生物媒质组分定征中声速混合定则的比较

本文分析研究了各种声速混合定则的异同,以及这些定则在预言生物媒质组分含量时的有效性.分析计算表明,各种声速定则对实际生物媒质声速的模拟符合程度有所差异,在一定条件下这些定则是兼容的;尚没有能完整描述生物媒质声速特征的统一的、最佳模拟定则。     

四角晶相HfO2(001)表面原子和电子结构研究

采用基于第一性原理的密度泛函理论研究了四角晶相二氧化铪(t-HfO₂)体相及 其(001)表面的原子几何与电子结构.理论计算结果表明，t-HfO₂(001)表面不会 产生重构现象.与体相电子结构相比, t-HfO₂(001)表面态密度明显高于体相态 密度.其次，表面原子的态密度更靠近费米能级(E_F)，价带往低能量处移动，并 有表面态产生.计算结果表明了t-HfO₂表面禁带宽度明显低于体相的禁带宽度. t-HfO₂(001)的表面态产生以及表面禁带宽度减小是由于Hf原子与O原子的配位 数减少，表面原子周围的环境发生变化而引起的. 关键词： 密度泛函理论 2(001)')" href="#">t-HfO₂(001) 表面电子结构     

甲醇在γ-Al2O3,CeO2及其负载Pd催化剂上吸附和分解的原位红外光谱研究

利用原位傅里叶变换红外光谱 (FTIR)技术对甲醇在γ Al2 O3,CeO2 以及Pd/Al2 O3,Pd/CeO2 催化剂上的吸附和分解行为进行了研究。综合考虑了载体和活性组分的作用 ,分析了甲醇在不同载体负载Pd催化剂上可能的分解途径。在Pd/CeO2 催化剂上 ,活性组分和载体对甲醇分解的过程表现出了一种协同效应。     

氨吸收式串联型动力/制冷复合循环

本文提出了一种新型的采用氨水混合工质的动力／制冷复合循环,该循环以中低温工业余热或燃气轮机排气为热源,将动力、制冷子循环采用串联方式连接,基础循环工质为氨质量浓度为0．27的氨水溶液,热源为365℃／104．3 kPa 的热空气,透平进气参数为350℃／3750 kPa,,以热效率η1、(火用)效率η2作为评价准则,模拟计算表明本循环的热效率η1 为17．8％,炯效率η2为45％,通过与其它有代表性的分供系统及联供系统进行热力性能方面的比较,表明本循环η1、η2均有不同程度提高。     

基于PXI总线的阵列探测器数据获取系统

描述了一种适用于阵列探测器的数据获取系统。系统基于PXI总线, 采用标准NIM插件作为前端电子学。系统软件采用C/C++语言编写, 在线分析通过调用ROOT类库实现, 系统运行在Linux操作系统下。多次测试结果表明, 系统稳定可靠, 单个ADC通道可以处理的最大事例率为40 kHz。A data acquisition system for array detectors is described. The system is based on PXI bus with standard NIM modules used as front\|end electronics. The system software is written in C/C++ language with its online analysis modules realized by ROOT class library. Several runs of the system under Linux show that it is reliable and is capable of handling event rates up to 40 k events/s for 1 ADC channel.     

PS_(3000)-b-PAA_(5000)球形胶束温度效应的原位小角X射线散射技术研究

应用小角X射线散射技术(SAXS)对两亲嵌段共聚物聚苯乙烯聚丙烯酸(PS-b-PAA)胶束形貌的温度影响进行了原位表征.SAXS结果表明:随着水含量的增加,粒子尺寸相应增加;对于水含量10%的PS_(3000)-b-PAA_(5000)胶束溶液,发现了明显的SAXS双峰现象;双峰的位置不随着温度的变化而改变,但是peak 1和peak 2的相对强度随着温度发生了减弱和增强的交错变化;相邻的SAXS双峰说明在PS_(3000)-b-PAA_(5000)胶束溶液中最初形成的粒子尺寸并不是均匀的,主要分为尺寸极其相近的两种球形粒子;随着温度的升高,粒径大小不同的两种粒子存在着一种消融和生长的过程,并且保持着一个相同的归一化动态平衡速率.     

A novel hyperchaotic system and its circuit implementation

A four-dimensional hyperchaotic system with five parameters is proposed. Its dynamical properties such as dissipativity, equilibrium points, Lyapunov exponent, Lyapunov dimension, bifurcation diagrams and Poincare maps are analyzed theoretically and numerically. Theoretical analyses and simulation tests indicate that the new system's dynamics behavior can be periodic attractor, chaotic attractor and hyperchaotic attractor as the parameter varies. Finally, the circuit of this new hyperchaotic system is designed and realized by Multisim software. The simulation results confirm that the chaotic system is different from the existing chaotic systems and is a novel hyperchaotic system. The system is recommendable for many engineering applications such as information processing, cryptology, secure communications, etc.     

火焰原子吸收光谱法测定马氏珠母贝与企鹅珍珠贝中的重金属镉

通过HNO3-HClO4混合酸消解样品,采用火焰原子吸收光谱法测定马氏珠母贝与企鹅珍珠贝中镉的含量.在最佳试验条件下,线性范围为0.05-1.00μg/mL,相关系数r=0.9998,检出限为0.00686μg/mL,测定结果的相对标准偏差均小于3％(n=6),加标回收率结果在96.77％-103.89％之间.该方法简便、快速,灵敏度高,准确性好,结果令人满意.     

A double toroidal analyzer for scanning probe electron energy spectrometer

An ultra-high vacuum(UHV) compatible electron spectrometer employing a double toroidal analyzer has been developed. It is designed to be combined with a custom-made scanning tunneling microscope(STM) to study the spatially localized electron energy spectrum on a surface. A tip–sample system composed of a piezo-driven field-emission tungsten tip and a sample of highly ordered pyrolytic graphite(HOPG) is employed to test the performance of the spectrometer.Two-dimensional images of the energy-resolved and angle-dispersed electrons backscattered from the surface of HOPG are obtained, the performance is optimized and the spectrometer is calibrated. A complete electron energy loss spectrum covering the elastic peak to the secondary electron peaks for the HOPG surface, acquired at a tip voltage of-140 V and a sample current of 0.5 pA, is presented, demonstrating the viability of the spectrometer.