C isotope precursors and amino acid feeding experiments. The cytotoxicity data revealed that the conformation of the conjugated system in malbranpyrroles does not affect cytotoxic potency against cancer cell lines. In addition, the chlorine atom was shown to be the pharmacophore for cytotoxicity. 相似文献
99.
M. C. Nuss P. C. M. Planken I. Brener H. G. Roskos M. S. C. Luo S. L. Chuang 《Applied physics. B, Lasers and optics》1994,58(3):249-259
The observation of terahertz electromagnetic dipole radiation from quantum well structures has finally proven the existence of charge oscillations in semiconductors associated with wave packet dynamics. This article closely examines the physics behind the emission of terahertz electromagnetic radiation from excitonic charge oscillations in such quantum well structures, points out similarities and differences between the various generation schemes, and discusses the various relaxation mechanisms involved. Finally, we show how both amplitude and phase of charge oscillations and the corresponding terahertz emission can be manipulated using phase-locked optical pulses. 相似文献
100.
Steve Lien‐Chung Hsu Guo‐Wei Luo Hui‐Tzu Chen Shih‐Wei Chuang 《Journal of polymer science. Part A, Polymer chemistry》2005,43(23):6020-6027
New poly(imide–benzoxazole) copolymers were prepared directly from a dianhydride, a diacid chloride, and a bis(o‐diaminophenol) monomer in a two‐step method. In the first step, poly(amic acid–hydroxyamide) precursors were synthesized by low‐temperature solution polymerization in an organic solvent. Subsequently, the thermal cyclodehydration of the poly(amic acid–hydroxyamide) precursors at 350 °C produced the corresponding poly(imide–benzoxazole) copolymers. The inherent viscosities of the precursor polymers were around 0.19–0.33 dL/g. The cyclized poly(imide–benzoxazole) copolymers had glass‐transition temperatures in the range of 331–377 °C. The 5% weight loss temperatures ranged from 524 to 535 °C in nitrogen and from 500 to 514 °C in air. The poly(imide–benzoxazole) copolymers were amorphous, as evidenced by the wide‐angle X‐ray diffraction measurements. The structures of the precursor copolymers and the fully cyclized copolymers were characterized by Fourier transform infrared, 1H NMR, and elemental analysis. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 6020–6027, 2005 相似文献