全文获取类型
收费全文 | 19723篇 |
免费 | 3910篇 |
国内免费 | 3278篇 |
专业分类
化学 | 15027篇 |
晶体学 | 360篇 |
力学 | 1118篇 |
综合类 | 293篇 |
数学 | 2149篇 |
物理学 | 7964篇 |
出版年
2024年 | 75篇 |
2023年 | 482篇 |
2022年 | 863篇 |
2021年 | 924篇 |
2020年 | 1004篇 |
2019年 | 979篇 |
2018年 | 823篇 |
2017年 | 848篇 |
2016年 | 1090篇 |
2015年 | 1133篇 |
2014年 | 1318篇 |
2013年 | 1682篇 |
2012年 | 1888篇 |
2011年 | 1849篇 |
2010年 | 1417篇 |
2009年 | 1339篇 |
2008年 | 1403篇 |
2007年 | 1224篇 |
2006年 | 1112篇 |
2005年 | 931篇 |
2004年 | 724篇 |
2003年 | 577篇 |
2002年 | 529篇 |
2001年 | 458篇 |
2000年 | 336篇 |
1999年 | 326篇 |
1998年 | 274篇 |
1997年 | 213篇 |
1996年 | 190篇 |
1995年 | 161篇 |
1994年 | 134篇 |
1993年 | 103篇 |
1992年 | 84篇 |
1991年 | 90篇 |
1990年 | 83篇 |
1989年 | 60篇 |
1988年 | 40篇 |
1987年 | 28篇 |
1986年 | 31篇 |
1985年 | 25篇 |
1984年 | 5篇 |
1983年 | 9篇 |
1982年 | 9篇 |
1981年 | 9篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1975年 | 2篇 |
1959年 | 3篇 |
1957年 | 3篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
101.
Suyun Jie Tianzhu Zhang Jiutong Chen Dongbing Liu Wei Chen 《Journal of organometallic chemistry》2005,690(7):1739-1749
A series of bridged bis(pyridinylimino) ligands were efficiently synthesized through the condensation reaction of 4,4′-methylene-bis(2,6-disubstituted aniline) with 2-pyridinecarboxaldehyde or 2-benzoylpyridine. They reacted with (DME)NiBr2 to form dinuclear Ni(II) complexes. All resultant compounds were characterized by elemental analysis, IR spectra as well as the single-crystal X-ray diffraction to confirm the structures of ligands and complexes. Activated with methylaluminoxane (MAO), these nickel complexes showed considerably good activities for ethylene oligomerization and polymerization. Their catalytic activities and the properties of PEs obtained were depended on the arched environment of ligand and reaction conditions. 相似文献
102.
Facile synthesis of exfoliated and highly conductive poly(arylene disulfide)/graphite nanocomposites
Exfoliated graphite has been synthesized by first synthesizing H2SO4 intercalated compound in a H2O2‐H2SO4 mixture, followed by exfoliation under microwave irradiation. Poly(arylene disulfide)/graphite nanocomposites were then fabricated by absorbing cyclic(arylene disulfide) oligomers into the pores of exfoliated graphite. Subsequently, the nanocomposite precursor was subjected to heat treatment to carry out the in situ ring‐opening polymerization of the oligomers via free radical mechanism. The as‐prepared nanocomposite exhibited a exfoliated nanostructure as evidenced by transmission electron microscopy (TEM) observation. The nanocomposite with a very small amount of graphite, 5 wt%, possesses a highly electrical conductivity of 4 S/cm, therefore, many applications can be found as conductive materials. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
103.
The perfluorohexylated 3,4-ethylenedioxythiophene 5 was prepared via Mitsunobu reaction of perfluorohexylatyed diol 2 with diethyl 3,4-dihydroxythiophenedicarboxylate followed by decarboxylation. The polymerization of 5 was conducted with both oxidative chemical and electrochemical polymerizations. The polymers were characterized by cyclic voltammogram, UV, IR, TGA and DSC. 相似文献
104.
105.
Multi-substituted dihydrofurans are valuable intermediates for the synthesis of natural products and pharmaceuticals. Considerable attention has been focused on the development of efficient and regioselective methods for their preparation. Using K2CO3 as a base, with the reaction of fur-2-oylmethyltriphenylarsonium bromide 1 and ethyl 2-acetyl-3-arylacrylate 2 in tetrahydrofuran at room temperature, we found an efficient protocol was achieved to synthesize trans-3-aryl-4-carbethoxy-2,3-dihydro-2-fur-2'-oyl-5-methylfurans 3 in good yield with high stereoselectivity. The structure of compound 3 was confirmed by IR, ^1H NMR, MS and HRMS. The mechanism for the formation of 3 was proposed. 相似文献
106.
Jin Yan Dong Ye Gao Chen Hong Chuan Song Yan Ping He Lei Li Yong Ping Zhong Yan Hui Zhu Jie Cao Luo Wang Ke Qin Zhang Laboratory for Conservation Utilization of Bioresources Yunnan University Kunming China Department of Chemistry Yunnan Normal University Kunming China Provincial Key Lab of Rural Energy Engineering Yunnan Normal University Kunming China 《中国化学快报》2007,18(2):165-167
Microbial transformation of nigranoic acid by Caryospora carllicarpa YMF1.01026 afforded the new derivative 6β-hydro-xynigranoic acid. Its structure was elucidated by spectroscopic methods. 相似文献
107.
A concise method to synthesize benzo[c]phenanthridine alkaloid, nornitidine, was developed utilizing nickel- or palladium-catalyzed iminoannulation of an internal alkyne. The advantages of this strategy included readily available starting materials, inexpensive reagents, short reaction steps, and good yields. 相似文献
108.
As a kind of special functional microspheres, fluorescent polymer microspheres could be used in cell label and separation, blood flow assay, flow cytometer marking, chemical reaction assay,and in analyst of the transform and diffusion of particles in soil 1. However, one of the most important applications of fluorescent microspheres is in the high-throughput screening of drugs (HTS) 2. Through affinity interaction, radioactive ligands (latent drugs) are bound to fluorescent microspheres covered by receptor, and luminescence is produced by radioactivity, so ligands can be assayed and screened.In this study, we developed a technique for preparing micron-size fluorescent microspheres with different functional groups. The methods included the synthesis of micron-size polystyrene microspheres through the dispersion polymerization of styrene in different media such as ethanol,ethanol-water, and isopropanol; the functional polystyrene microspheres were prepared by introduction of functional monomers into the reaction system of styrene; the functional fluorescent microspheres were obtained by the way of dying functional microspheres in the fluorescent material's ethanol solvent.The average diameter of microspheres was in the range of 1~10 μm, and the distribution was normal distribution. The functional groups included -OH, -CHO, -COOH, -CONH2, and SO3H. The absorbing spectrum and exciting spectrum were tested, the results showed that the maximal absorbance of fluorescent microsphere was near 306.5 nm, and its maximal excitation was near 362 nm. The excitation spectrum of fluorescent material (DPO) and fluorescent microspheres were shown in figure 1, and it indicated that the developed fluorescent microspheres showed the same excitation behavior like DPO, which related to the fluorescent microspheres had stable luminescence property. 相似文献
109.
110.
用密度泛含方法研究了LaC5n(n=-1,0,+1)分子簇的结构和稳定性及振动光谱,对这个六原子体系提出了三种可能构型,点群结构为C2v对称性.第一个构型为La接在弯曲的C5链上,第二个是La通过二个键与C5环相连第三个是La通过一个键与C5环相连;结果表明,第一个构型即当La接在弯曲的C5链上时能量最低.振动光谱分析指出,当n=-1时,第二个构型为局域极小值;当n=+1时,第一个和第二个构型为局域极小值;对n=0,局域极小值没有找到. 相似文献