Synthesis and structural characterisation of [(Ph3P)AuCo(CO)3(PPh3)]

Summary [(Ph₃P)AuCo(CO)₃(PPh₃)] has been synthesised from [(Ph₃P)AuCo(CO)₄], PPh₃v and Me₃NO in acetonitrile. Its molecular structure, determined by single-crystal x-ray crystallography, consists of an almost linear P-Au-Co-P arrangement in which the Co atom is in a slightly distorted trigonalbipyramidal geometry, with the Au and P atoms occupying the apical sites. The Au-Co bond length of 2.450(1) ? is shorter than that reported for [(Ph₃P)AuCo(CO)₄]. The carbonyl ligands are bent towards the Au atom and the mean Au-Co-C angle is 81(1)°.     

Preparation of polysiloxane stationary phases for capillary column chromatography: A New methoxyphenyl phase

Contemporary methods for the synthesis of alkyl- and arylsubstituted polysiloxane stationary phases are reviewed. A new, moderately polar phase containing the 3-(4-methoxyphenyl)-propyl group is reported.     

Photochemical reactions of Ru3(CO)12 involving metalmetal bond fission

Photolysis of Ru₃(CO)₁₂ in the presence of donor ligands rapidly produces monomeric ruthenium species.     

An integrated microfluidic device for influenza and other genetic analyses

An integrated microfluidic device capable of performing a variety of genetic assays has been developed as a step towards building systems for widespread dissemination. The device integrates fluidic and thermal components such as heaters, temperature sensors, and addressable valves to control two nanoliter reactors in series followed by an electrophoretic separation. This combination of components is suitable for a variety of genetic analyses. As an example, we have successfully identified sequence-specific hemagglutinin A subtype for the A/LA/1/87 strain of influenza virus. The device uses a compact design and mass production technologies, making it an attractive platform for a variety of widely disseminated applications.     

Singular measures without restrictive intervals

For the transformationT:[0,1][0,1] defined byT(x)=x(1–x) with 04, a is shown to exist for whichT has no restrictive intervals, hence is sensitive to initial conditions, but for which no finite absolutely continuous invariant measure exists forT.Supported by the U.S. Army Research Office through the Mathematical Sciences Institute of Cornell University