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181.
Li-Na Xiang Li-Juan Chen Lin Tan Chong Zhang Fu-Hu Cao Song-Tao Liu Yan-Mei Wang 《中国化学快报》2013,24(7):597-600
A novel polydopamine-graft-poly(2-methyl-2-oxazoline)(PDA-g-PMOXA) coating was prepared by immobilizing poly(2-methyl-2-oxazoline)(PMOXA) onto material surfaces through polydopamine (PDA) anchored coating for the first time.And then,the chemical composition,hydrophilicity,and protein-resistant properties of the PDA-g-PMOXA coating were studied using X-ray photoelectron spectroscopy(XPS),contact angel(CA) test,surface plasmon resonance(SPR),and quartz crystal microbalance with dissipation(QCM-D) measurement.Finally,the coating was applied to the capillary inner surface for protein separation by capillary electrophoresis(CE). 相似文献
182.
以乙二醇、乙醇为溶剂通过溶剂热法制备出立方状ITO纳米粉体,研究了反应时间、NaOH浓度对ITO纳米粉体形貌的影响,并讨论了溶剂体积比、NaOH浓度对ITO粉体导电性的影响及机理。结果表明:采用乙二醇与乙醇做溶剂,VEG:VEtOH=4:1时,制备出分散性良好的立方状ITO纳米粉体,平均粒径为10.7 nm,且其XRD衍射峰强度比I400/I222最高为0.380;乙二醇与乙醇做溶剂,VEG:VEtOH=4:1,且NaOH浓度为0.275 mol·L-1时,粉体电导率最高为46.75 mS·cm-1。 相似文献
183.
Kundawlet Alimaje Xiang Wang Zhe-Yu Zhang Jun Peng Zhen-Yu Shi Xia Yu Zi-Xing Ren 《Journal of Cluster Science》2013,24(4):1021-1030
Two bisupporting Keggin-type polyoxoanion-based hybrids decorated by [Zn(phen)2]2+ complexes, [Zn(phen)2]2(PW 11 VI WVO40) (1) and K[Zn(phen)2(H2O)]2(OH) (SiW12O40)·H2O (2) (phen = 1,10′-phenanthroline), have been hydrothermally synthesized, and characterized by elemental analysis, IR spectra, UV–Vis spectrum, X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis, and single-crystal X-ray diffraction. The structural analyses reveal that compound 1 consists of a 0D bisupporting Keggin-type heteropoly blue cluster obtained by using reductant glucose, which is grafted by two [Zn(phen)2]2+ fragments; compound 2 presents a 1D infinite chain, which is constructed from bisupporting [SiW12O40]4? polyoxoanions decorated by [Zn(phen)2(H2O)]2+ fragments and K+ ions. Additionally, the electrochemical behaviors of two compounds were studied. 相似文献
184.
Xiang Ting Zhang ZuLei Liu HaiQing Yin ZhengZhi Li Lei Liu XiaoMing 《中国科学:化学(英文版)》2013,56(5):567-575
Science China Chemistry - Nanofiber membranes from the composite of cellulose acetate/polyvinylpyrrolidone were prepared using electrospinning technique. After treated with water and alcoholic KOH... 相似文献
185.
186.
Xiang Wang Dr. Qian Xu Dr. Fengtao Fan Dr. Xiuli Wang Dr. Mingrun Li Prof. Zhaochi Feng Prof. Can Li 《化学:亚洲杂志》2013,8(9):2189-2195
By taking advantage of UV‐Raman spectroscopy and high‐resolution TEM (HRTEM), combined with the focused ion beam (FIB) technique, the transformation from GaOOH into α‐Ga2O3 and then into β‐Ga2O3 was followed. We found that the stepwise transformations took place from the surface region before developing into the bulk of single particles without particle agglomeration and growth. During the transformation from GaOOH into α‐Ga2O3, the elimination of water vapor through the dehydroxylation of GaOOH resulted in the formation of micropores in the single particles, whilst maintaining their particle size. For the phase transformation from α‐Ga2O3 into β‐Ga2O3, the nucleation of β‐Ga2O3 was found to occur at the surface defects and this process could be retarded by occupying these defects with a small amount of La2O3. By finely controlling the process of the phase transformation, the β‐Ga2O3 domains gradually developed from the surface into the bulk of the single particles without particle agglomeration. Therefore, the surface structure of the α‐Ga2O3 single particles can be easily tuned and a particle with an α@β core–shell phase structure has been obtained. 相似文献
187.
Two types of β‐enaminoketone derivatives of 3‐(2‐oxo‐2‐arylethylidene)‐3,4‐dihydro‐1H‐quinoxalin‐2‐ones and 3‐(2‐oxo‐2‐arylethylidene)‐3,4‐dihydro‐benzo[1,4]oxazin‐2‐ ones were effectively and conveniently prepared in good to excellent yields under solvent‐free conditions via the catalysis of sulfamic acid in the corresponding condensations of o‐phenylenediamine and o‐aminophenol with ethyl 2,4‐dioxo‐4‐arylbutyrate respectively. The compounds were confirmed by IR, 1H NMR, and 13C NMR, and a representative was further determined by X‐ray crystallography. 相似文献
188.
Dianlong Zhang Xiang Li Guojin Li Guoyong Wang 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2013,87(11):1817-1820
The aggregation behavior of tetrasiloxane-lactobionamide (Si4N2-LA) in aqueous solution has been characterized by dynamic light scattering (DLS), negative-stained transmission electron microscopy (TEM) and X-ray Diffraction methods. Compared with the micellar sizes 7.0 nm of n-dodecyllactobionamide (C12Glu2), the Si4N2-LA molecule can self-assemble into spherical vesicle with diameters in the range from 60 to 300 nm. 相似文献
189.
190.
A series of nickel halides bearing 2,4-di-t-butyl-6-(quinolin-8-yliminomethyl) phenolate ligands was synthesized and characterized by IR spectroscopy and elemental analysis.Molecular structures of C1(R = H,X = Br) and C2(R = H,X = Cl) were further confirmed by single-crystal X-ray crystallographic studies,and revealed a distorted square planar geometry at nickel.Upon activation with diethylaluminum chloride(Et 2 AlCl),all nickel pre-catalysts displayed good catalytic activity [up to 9.3 × 10 5 g mol 1(Ni) h 1 ] for ethylene oligomerization with major dimerization.In the presence of methylaluminoxane(MAO),the nickel complex C1 was capable of ethylene polymerization under 3 MPa,and produced polyethylene products with narrow polydispersity(1.16 1.73) and molecular weights in the range of 2.6 4.95 kg/mol. 相似文献